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High-Temperature Steam- and CO 2 -Assisted Gasification of Oil Sludge and Petcoke

Author

Listed:
  • Sergey M. Frolov

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia
    Kutateladze Institute of Thermophysics, Siberian Branch of the Russian Academy of Sciences, 1, Ac. Lavrentieva Avenue, Novosibirsk 630090, Russia)

  • Viktor A. Smetanyuk

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia)

  • Ilyas A. Sadykov

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia)

  • Anton S. Silantiev

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia
    Kutateladze Institute of Thermophysics, Siberian Branch of the Russian Academy of Sciences, 1, Ac. Lavrentieva Avenue, Novosibirsk 630090, Russia)

  • Fedor S. Frolov

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia)

  • Vera Ya. Popkova

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia)

  • Jaroslav K. Hasiak

    (Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 28 Vavilov Street, Moscow 119443, Russia)

  • Anastasiya G. Buyanovskaya

    (Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 28 Vavilov Street, Moscow 119443, Russia)

  • Rina U. Takazova

    (Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 28 Vavilov Street, Moscow 119443, Russia)

  • Tatiana V. Dudareva

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia)

  • Valentin G. Bekeshev

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia)

  • Alexey B. Vorobyov

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia)

  • Alexey V. Inozemtsev

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia)

  • Jaroslav O. Inozemtsev

    (Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences, 4, Kosyging Street, Moscow 119991, Russia)

Abstract

A new high-temperature allothermal gasification technology is used to process three types of oil waste: ground oil sludge (GOS), tank oil sludge (TOS), and petcoke. The gasifying agent (GA), mainly composed of H 2 O and CO 2 at a temperature above 2300 K and atmospheric pressure, is produced by pulsed detonations of a near-stochiometric methane-oxygen mixture. The gasification experiments show that the dry off-gas contains 80–90 vol.% combustible gas composed of 40–45 vol.% CO, 28–33 vol.% H 2 , 5–10 vol.% CH 4 , and 4–7 vol.% noncondensable C 2 –C 3 hydrocarbons. The gasification process is accompanied by the removal of mass from a flow gasifier in the form of fine solid ash particles with a size of about 1 μm. The ash particles have a mesoporous structure with a specific surface area ranging from 3.3 to 15.2 m 2 /g and pore sizes ranging from 3 to 50 nm. The measured wall temperatures of the gasifier are in reasonable agreement with the calculated value of the thermodynamic equilibrium temperature of the off-gas. The measured CO content in the off-gas is in good agreement with the thermodynamic calculations. The reduced H 2 content and elevated contents of CH 4 , CO 2 , and C x H y are apparently associated with the nonuniform distribution of the waste/GA mass ratio in the gasifier. To increase the H 2 yield, it is necessary to improve the mixing of waste with the GA. It is proposed to mix crushed petcoke with oil sludge to form a paste and feed the combined waste into the gasifier using a specially designed feeder.

Suggested Citation

  • Sergey M. Frolov & Viktor A. Smetanyuk & Ilyas A. Sadykov & Anton S. Silantiev & Fedor S. Frolov & Vera Ya. Popkova & Jaroslav K. Hasiak & Anastasiya G. Buyanovskaya & Rina U. Takazova & Tatiana V. Du, 2025. "High-Temperature Steam- and CO 2 -Assisted Gasification of Oil Sludge and Petcoke," Clean Technol., MDPI, vol. 7(1), pages 1-26, February.
    • Handle: RePEc:gam:jcltec:v:7:y:2025:i:1:p:17-:d:1591654
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    References listed on IDEAS

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    4. Nipattummakul, Nimit & Ahmed, Islam I. & Kerdsuwan, Somrat & Gupta, Ashwani K., 2012. "Steam gasification of oil palm trunk waste for clean syngas production," Applied Energy, Elsevier, vol. 92(C), pages 778-782.
    5. Sergey M. Frolov & Konstantin S. Panin & Viktor A. Smetanyuk, 2024. "Gasification of Liquid Hydrocarbon Waste by the Ultra-Superheated Mixture of Steam and Carbon Dioxide: A Thermodynamic Study," Energies, MDPI, vol. 17(9), pages 1-20, April.
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