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Experimental investigation on a MnCl2–CaCl2–NH3 thermal energy storage system

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  • Jiang, L.
  • Zhu, F.Q.
  • Wang, L.W.
  • Liu, C.Z.
  • Wang, R.Z.

Abstract

Thermal energy storage (TES) is regarded as one promising technology for renewable energy and waste heat recovery. Among TES technologies, sorption thermal energy storage (STES) has drawn burgeoning attention due to high energy storage density, long-term heat storage capability and flexible working modes. Originating from STES system, resorption thermal energy storage (RTES) system is established and investigated for recovering the heat in this paper. The system is mainly composed of three high temperature salt (HTS) unit beds; three low temperature salt (LTS) unit beds, valves and heat exchange pipes. Working pair of MnCl2–CaCl2–NH3 is selected for the RTES system. 4.8 kg and 3.9 kg MnCl2 and CaCl2 composite adsorbents are filled in the adsorption bed. Results indicate that the highest thermal storage density is about 1836 kJ/kg when the heat charging and discharging temperature is 155 °C and 55 °C, respectively. Volume density of heat storage ranges from 144 to 304 kWh/m3. The highest ratio of latent heat to sensible heat is about 1.145 when the discharging temperature is 55 °C. The energy efficiency decreases from 97% to 73% when the discharging temperature increases from 55 to 75 °C.

Suggested Citation

  • Jiang, L. & Zhu, F.Q. & Wang, L.W. & Liu, C.Z. & Wang, R.Z., 2016. "Experimental investigation on a MnCl2–CaCl2–NH3 thermal energy storage system," Renewable Energy, Elsevier, vol. 91(C), pages 130-136.
    • Handle: RePEc:eee:renene:v:91:y:2016:i:c:p:130-136
    DOI: 10.1016/j.renene.2016.01.046
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    References listed on IDEAS

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    1. Zhu, F.Q. & Jiang, L. & Wang, L.W. & Wang, R.Z., 2016. "Experimental investigation on a MnCl2CaCl2NH3 resorption system for heat and refrigeration cogeneration," Applied Energy, Elsevier, vol. 181(C), pages 29-37.
    2. Gao, J. & Wang, L.W. & An, G.L. & Liu, J.Y. & Xu, S.Z., 2018. "Performance analysis of multi-salt sorbents without sorption hysteresis for low-grade heat recovery," Renewable Energy, Elsevier, vol. 118(C), pages 718-726.
    3. Cabeza, Luisa F. & Solé, Aran & Barreneche, Camila, 2017. "Review on sorption materials and technologies for heat pumps and thermal energy storage," Renewable Energy, Elsevier, vol. 110(C), pages 3-39.
    4. Elsayed, Ahmed & Elsayed, Eman & AL-Dadah, Raya & Mahmoud, Saad & Elshaer, Amr & Kaialy, Waseem, 2017. "Thermal energy storage using metal–organic framework materials," Applied Energy, Elsevier, vol. 186(P3), pages 509-519.
    5. Jiang, L. & Roskilly, A.P. & Wang, R.Z. & Wang, L.W. & Lu, Y.J., 2017. "Analysis on innovative modular sorption and resorption thermal cell for cold and heat cogeneration," Applied Energy, Elsevier, vol. 204(C), pages 767-779.
    6. Yan, Ting & Kuai, Z.H. & Wu, S.F., 2020. "Experimental investigation on a MnCl2–SrCl2/NH3 thermochemical resorption heat storage system," Renewable Energy, Elsevier, vol. 147(P1), pages 874-883.
    7. Yan, Ting & Zhang, Hong & Yu, Nan & Li, Dong & Pan, Q.W., 2022. "Performance of thermochemical adsorption heat storage system based on MnCl2-NH3 working pair," Energy, Elsevier, vol. 239(PD).
    8. Wang, L.W. & Jiang, L. & Gao, J. & Gao, P. & Wang, R.Z., 2017. "Analysis of resorption working pairs for air conditioners of electric vehicles," Applied Energy, Elsevier, vol. 207(C), pages 594-603.
    9. Sharma, Rakesh & Anil Kumar, E., 2017. "Study of ammoniated salts based thermochemical energy storage system with heat up-gradation: A thermodynamic approach," Energy, Elsevier, vol. 141(C), pages 1705-1716.

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