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Hydropyrolysis of n- Hexane and Toluene to Acetylene in Rotating-Arc Plasma

Author

Listed:
  • Jie Ma

    (Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China)

  • Ming Zhang

    (Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China)

  • Jianhua Wu

    (Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China)

  • Qiwei Yang

    (Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China)

  • Guangdong Wen

    (Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China)

  • Baogen Su

    (Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China)

  • Qilong Ren

    (Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China)

Abstract

Thermal plasma pyrolysis is a powerful technology for converting waste or low-value materials to valuable gaseous hydrocarbons. This paper presents for the first time the hydropyrolysis of n- hexane and toluene in a rotating-arc plasma reactor. Effects of the mole ratio of H/C in the feed, power input and magnetic induction were investigated to evaluate the reaction performance. A lower H/C ratio could lead to a lower yield of C 2 H 2 and lower specific energy consumption, and there existed an optimum range of power input for both n- hexane and toluene pyrolysis within the investigated range. The yield of C 2 H 2 in n- hexane and toluene pyrolysis could reach 85% and 68%, respectively, with respective specific energy consumption (SEC) of 13.8 kWh/kg·C 2 H 2 and 19.9 kWh/kg·C 2 H 2 . Compared with the results reported in literature, the rotating-arc plasma process showed higher C 2 H 2 yield and lower energy consumption, which is attributed to the better initial mixing of the reactant with the hot plasma gas and the more uniform temperature distribution.

Suggested Citation

  • Jie Ma & Ming Zhang & Jianhua Wu & Qiwei Yang & Guangdong Wen & Baogen Su & Qilong Ren, 2017. "Hydropyrolysis of n- Hexane and Toluene to Acetylene in Rotating-Arc Plasma," Energies, MDPI, vol. 10(7), pages 1-12, July.
  • Handle: RePEc:gam:jeners:v:10:y:2017:i:7:p:899-:d:103304
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    References listed on IDEAS

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    1. Andrius Tamošiūnas & Ajmia Chouchène & Pranas Valatkevičius & Dovilė Gimžauskaitė & Mindaugas Aikas & Rolandas Uscila & Makrem Ghorbel & Mejdi Jeguirim, 2017. "The Potential of Thermal Plasma Gasification of Olive Pomace Charcoal," Energies, MDPI, vol. 10(5), pages 1-14, May.
    2. Ming Zhang & Jie Ma & Baogen Su & Guangdong Wen & Qiwei Yang & Qilong Ren, 2017. "Pyrolysis of Polyolefins Using Rotating Arc Plasma Technology for Production of Acetylene," Energies, MDPI, vol. 10(4), pages 1-13, April.
    3. Zhang, Ming & Xue, Wenfeng & Su, Baogen & Bao, Zongbi & Wen, Guangdong & Xing, Huabin & Ren, Qilong, 2017. "Conversion of glycerol into syngas by rotating DC arc plasma," Energy, Elsevier, vol. 123(C), pages 1-8.
    4. Hossam A. Gabbar & Mohamed Aboughaly & C.A. Barry Stoute, 2017. "DC Thermal Plasma Design and Utilization for the Low Density Polyethylene to Diesel Oil Pyrolysis Reaction," Energies, MDPI, vol. 10(6), pages 1-15, June.
    5. Majidi Bidgoli, Abbas & Ghorbanzadeh, Atamalek & Lotfalipour, Raheleh & Roustaei, Ehsan & Zakavi, Marjan, 2017. "Gliding spark plasma: Physical principles and performance in direct pyrolysis of methane," Energy, Elsevier, vol. 125(C), pages 705-715.
    6. Zhang, Qinglin & Dor, Liran & Zhang, Lan & Yang, Weihong & Blasiak, Wlodzimierz, 2012. "Performance analysis of municipal solid waste gasification with steam in a Plasma Gasification Melting reactor," Applied Energy, Elsevier, vol. 98(C), pages 219-229.
    7. Ahmed El-Tayeb & Ahmed H. El-Shazly & Marwa F. Elkady, 2016. "Investigation the Influence of Different Salts on the Degradation of Organic Dyes Using Non-Thermal Plasma," Energies, MDPI, vol. 9(11), pages 1-19, October.
    8. Zhang, Qinglin & Dor, Liran & Fenigshtein, Dikla & Yang, Weihong & Blasiak, Wlodzmierz, 2012. "Gasification of municipal solid waste in the Plasma Gasification Melting process," Applied Energy, Elsevier, vol. 90(1), pages 106-112.
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    2. Wei Huang & Junkui Jin & Guangdong Wen & Qiwei Yang & Baogen Su & Qilong Ren, 2018. "Effect of Nitrogen/Oxygen Substances on the Pyrolysis of Alkane-Rich Gases to Acetylene by Thermal Plasma," Energies, MDPI, vol. 11(2), pages 1-14, February.
    3. Dong Kyoo Park & Ji-Hyeon Kim & Hyo-Sik Kim & Jin-Ho Kim & Jae-Hong Ryu, 2023. "Possibility Study in CO 2 Free Hydrogen Production Using Dodecane (C 12 H 26 ) from Plasma Reaction," Energies, MDPI, vol. 16(4), pages 1-13, February.

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