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Nanocomposites of cobalt benzene tricarboxylic acid MOF with rGO: An efficient and robust electrocatalyst for oxygen evolution reaction (OER)

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  • Yaqoob, Lubna
  • Noor, Tayyaba
  • Iqbal, Naseem
  • Nasir, Habib
  • Sohail, Manzar
  • Zaman, Neelam
  • Usman, Muhammad

Abstract

In this work, electrocatalytic studies of highly active and non-precious metal based Cobalt benzene tricarboxlic acid (Co BTC) metal organic framework (MOF) and its reduced graphene oxide (rGO) composites for oxygen evolution reaction (OER) were performed in an alkaline media by employing cyclic voltammetry. Cobalt based MOF and their rGO composites were solvothermally synthesized. Prepared samples were further characterized for structural and morphological analysis through X-rays diffraction (XRD), scanning electron microscopy (SEM), Fourier transform Infrared (FTIR) spectroscopy and Energy dispersive spectroscopy (EDX) techniques. During CV studies the main emphasis was to observe the effect of rGO concentration on electrochemical response of synthesized materials for OER. Co BTC-5 wt % rGO (Cobalt benzene tricarboxlic acid-reduced graphene oxide) composite with current density of 10 mA/cm2 at over potential 0.29 V vs. RHE proved to be a potential candidate due to its high activity and stability for OER.

Suggested Citation

  • Yaqoob, Lubna & Noor, Tayyaba & Iqbal, Naseem & Nasir, Habib & Sohail, Manzar & Zaman, Neelam & Usman, Muhammad, 2020. "Nanocomposites of cobalt benzene tricarboxylic acid MOF with rGO: An efficient and robust electrocatalyst for oxygen evolution reaction (OER)," Renewable Energy, Elsevier, vol. 156(C), pages 1040-1054.
  • Handle: RePEc:eee:renene:v:156:y:2020:i:c:p:1040-1054
    DOI: 10.1016/j.renene.2020.04.131
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    References listed on IDEAS

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    1. Hongbin Feng & Rui Cheng & Xin Zhao & Xiangfeng Duan & Jinghong Li, 2013. "A low-temperature method to produce highly reduced graphene oxide," Nature Communications, Nature, vol. 4(1), pages 1-8, June.
    2. Hafizi, A. & Rahimpour, M.R. & Hassanajili, Sh., 2016. "Hydrogen production via chemical looping steam methane reforming process: Effect of cerium and calcium promoters on the performance of Fe2O3/Al2O3 oxygen carrier," Applied Energy, Elsevier, vol. 165(C), pages 685-694.
    3. Kara Strickland & Elise Miner & Qingying Jia & Urszula Tylus & Nagappan Ramaswamy & Wentao Liang & Moulay-Tahar Sougrati & Frédéric Jaouen & Sanjeev Mukerjee, 2015. "Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
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    Cited by:

    1. Muhammad Usman & Muhammad Humayun & Syed Shaheen Shah & Habib Ullah & Asif A Tahir & Abbas Khan & Habib Ullah, 2021. "Bismuth-Graphene Nanohybrids: Synthesis, Reaction Mechanisms, and Photocatalytic Applications—A Review," Energies, MDPI, vol. 14(8), pages 1-36, April.
    2. Myung Jun Lee & Junyeop Kim & Jaeun Kang & Hyewon Shin & Junghwan Do & Seong Jung Kwon, 2021. "Electrocatalytic Activity of Reduced Graphene Oxide Supported Cobalt Cinnamate for Oxygen Evolution Reaction," Energies, MDPI, vol. 14(16), pages 1-11, August.

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