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Development of graphite foam infiltrated with MgCl2 for a latent heat based thermal energy storage (LHTES) system

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  • Singh, Dileep
  • Kim, Taeil
  • Zhao, Weihuan
  • Yu, Wenhua
  • France, David M.

Abstract

Thermal energy storage (TES) systems that are compatible with high temperature power cycles for concentrating solar power (CSP) require high temperature media for transporting and storing thermal energy. To that end, TES systems have been proposed based on the latent heat of fusion of the phase change materials (PCMs). However, PCMs have relatively low thermal conductivities. In this paper, use of high-thermal-conductivity graphite foam infiltrated with a PCM (MgCl2) has been investigated as a potential TES system. Graphite foams with two porosities were infiltrated with MgCl2. The infiltrated composites were evaluated for density, heat of fusion, melting/freezing temperatures, and thermal diffusivities. Estimated thermal conductivities of MgCl2/graphite foam composites were significantly higher than those of MgCl2 alone over the measured temperature range. Furthermore, heat of fusion, melting/freezing temperatures, and densities showed comparable values to those of pure MgCl2. Results of this study indicate that MgCl2/graphite foam composites show promise as storage media for a latent heat thermal energy storage system for CSP applications.

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  • Singh, Dileep & Kim, Taeil & Zhao, Weihuan & Yu, Wenhua & France, David M., 2016. "Development of graphite foam infiltrated with MgCl2 for a latent heat based thermal energy storage (LHTES) system," Renewable Energy, Elsevier, vol. 94(C), pages 660-667.
    • Handle: RePEc:eee:renene:v:94:y:2016:i:c:p:660-667
    DOI: 10.1016/j.renene.2016.03.090
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    1. Zhao, Weihuan & France, David M. & Yu, Wenhua & Kim, Taeil & Singh, Dileep, 2014. "Phase change material with graphite foam for applications in high-temperature latent heat storage systems of concentrated solar power plants," Renewable Energy, Elsevier, vol. 69(C), pages 134-146.
    2. Nithyanandam, K. & Pitchumani, R., 2013. "Computational studies on a latent thermal energy storage system with integral heat pipes for concentrating solar power," Applied Energy, Elsevier, vol. 103(C), pages 400-415.
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    9. Hamidi, E. & Ganesan, P.B. & Sharma, R.K. & Yong, K.W., 2023. "Computational study of heat transfer enhancement using porous foams with phase change materials: A comparative review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
    10. Liu, Ming & Omaraa, Ehsan Shamil & Qi, Jia & Haseli, Pegah & Ibrahim, Jumal & Sergeev, Dmitry & Müller, Michael & Bruno, Frank & Majewski, Peter, 2021. "Review and characterisation of high-temperature phase change material candidates between 500 C and 700°C," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
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    12. Zhao, Y. & Zhao, C.Y. & Markides, C.N. & Wang, H. & Li, W., 2020. "Medium- and high-temperature latent and thermochemical heat storage using metals and metallic compounds as heat storage media: A technical review," Applied Energy, Elsevier, vol. 280(C).
    13. Rea, Jonathan E. & Oshman, Christopher J. & Singh, Abhishek & Alleman, Jeff & Parilla, Philip A. & Hardin, Corey L. & Olsen, Michele L. & Siegel, Nathan P. & Ginley, David S. & Toberer, Eric S., 2018. "Experimental demonstration of a dispatchable latent heat storage system with aluminum-silicon as a phase change material," Applied Energy, Elsevier, vol. 230(C), pages 1218-1229.
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