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A review of the microporous layer in proton exchange membrane fuel cells: Materials and structural designs based on water transport mechanism

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  • Zhang, Jingjing
  • Wang, Biao
  • Jin, Junhong
  • Yang, Shenglin
  • Li, Guang

Abstract

Proton exchange membrane fuel cells (PEMFCs) have exhibited great potential as future electrochemical devices to power a wide scope of applications. Despite recent rapid progress in optimizing the individual component such as catalyst and membrane, efficient water management has been relatively underexplored. Improper water loading raises various issues including material degradation and local reactant starvation, which accordingly compromises the long-term durability of the cell. Introducing the microporous layer (MPL) to the gas diffusion layer (GDL) has been demonstrated as an effective strategy to resolve these issues by promoting smooth gas and water transport. Here, we summarize recent progress on the materials and structural designs of MPL, as well as investigations involving the correlated water transport behaviors. Influence of the key parameters of MPL including pore size, porosity, thickness, hydrophobicity and hydrophilicity, and surface morphology are thoroughly discussed from both mechanistic and performance-driven perspectives. We also highlight the employment of advanced fabrication and characterization techniques, which afford important insights into the prevention of water flooding and membrane dehydration. We hope the efforts presented here can guide rational material design and exquisite structure engineering of MPL, which will set the stage for future research in this area and beyond.

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  • Zhang, Jingjing & Wang, Biao & Jin, Junhong & Yang, Shenglin & Li, Guang, 2022. "A review of the microporous layer in proton exchange membrane fuel cells: Materials and structural designs based on water transport mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
  • Handle: RePEc:eee:rensus:v:156:y:2022:i:c:s1364032121012612
    DOI: 10.1016/j.rser.2021.111998
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    1. Chun, Jeong Hwan & Jo, Dong Hyun & Kim, Sang Gon & Park, Sun Hee & Lee, Chang Hoon & Lee, Eun Sook & Jyoung, Jy-Young & Kim, Sung Hyun, 2013. "Development of a porosity-graded micro porous layer using thermal expandable graphite for proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 58(C), pages 28-33.
    2. Kui Jiao & Jin Xuan & Qing Du & Zhiming Bao & Biao Xie & Bowen Wang & Yan Zhao & Linhao Fan & Huizhi Wang & Zhongjun Hou & Sen Huo & Nigel P. Brandon & Yan Yin & Michael D. Guiver, 2021. "Designing the next generation of proton-exchange membrane fuel cells," Nature, Nature, vol. 595(7867), pages 361-369, July.
    3. Zachary P. Cano & Dustin Banham & Siyu Ye & Andreas Hintennach & Jun Lu & Michael Fowler & Zhongwei Chen, 2018. "Batteries and fuel cells for emerging electric vehicle markets," Nature Energy, Nature, vol. 3(4), pages 279-289, April.
    4. Yuanjun Chen & Shufang Ji & Shu Zhao & Wenxing Chen & Juncai Dong & Weng-Chon Cheong & Rongan Shen & Xiaodong Wen & Lirong Zheng & Alexandre I. Rykov & Shichang Cai & Haolin Tang & Zhongbin Zhuang & C, 2018. "Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell," Nature Communications, Nature, vol. 9(1), pages 1-12, December.
    5. John H. Martin & Brennan D. Yahata & Jacob M. Hundley & Justin A. Mayer & Tobias A. Schaedler & Tresa M. Pollock, 2017. "3D printing of high-strength aluminium alloys," Nature, Nature, vol. 549(7672), pages 365-369, September.
    6. Wang, Yang & Luo, Hui & Li, Guang & Jiang, Jianming, 2016. "Highly active platinum electrocatalyst towards oxygen reduction reaction in renewable energy generations of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 173(C), pages 59-66.
    7. Fadzillah, D.M. & Rosli, M.I. & Talib, M.Z.M. & Kamarudin, S.K. & Daud, W.R.W., 2017. "Review on microstructure modelling of a gas diffusion layer for proton exchange membrane fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1001-1009.
    8. Jones, J. & Genovese, A. & Tob-Ogu, A., 2020. "Hydrogen vehicles in urban logistics: A total cost of ownership analysis and some policy implications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    9. Park, Jaeman & Oh, Hwanyeong & Lee, Yoo Il & Min, Kyoungdoug & Lee, Eunsook & Jyoung, Jy-Young, 2016. "Effect of the pore size variation in the substrate of the gas diffusion layer on water management and fuel cell performance," Applied Energy, Elsevier, vol. 171(C), pages 200-212.
    10. Nishimura, Akira & Yamamoto, Kohei & Okado, Tatsuya & Kojima, Yuya & Hirota, Masafumi & Kolhe, Mohan Lal, 2020. "Impact analysis of MPL and PEM thickness on temperature distribution within PEFC operating at relatively higher temperature," Energy, Elsevier, vol. 205(C).
    11. Lin, Rui & Tang, Shenghao & Diao, Xiaoyu & Zhong, Di & Chen, Liang & Froning, Dieter & Hao, Zhixian, 2020. "Detailed optimization of multiwall carbon nanotubes doped microporous layer in polymer electrolyte membrane fuel cells for enhanced performance," Applied Energy, Elsevier, vol. 274(C).
    Full references (including those not matched with items on IDEAS)

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    1. Zhang, Yuqi & Li, Yu & Zhang, Caizhi & Yang, Yunzi & Yu, Xingzi & Niu, Tong & Wang, Lei & Wang, Gucheng, 2024. "Intelligent diagnosis of proton exchange membrane fuel cell water states based on flooding-specificity experiment and deep learning method," Renewable Energy, Elsevier, vol. 222(C).
    2. Calili-Cankir, Fatma & Ismail, Mohammed S. & Ingham, Derek B. & Hughes, Kevin J. & Ma, Lin & Pourkashanian, Mohamed, 2023. "Air-breathing polymer electrolyte fuel cells: A review," Renewable Energy, Elsevier, vol. 213(C), pages 86-108.
    3. Lee, F.C. & Ismail, M.S. & Ingham, D.B. & Hughes, K.J. & Ma, L & Lyth, S.M. & Pourkashanian, M., 2022. "Alternative architectures and materials for PEMFC gas diffusion layers: A review and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    4. Hossein Pourrahmani & Majid Siavashi & Adel Yavarinasab & Mardit Matian & Nazanin Chitgar & Ligang Wang & Jan Van herle, 2022. "A Review on the Long-Term Performance of Proton Exchange Membrane Fuel Cells: From Degradation Modeling to the Effects of Bipolar Plates, Sealings, and Contaminants," Energies, MDPI, vol. 15(14), pages 1-30, July.
    5. Antonio Nicolò Mancino & Carla Menale & Francesco Vellucci & Manlio Pasquali & Roberto Bubbico, 2023. "PEM Fuel Cell Applications in Road Transport," Energies, MDPI, vol. 16(17), pages 1-27, August.

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