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Preparation of carbon molecular sieve from lignocellulosic biomass: A review

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  • Mohamed, Abdul Rahman
  • Mohammadi, Maedeh
  • Darzi, Ghasem Najafpour

Abstract

A literature review on preparation of carbon molecular sieve (CMS) from lignocellulosic biomass is presented. The effect of various operation parameters such as pyrolytic temperature, flow rate of the carbonizing agent and time of pyrolysis on the carbonization of the lignocellulosic biomass as a carbon precursor was reviewed. Various physical and chemical processes for the activation of the biomass-based char and their effects on textural properties of the activated char were discussed. Conversion of activated chars to CMS as the final stage of the preparation process through different techniques of chemical vapor deposition (CVD) and controlled pyrolysis was assessed. Survey of literature revealed that production of CMS with BET surface area of 1247Â m2/g and micropore volume of 0.51Â cm3/g, under appropriate conditions has been reported. Also, maximum selectivity of 7.6 and 400 for separation of O2/N2 and CO2/CH4 was devoted to palm shell and coconut shell-based CMS, respectively.

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  • Mohamed, Abdul Rahman & Mohammadi, Maedeh & Darzi, Ghasem Najafpour, 2010. "Preparation of carbon molecular sieve from lignocellulosic biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(6), pages 1591-1599, August.
    • Handle: RePEc:eee:rensus:v:14:y:2010:i:6:p:1591-1599
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    1. Ioannidou, O. & Zabaniotou, A., 2007. "Agricultural residues as precursors for activated carbon production--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1966-2005, December.
    2. Saxena, R.C. & Adhikari, D.K. & Goyal, H.B., 2009. "Biomass-based energy fuel through biochemical routes: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(1), pages 167-178, January.
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    1. Seo, Dong-June & Gou, Zhichao & Fujita, Hirotaka & Fujii, Takao & Sakoda, Akiyoshi, 2016. "Simple fabrication of molecular sieving carbon for biogas upgrading via a temperature controlled carbonization of Phyllostachys pubescens," Renewable Energy, Elsevier, vol. 86(C), pages 693-702.
    2. Antolini, Ermete, 2016. "Nitrogen-doped carbons by sustainable N- and C-containing natural resources as nonprecious catalysts and catalyst supports for low temperature fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 34-51.
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