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Synthesis and characteristics of carbon-based synfuel from biomass and coal powder by synergistic co-carbonization technology

Author

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  • Dong, Xinyuan
  • Wang, Zhixing
  • Zhang, Junhong
  • Zhan, Wenlong
  • Gao, Lihua
  • He, Zhijun

Abstract

A synergistic co-carbonization method based on the use of corn stalk (CS), wood shavings (WS) and bituminous coal (BC) is proposed as a green and low-cost technology. The preparation parameters included a co-carbonization temperature of 600 °C, a co-carbonization time of 30 min, and a biomass/coal ratio of 4/6. The high calorific value (HCV) and bulk density of the CS/BC synfuel were 29.81 MJ kg−1 and 495 kg m−3, respectively, and those of the WS/BC synfuel were 30.11 MJ kg−1 and 485 kg m−3, respectively. The results indicated that the microcrystalline structure was ordered and that the proportion of the graphitic structure increased during the synergistic co-carbonization process. In addition, the co-carbonization process changed the contents of the functional groups on the surface. The amount of aromatic C–O increased during the synergistic co-carbonization process. Decreases in the O-containing functional groups and increases in the graphitic carbon content in the synfuel demonstrated that the interactions of the biomass volatiles with the bituminous coal generated a more regular structure for the carbon-based synfuel and changed the carbon type of the synfuel. This work provides a mechanism for the biomass and coal interactions occurring during the preparation of carbon-based synfuels.

Suggested Citation

  • Dong, Xinyuan & Wang, Zhixing & Zhang, Junhong & Zhan, Wenlong & Gao, Lihua & He, Zhijun, 2024. "Synthesis and characteristics of carbon-based synfuel from biomass and coal powder by synergistic co-carbonization technology," Renewable Energy, Elsevier, vol. 227(C).
    • Handle: RePEc:eee:renene:v:227:y:2024:i:c:s0960148124005238
    DOI: 10.1016/j.renene.2024.120458
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