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Synthesis of Ni/Clinoptilolite catalyst by modified polyol method for upgrading of bio-oil produced from hazelnut husk pyrolysis

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  • Bayrakdar Ates, Ezgi

Abstract

Bio-oil obtained by pyrolysis of biomass contains high amounts of oxygenated compounds as a result its physicochemical properties may give rise to certain challenges. Zeolite-based catalysts, such as clinoptilolite, have the ability to convert oxygenated compounds into less oxygenated compounds.10%Ni/Clinoptilolite catalyst was synthesized by modified polyol method as an alternative to known methods instead of common catalysts to improve bio-oil quality. Catalyzed/uncatalyzed pyrolysis of hazelnut husk (HH) was conducted for two distinct retention times (15 s and 25 s) and two catalyst/biomass ratios (1:1 and 2:1) to determine the effect of the catalyst. The optimal catalyst/biomass ratio for obtaining the highest aromatic hydrocarbon content was found to be two, whereas the highest aliphatic hydrocarbon content was observed at a ratio of one. An increase in retention time from 15 s to 25 s was found to have a positive impact on the composition of bio-oil, whereas it decreased the aromatic hydrocarbon content only when the ratio of catalyst to biomass was two.

Suggested Citation

  • Bayrakdar Ates, Ezgi, 2023. "Synthesis of Ni/Clinoptilolite catalyst by modified polyol method for upgrading of bio-oil produced from hazelnut husk pyrolysis," Renewable Energy, Elsevier, vol. 219(P2).
  • Handle: RePEc:eee:renene:v:219:y:2023:i:p2:s0960148123014751
    DOI: 10.1016/j.renene.2023.119560
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    1. Wang, Jicong & Bi, Peiyan & Zhang, Yajing & Xue, He & Jiang, Peiwen & Wu, Xiaoping & Liu, Junxu & Wang, Tiejun & Li, Quanxin, 2015. "Preparation of jet fuel range hydrocarbons by catalytic transformation of bio-oil derived from fast pyrolysis of straw stalk," Energy, Elsevier, vol. 86(C), pages 488-499.
    2. Balasundram, Vekes & Ibrahim, Norazana & Kasmani, Rafiziana Md. & Isha, Ruzinah & Hamid, Mohd. Kamaruddin Abd. & Hasbullah, Hasrinah & Ali, Roshafima Rasit, 2018. "Catalytic upgrading of sugarcane bagasse pyrolysis vapours over rare earth metal (Ce) loaded HZSM-5: Effect of catalyst to biomass ratio on the organic compounds in pyrolysis oil," Applied Energy, Elsevier, vol. 220(C), pages 787-799.
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