IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v221y2024ics0960148123016099.html
   My bibliography  Save this article

Thermochemical conversion of neem seed biomass to sustainable hydrogen and biofuels: Experimental and theoretical evaluation

Author

Listed:
  • Saidi, Majid
  • Faraji, Mehdi

Abstract

This study aims to investigate the potential of neem seeds as a renewable energy source for producing bio-oil and syngas through both experimental and theoretical approaches. Neem seeds underwent thermal pyrolysis in a semi-batch reactor after undergoing acid wash pre-treatment. The effects of pyrolysis temperatures (350–550 °C) and heating rates (10–40 °C/min) on product yields were analyzed, and the highest achieved bio-oil yield was 60.2 % at 450 °C and a heating rate of 40 °C/min. In the theoretical section, the Aspen Plus software was employed to simulate the process of steam gasification of neem seeds to identify optimal operating conditions for maximizing hydrogen production and cold gas efficiency (CGE) while maintaining an ideal H2/CO ratio. By analyzing the impact of operating parameters such as steam-to-biomass (S/B) ratio and temperature on the composition of the syngas stream, H2/CO ratio, and CGE, the study determined that the optimal operating conditions are an S/B ratio of 0.9 and temperatures ranging from 650 to 750 °C. The findings of this study can shed light on the potential of neem seed as a non-edible biomass source for renewable energy production, which can help reduce greenhouse gas emissions and mitigate the negative impacts of traditional energy sources on the environment.

Suggested Citation

  • Saidi, Majid & Faraji, Mehdi, 2024. "Thermochemical conversion of neem seed biomass to sustainable hydrogen and biofuels: Experimental and theoretical evaluation," Renewable Energy, Elsevier, vol. 221(C).
    • Handle: RePEc:eee:renene:v:221:y:2024:i:c:s0960148123016099
    DOI: 10.1016/j.renene.2023.119694
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123016099
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.119694?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. J.G. Usman & P.C. Okonkwo & M.S. Shehu, 2014. "Investigation into the Usage of Solvent for Extracting Neem Oil from Neem Seed for Industrial Application," Academic Journal of Interdisciplinary Studies, Richtmann Publishing Ltd, vol. 3, July.
    2. Safaripour, Maryam & Saidi, Majid & Nodeh, Hamid Rashidi, 2023. "Synthesis and application of barium tin oxide-reduced graphene oxide nanocomposite as a highly stable heterogeneous catalyst for the biodiesel production," Renewable Energy, Elsevier, vol. 217(C).
    3. Kakati, Ujjiban & Sakhiya, Anil Kumar & Baghel, Paramjeet & Trada, Akshit & Mahapatra, Sadhan & Upadhyay, Darshit & Kaushal, Priyanka, 2022. "Sustainable utilization of bamboo through air-steam gasification in downdraft gasifier: Experimental and simulation approach," Energy, Elsevier, vol. 252(C).
    4. dos Santos, Letícia Karen & Hatanaka, Rafael Rodrigues & de Oliveira, José Eduardo & Flumignan, Danilo Luiz, 2019. "Production of biodiesel from crude palm oil by a sequential hydrolysis/esterification process using subcritical water," Renewable Energy, Elsevier, vol. 130(C), pages 633-640.
    5. Radenahmad, Nikdalila & Azad, Atia Tasfiah & Saghir, Muhammad & Taweekun, Juntakan & Bakar, Muhammad Saifullah Abu & Reza, Md Sumon & Azad, Abul Kalam, 2020. "A review on biomass derived syngas for SOFC based combined heat and power application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    6. Jerry L. Holechek & Hatim M. E. Geli & Mohammed N. Sawalhah & Raul Valdez, 2022. "A Global Assessment: Can Renewable Energy Replace Fossil Fuels by 2050?," Sustainability, MDPI, vol. 14(8), pages 1-22, April.
    7. Zamani, Ali Salehi & Saidi, Majid & Najafabadi, Ali Taheri, 2023. "Selective production of diesel-like alkanes via Neem seed oil hydrodeoxygenation over Ni/MgSiO3 catalyst," Renewable Energy, Elsevier, vol. 209(C), pages 462-470.
    8. Vikram, Shruti & Deore, Sujeetkumar P. & De Blasio, Cataldo & Mahajani, Sanjay M. & Kumar, Sandeep, 2023. "Air gasification of high-ash solid waste in a pilot-scale downdraft gasifier: Experimental and numerical analysis," Energy, Elsevier, vol. 270(C).
    9. Adnan, Muflih A. & Hossain, Mohammad M. & Kibria, Md Golam, 2020. "Biomass upgrading to high-value chemicals via gasification and electrolysis: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 162(C), pages 1367-1379.
    10. Wang, Tengfei & Zhai, Yunbo & Zhu, Yun & Li, Caiting & Zeng, Guangming, 2018. "A review of the hydrothermal carbonization of biomass waste for hydrochar formation: Process conditions, fundamentals, and physicochemical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 223-247.
    11. Ascher, Simon & Watson, Ian & You, Siming, 2022. "Machine learning methods for modelling the gasification and pyrolysis of biomass and waste," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    12. Zeng, Jimin & Xiao, Rui & Yuan, Jun, 2021. "High-quality syngas production from biomass driven by chemical looping on a PY-GA coupled reactor," Energy, Elsevier, vol. 214(C).
    13. López-González, D. & Fernandez-Lopez, M. & Valverde, J.L. & Sanchez-Silva, L., 2014. "Gasification of lignocellulosic biomass char obtained from pyrolysis: Kinetic and evolved gas analyses," Energy, Elsevier, vol. 71(C), pages 456-467.
    14. Chuayboon, Srirat & Abanades, Stéphane & Rodat, Sylvain, 2019. "Insights into the influence of biomass feedstock type, particle size and feeding rate on thermochemical performances of a continuous solar gasification reactor," Renewable Energy, Elsevier, vol. 130(C), pages 360-370.
    15. Abu-Ghazala, Abdelmoniem H. & Abdelhady, Hosam H. & Mazhar, Amina A. & El-Deab, Mohamed S., 2022. "Valorization of hazard waste: Efficient utilization of white brick waste powder in the catalytic production of biodiesel from waste cooking oil via RSM optimization process," Renewable Energy, Elsevier, vol. 200(C), pages 1120-1133.
    16. Yang, Ke & Wu, Kai & Zhang, Huiyan, 2022. "Machine learning prediction of the yield and oxygen content of bio-oil via biomass characteristics and pyrolysis conditions," Energy, Elsevier, vol. 254(PB).
    17. Pio, D.T. & Gomes, H.G.M.F. & Tarelho, L.A.C. & Vilas-Boas, A.C.M. & Matos, M.A.A. & Lemos, F.M.S., 2022. "Superheated steam injection as primary measure to improve producer gas quality from biomass air gasification in an autothermal pilot-scale gasifier," Renewable Energy, Elsevier, vol. 181(C), pages 1223-1236.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Md Sumon Reza & Zhanar Baktybaevna Iskakova & Shammya Afroze & Kairat Kuterbekov & Asset Kabyshev & Kenzhebatyr Zh. Bekmyrza & Marzhan M. Kubenova & Muhammad Saifullah Abu Bakar & Abul K. Azad & Hrido, 2023. "Influence of Catalyst on the Yield and Quality of Bio-Oil for the Catalytic Pyrolysis of Biomass: A Comprehensive Review," Energies, MDPI, vol. 16(14), pages 1-39, July.
    2. Montazerinejad, H. & Eicker, U., 2022. "Recent development of heat and power generation using renewable fuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).
    3. Zamani, Ali Salehi & Saidi, Majid & Najafabadi, Ali Taheri, 2023. "Selective production of diesel-like alkanes via Neem seed oil hydrodeoxygenation over Ni/MgSiO3 catalyst," Renewable Energy, Elsevier, vol. 209(C), pages 462-470.
    4. Wei Wang & Leonid Melnyk & Oleksandra Kubatko & Bohdan Kovalov & Luc Hens, 2023. "Economic and Technological Efficiency of Renewable Energy Technologies Implementation," Sustainability, MDPI, vol. 15(11), pages 1-19, May.
    5. Vlachokostas, Ch. & Michailidou, A.V. & Achillas, Ch., 2021. "Multi-Criteria Decision Analysis towards promoting Waste-to-Energy Management Strategies: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    6. Tiago Teribele & Maria Elizabeth Gemaque Costa & Conceição de Maria Sales da Silva & Lia Martins Pereira & Lucas Pinto Bernar & Douglas Alberto Rocha de Castro & Fernanda Paula da Costa Assunção & Mar, 2023. "Hydrothermal Carbonization of Corn Stover: Structural Evolution of Hydro-Char and Degradation Kinetics," Energies, MDPI, vol. 16(7), pages 1-22, April.
    7. Andrea G. Capodaglio & Gustaf Olsson, 2019. "Energy Issues in Sustainable Urban Wastewater Management: Use, Demand Reduction and Recovery in the Urban Water Cycle," Sustainability, MDPI, vol. 12(1), pages 1-17, December.
    8. Zhang, Zhikun & Zhu, Zongyuan & Shen, Boxiong & Liu, Lina, 2019. "Insights into biochar and hydrochar production and applications: A review," Energy, Elsevier, vol. 171(C), pages 581-598.
    9. Zhang, Chao & Zhao, Yangsheng & Feng, Zijun & Meng, Qiaorong & Wang, Lei & Lu, Yang, 2023. "Thermal maturity and chemical structure evolution of lump long-flame coal during superheated water vapor–based in situ pyrolysis," Energy, Elsevier, vol. 263(PC).
    10. Sooraj Kumar & Suhail Ahmed Soomro & Khanji Harijan & Mohammad Aslam Uqaili & Laveet Kumar, 2023. "Advancements of Biochar-Based Catalyst for Improved Production of Biodiesel: A Comprehensive Review," Energies, MDPI, vol. 16(2), pages 1-20, January.
    11. Ahmed Hussain Elmetwaly & Ramy Adel Younis & Abdelazeem Abdallah Abdelsalam & Ahmed Ibrahim Omar & Mohamed Metwally Mahmoud & Faisal Alsaif & Adel El-Shahat & Mohamed Attya Saad, 2023. "Modeling, Simulation, and Experimental Validation of a Novel MPPT for Hybrid Renewable Sources Integrated with UPQC: An Application of Jellyfish Search Optimizer," Sustainability, MDPI, vol. 15(6), pages 1-30, March.
    12. Śliz, Maciej & Wilk, Małgorzata, 2020. "A comprehensive investigation of hydrothermal carbonization: Energy potential of hydrochar derived from Virginia mallow," Renewable Energy, Elsevier, vol. 156(C), pages 942-950.
    13. Elfarra, Barakat & Yasmeen, Rizwana & Shah, Wasi Ul Hassan, 2024. "The impact of energy security, energy mix, technological advancement, trade openness, and political stability on energy efficiency: Evidence from Arab countries," Energy, Elsevier, vol. 295(C).
    14. Dupont, Capucine & Jacob, Sylvain & Marrakchy, Khalil Ould & Hognon, Céline & Grateau, Maguelone & Labalette, Françoise & Da Silva Perez, Denilson, 2016. "How inorganic elements of biomass influence char steam gasification kinetics," Energy, Elsevier, vol. 109(C), pages 430-435.
    15. Sun, Youhong & Bai, Fengtian & Lü, Xiaoshu & Jia, Chunxia & Wang, Qing & Guo, Mingyi & Li, Qiang & Guo, Wei, 2015. "Kinetic study of Huadian oil shale combustion using a multi-stage parallel reaction model," Energy, Elsevier, vol. 82(C), pages 705-713.
    16. López-González, D. & Puig-Gamero, M. & Acién, F.G. & García-Cuadra, F. & Valverde, J.L. & Sanchez-Silva, L., 2015. "Energetic, economic and environmental assessment of the pyrolysis and combustion of microalgae and their oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1752-1770.
    17. Hatem Abushammala & Muhammad Adil Masood & Salma Taqi Ghulam & Jia Mao, 2023. "On the Conversion of Paper Waste and Rejects into High-Value Materials and Energy," Sustainability, MDPI, vol. 15(8), pages 1-21, April.
    18. Hagreaves Kumba & Oludolapo A. Olanrewaju & Ratidzo Pasipamire, 2024. "Integration of Renewable Energy Technologies for Sustainable Development in South Africa: A Focus on Grid-Connected PV Systems," Energies, MDPI, vol. 17(12), pages 1-22, June.
    19. Santa Margarida Santos & Ana Carolina Assis & Leandro Gomes & Catarina Nobre & Paulo Brito, 2022. "Waste Gasification Technologies: A Brief Overview," Waste, MDPI, vol. 1(1), pages 1-26, December.
    20. Khushbu Kumari & Raushan Kumar & Nirmali Bordoloi & Tatiana Minkina & Chetan Keswani & Kuldeep Bauddh, 2023. "Unravelling the Recent Developments in the Production Technology and Efficient Applications of Biochar for Agro-Ecosystems," Agriculture, MDPI, vol. 13(3), pages 1-26, February.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:221:y:2024:i:c:s0960148123016099. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.