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Biodiesel production from waste coconut oil by esterification with ethanol: The effect of water removal by adsorption

Author

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  • Oliveira, João Felipe G.
  • Lucena, Izabelly Larissa
  • Saboya, Rosana M. Alves
  • Rodrigues, Marcelo L.
  • Torres, Antonio Eurico B.
  • Fernandes, Fabiano A. Narciso
  • Cavalcante, Célio L.
  • Parente, Expedito José S.

Abstract

The production of biodiesel by esterification with ethanol using waste oil generated in the refining of coconut oil was investigated in this study. The reaction was performed with and without adsorption of water in order to verify the effect of removing water on the reaction conversion. Methanol was also evaluated as an esterification agent. For both ethanol and methanol, conversions over 99%mol were observed. Simultaneous water adsorption allowed the use of lower alcohol/oil molar ratios thus enabling better economics to a possible industrial process.

Suggested Citation

  • Oliveira, João Felipe G. & Lucena, Izabelly Larissa & Saboya, Rosana M. Alves & Rodrigues, Marcelo L. & Torres, Antonio Eurico B. & Fernandes, Fabiano A. Narciso & Cavalcante, Célio L. & Parente, Expe, 2010. "Biodiesel production from waste coconut oil by esterification with ethanol: The effect of water removal by adsorption," Renewable Energy, Elsevier, vol. 35(11), pages 2581-2584.
    • Handle: RePEc:eee:renene:v:35:y:2010:i:11:p:2581-2584
    DOI: 10.1016/j.renene.2010.03.035
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    1. Shahid, Ejaz M. & Jamal, Younis, 2008. "A review of biodiesel as vehicular fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(9), pages 2484-2494, December.
    2. Chongkhong, S. & Tongurai, C. & Chetpattananondh, P., 2009. "Continuous esterification for biodiesel production from palm fatty acid distillate using economical process," Renewable Energy, Elsevier, vol. 34(4), pages 1059-1063.
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    1. D'Amato Villardi, Hugo Gomes & Leal, Monique Ferreira & Pellegrini Pessoa, Fernando Luiz & Salgado, Andréa Medeiros, 2019. "Synthesis of methyl esters through residual feedstock using acid and free catalyst – Proposal of new reactor," Renewable Energy, Elsevier, vol. 131(C), pages 1146-1155.
    2. Amani, H. & Ahmad, Z. & Hameed, B.H., 2014. "Synthesis of fatty acid methyl esters via the methanolysis of palm oil over Ca3.5xZr0.5yAlxO3 mixed oxide catalyst," Renewable Energy, Elsevier, vol. 66(C), pages 680-685.
    3. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    4. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    5. Farobie, Obie & Sasanami, Kazuma & Matsumura, Yukihiko, 2015. "A novel spiral reactor for biodiesel production in supercritical ethanol," Applied Energy, Elsevier, vol. 147(C), pages 20-29.
    6. Kanjaikaew, Utaiwan & Tongurai, Chakrit & Chongkhong, Sininart & Prasertsit, Kulchanat, 2018. "Two-step esterification of palm fatty acid distillate in ethyl ester production: Optimization and sensitivity analysis," Renewable Energy, Elsevier, vol. 119(C), pages 336-344.
    7. Li, Qiang & Xu, Jingyang & Du, Wei & Li, Yang & Liu, Dehua, 2013. "Ethanol as the acyl acceptor for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 742-748.
    8. Verma, Puneet & Sharma, M.P. & Dwivedi, Gaurav, 2016. "Impact of alcohol on biodiesel production and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 319-333.

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