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Fabrication of PEO-PMMA-LiClO 4 -Based Solid Polymer Electrolytes Containing Silica Aerogel Particles for All-Solid-State Lithium Batteries

Author

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  • Ye Sol Lim

    (Department of Materials Science and Engineering, Inha University, 100 Inha-ro, Michuhol-gu, Incheon 22212, Korea)

  • Hyun-Ah Jung

    (Department of Materials Science and Engineering, Inha University, 100 Inha-ro, Michuhol-gu, Incheon 22212, Korea)

  • Haejin Hwang

    (Department of Materials Science and Engineering, Inha University, 100 Inha-ro, Michuhol-gu, Incheon 22212, Korea)

Abstract

To improve the ionic conductivity and thermal stability of a polyethylene oxide (PEO)-ethylene carbonate (EC)-LiClO 4 -based solid polymer electrolyte for lithium-ion batteries, polymethyl methacrylate (PMMA) and silica aerogel were incorporated into the PEO matrix. The effects of the PEO:PMMA molar ratio and the amount of silica aerogel on the structure of the PEO-PMMA-LiClO 4 solid polymer electrolyte were studied by X-ray diffraction, Fourier-transform infrared spectroscopy and alternating current (AC) impedance measurements. The solid polymer electrolyte with PEO:PMMA = 8:1 and 8 wt% silica aerogel exhibited the highest lithium-ion conductivity (1.35 × 10 −4 S∙cm −1 at 30 °C) and good mechanical stability. The enhanced amorphous character and high degree of dissociation of the LiClO 4 salt were responsible for the high lithium-ion conductivity observed. Silica aerogels with a high specific surface area and mesoporosity could thus play an important role in the development of solid polymer electrolytes with improved structure and stability.

Suggested Citation

  • Ye Sol Lim & Hyun-Ah Jung & Haejin Hwang, 2018. "Fabrication of PEO-PMMA-LiClO 4 -Based Solid Polymer Electrolytes Containing Silica Aerogel Particles for All-Solid-State Lithium Batteries," Energies, MDPI, vol. 11(10), pages 1-10, September.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:10:p:2559-:d:172034
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    References listed on IDEAS

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    1. Ruxing Gao & Hyo On Nam & Won Il Ko & Hong Jang, 2017. "National Options for a Sustainable Nuclear Energy System: MCDM Evaluation Using an Improved Integrated Weighting Approach," Energies, MDPI, vol. 10(12), pages 1-24, December.
    2. Golriz Kermani & Elham Sahraei, 2017. "Review: Characterization and Modeling of the Mechanical Properties of Lithium-Ion Batteries," Energies, MDPI, vol. 10(11), pages 1-25, October.
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    Cited by:

    1. Bin Zhao & Qi Wang & Boheng Yuan & Yafei Lu & Xiaogang Han, 2021. "An All-Solid-State Lithium Metal Battery Based on Electrodes-Compatible Plastic Crystal Electrolyte," Energies, MDPI, vol. 14(21), pages 1-9, October.

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