IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v210y2023icp627-639.html
   My bibliography  Save this article

Formation and transformation of mineral phases in biomass ashes and evaluation of the feedstocks for application in high-temperature processes

Author

Listed:
  • Reinmöller, Markus
  • Schreiner, Marcus
  • Laabs, Marcel
  • Scharm, Christoph
  • Yao, Zhitong
  • Guhl, Stefan
  • Neuroth, Manuela
  • Meyer, Bernd
  • Gräbner, Martin

Abstract

Biomasses are known for their variety of ash systems, often accompanied by limiting effects such as fouling, sintering, slagging, agglomeration and corrosion, which affect thermochemical conversion processes (combustion, gasification, pyrolysis etc.). To explore those limiting effects, five different feedstocks from agricultural, woody, and processed biomasses are investigated after ashing in a temperature range between 200 and 815 °C. The ash composition and their specific distribution inside the particles are studied using X-ray fluorescence (XRF) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDX). Distinct differences are detected in the ashes from various biomasses, indicating that the ash systems can be homogeneous (mainly authigenic origin) or heterogeneous (with significant contributions of detrital/technogenic origin). Using X-ray diffraction (XRD), the formation and transformation of mineral phases are monitored in the ashes produced at various temperatures. The data are then compared to the results of thermochemical calculations. The experimental findings agree almost completely with those calculated using the FactSage™ software package. In connection with the identified mineral phases, the release behavior of the main alkali species, potassium, is monitored as a function of the ashing temperature. Based on these results indicating the ashes' mineral phase composition and their observed heterogeneity, the high-temperature behavior of the ash fusion temperatures (AFT) and ash fusion interval (AFI) between deformation and flow temperature can be ascertained. Finally, based on their ashing behavior, the biomasses’ potential use in thermochemical conversion processes at high temperatures is evaluated.

Suggested Citation

  • Reinmöller, Markus & Schreiner, Marcus & Laabs, Marcel & Scharm, Christoph & Yao, Zhitong & Guhl, Stefan & Neuroth, Manuela & Meyer, Bernd & Gräbner, Martin, 2023. "Formation and transformation of mineral phases in biomass ashes and evaluation of the feedstocks for application in high-temperature processes," Renewable Energy, Elsevier, vol. 210(C), pages 627-639.
    • Handle: RePEc:eee:renene:v:210:y:2023:i:c:p:627-639
    DOI: 10.1016/j.renene.2023.04.072
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123005189
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.04.072?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wu, Dongyin & Wang, Yuhao & Wang, Yang & Li, Sen & Wei, Xiaolin, 2016. "Release of alkali metals during co-firing biomass and coal," Renewable Energy, Elsevier, vol. 96(PA), pages 91-97.
    2. Oladejo, Jumoke M. & Adegbite, Stephen & Pang, Chengheng & Liu, Hao & Lester, Edward & Wu, Tao, 2020. "In-situ monitoring of the transformation of ash upon heating and the prediction of ash fusion behaviour of coal/biomass blends," Energy, Elsevier, vol. 199(C).
    3. Zhang, Heng & Hao, Zhenhua & Li, Junguo & Yang, Xin & Wang, Zhiqing & Liu, Zheyu & Huang, Jiejie & Zhang, Yongqi & Fang, Yitian, 2021. "Effect of coal ash additive on potassium fixation and melting behaviors of the mixture under simulated biomass gasification condition," Renewable Energy, Elsevier, vol. 168(C), pages 806-814.
    4. Situmorang, Yohanes Andre & Zhao, Zhongkai & Yoshida, Akihiro & Abudula, Abuliti & Guan, Guoqing, 2020. "Small-scale biomass gasification systems for power generation (<200 kW class): A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 117(C).
    5. Lim, Jonghun & Kim, Junghwan, 2022. "Optimizing ash deposit removal system to maximize biomass recycling as renewable energy for CO2 reduction," Renewable Energy, Elsevier, vol. 190(C), pages 1006-1017.
    6. Xiao, Ruirui & Chen, Xueli & Wang, Fuchen & Yu, Guangsuo, 2011. "The physicochemical properties of different biomass ashes at different ashing temperature," Renewable Energy, Elsevier, vol. 36(1), pages 244-249.
    7. Xu, Jie & Wang, Ju & Du, Chunhua & Li, Shuaidan & Liu, Xia, 2020. "Understanding fusibility characteristics and flow properties of the biomass and biomass-coal ash samples," Renewable Energy, Elsevier, vol. 147(P1), pages 1352-1357.
    8. Ahlström, Johan M. & Walter, Viktor & Göransson, Lisa & Papadokonstantakis, Stavros, 2022. "The role of biomass gasification in the future flexible power system – BECCS or CCU?," Renewable Energy, Elsevier, vol. 190(C), pages 596-605.
    9. Rodrigues, Renato & Pietzcker, Robert & Fragkos, Panagiotis & Price, James & McDowall, Will & Siskos, Pelopidas & Fotiou, Theofano & Luderer, Gunnar & Capros, Pantelis, 2022. "Narrative-driven alternative roads to achieve mid-century CO2 net neutrality in Europe," Energy, Elsevier, vol. 239(PA).
    10. Wang, Chang’an & Zhou, Lei & Fan, Gaofeng & Yuan, Maobo & Zhao, Lei & Tang, Guantao & Liu, Chengchang & Che, Defu, 2021. "Experimental study on ash morphology, fusibility, and mineral transformation during co-combustion of antibiotic filter residue and biomass," Energy, Elsevier, vol. 217(C).
    11. Wang, Qian & Han, Kuihua & Wang, Jiamin & Gao, Jie & Lu, Chunmei, 2017. "Influence of phosphorous based additives on ash melting characteristics during combustion of biomass briquette fuel," Renewable Energy, Elsevier, vol. 113(C), pages 428-437.
    12. Yao, Xiwen & Zheng, Yan & Zhou, Haodong & Xu, Kaili & Xu, Qingwei & Li, Li, 2020. "Effects of biomass blending, ashing temperature and potassium addition on ash sintering behaviour during co-firing of pine sawdust with a Chinese anthracite," Renewable Energy, Elsevier, vol. 147(P1), pages 2309-2320.
    13. Yao, Xiwen & Zhou, Haodong & Xu, Kaili & Xu, Qingwei & Li, Li, 2020. "Investigation on the fusion characterization and melting kinetics of ashes from co-firing of anthracite and pine sawdust," Renewable Energy, Elsevier, vol. 145(C), pages 835-846.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ziqiang Yang & Fenghai Li & Mingjie Ma & Xuefei Liu & Hongli Fan & Zhenzhu Li & Yong Wang & Yitian Fang, 2023. "Regulation Mechanism of Solid Waste on Ash Fusion Characteristics of Sorghum Straw under O 2 /CO 2 Atmosphere," Energies, MDPI, vol. 16(20), pages 1-17, October.
    2. Li, Fenghai & Zhao, Chaoyue & Fan, Hongli & Xu, Meiling & Guo, Qianqian & Li, Yang & Wu, Lishun & Wang, Tao & Fang, Yitian, 2022. "Ash fusion behaviors of sugarcane bagasse and its modification with sewage sludge addition," Energy, Elsevier, vol. 251(C).
    3. Zhang, Heng & Hao, Zhenhua & Li, Junguo & Yang, Xin & Wang, Zhiqing & Liu, Zheyu & Huang, Jiejie & Zhang, Yongqi & Fang, Yitian, 2021. "Effect of coal ash additive on potassium fixation and melting behaviors of the mixture under simulated biomass gasification condition," Renewable Energy, Elsevier, vol. 168(C), pages 806-814.
    4. Yao, Xiwen & Zhao, Zhicheng & Xu, Kaili & Zhou, Haodong, 2020. "Determination of ash forming characteristics and fouling/slagging behaviours during gasification of masson pine in a fixed-bed gasifier," Renewable Energy, Elsevier, vol. 160(C), pages 1420-1430.
    5. Hariana, & Ghazidin, Hafizh & Putra, Hanafi Prida & Darmawan, Arif & Prabowo, & Hilmawan, Edi & Aziz, Muhammad, 2023. "The effects of additives on deposit formation during co-firing of high-sodium coal with high-potassium and -chlorine biomass," Energy, Elsevier, vol. 271(C).
    6. Jiang, Jiahao & Tie, Yuan & Deng, Lei & Che, Defu, 2022. "Influence of water-washing pretreatment on ash fusibility of biomass," Renewable Energy, Elsevier, vol. 200(C), pages 125-135.
    7. Hariana, & Putra, Hanafi Prida & Prabowo, & Hilmawan, Edi & Darmawan, Arif & Mochida, Keiichi & Aziz, Muhammad, 2023. "Theoretical and experimental investigation of ash-related problems during coal co-firing with different types of biomass in a pulverized coal-fired boiler," Energy, Elsevier, vol. 269(C).
    8. Zhai, Jihua & Burke, Ian T. & Stewart, Douglas I., 2021. "Beneficial management of biomass combustion ashes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    9. Yao, Xiwen & Zhao, Zhicheng & Li, Jishuo & Zhang, Bohan & Zhou, Haodong & Xu, Kaili, 2020. "Experimental investigation of physicochemical and slagging characteristics of inorganic constituents in ash residues from gasification of different herbaceous biomass," Energy, Elsevier, vol. 198(C).
    10. Wang, Qian & Han, Kuihua & Wang, Peifu & Li, Shijie & Zhang, Mingyang, 2020. "Influence of additive on ash and combustion characteristics during biomass combustion under O2/CO2 atmosphere," Energy, Elsevier, vol. 195(C).
    11. Zhou, Haodong & Xu, Kaili & Yao, Xiwen & Li, Jishuo, 2023. "Mineral transformations and molten mechanism during combustion of biomass ash," Renewable Energy, Elsevier, vol. 216(C).
    12. Yao, Xiwen & Zheng, Yan & Zhou, Haodong & Xu, Kaili & Xu, Qingwei & Li, Li, 2020. "Effects of biomass blending, ashing temperature and potassium addition on ash sintering behaviour during co-firing of pine sawdust with a Chinese anthracite," Renewable Energy, Elsevier, vol. 147(P1), pages 2309-2320.
    13. Zhu, Hongqing & Liao, Qi & Hu, Lintao & Xie, Linhao & Qu, Baolin & Gao, Rongxiang, 2023. "Effect of removal of alkali and alkaline earth metals in cornstalk on slagging/fouling and co-combustion characteristics of cornstalk/coal blends for biomass applications," Renewable Energy, Elsevier, vol. 207(C), pages 275-285.
    14. Yao, Xiwen & Zhao, Zhicheng & Chen, Shoukun & Zhou, Haodong & Xu, Kaili, 2020. "Migration and transformation behaviours of ash residues from a typical fixed-bed gasification station for biomass syngas production in China," Energy, Elsevier, vol. 201(C).
    15. Migo-Sumagang, Maria Victoria & Tan, Raymond R. & Aviso, Kathleen B., 2023. "A multi-period model for optimizing negative emission technology portfolios with economic and carbon value discount rates," Energy, Elsevier, vol. 275(C).
    16. Huang, Shengxiong & Lei, Can & Qin, Jie & Yi, Cheng & Chen, Tao & Yao, Lingling & Li, Bo & Wen, Yujiao & Zhou, Zhi & Xia, Mao, 2022. "Properties, kinetics and pyrolysis products distribution of oxidative torrefied camellia shell in different oxygen concentration," Energy, Elsevier, vol. 251(C).
    17. Shan Gu & Maosheng Liu & Xiaoye Liang, 2024. "Analysis of Operational Problems and Improvement Measures for Biomass-Circulating Fluidized Bed Gasifiers," Energies, MDPI, vol. 17(2), pages 1-11, January.
    18. Chapela, Sergio & Cid, Natalia & Porteiro, Jacobo & Míguez, José Luis, 2020. "Numerical transient modelling of the fouling phenomena and its influence on thermal performance in a low-scale biomass shell boiler," Renewable Energy, Elsevier, vol. 161(C), pages 309-318.
    19. Wang, Gang & Zhang, Zhen & Lin, Jianqing, 2024. "Multi-energy complementary power systems based on solar energy: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    20. Adnan, Muflih A. & Hossain, Mohammad M. & Kibria, Md Golam, 2020. "Biomass upgrading to high-value chemicals via gasification and electrolysis: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 162(C), pages 1367-1379.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:210:y:2023:i:c:p:627-639. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.