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Transesterification of palm oil into biodiesel using ChOH ionic liquid in a microwave heated continuous flow reactor

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  • Phromphithak, Sanphawat
  • Meepowpan, Puttinan
  • Shimpalee, Sirivatch
  • Tippayawong, Nakorn

Abstract

Palm oil is one of the most rapidly expanding equatorial crops, which is suitable for feedstock of biodiesel production. In this work, production of methyl esters from palm oil transesterification in a microwave heated continuous flow system was investigated. Choline hydroxide (ChOH) was employed as a green ionic liquid catalyst. The oil to methanol molar ratio, flow rate, power of the microwave, and catalyst loading were varied and optimized by response surface methodology combined with the Box-Behnken design of experiments for maximum biodiesel yield. The ionic liquid proved to be effective in tranesterification of palm oil. The quadratic regression model can be used to forecast the resulting methyl esters content. The optimum condition was identified at molar ratio between oil to methanol of 1:13.2, flow rate of 20 ml/min, microwave power of 800 W and catalyst loading of 6% (w/w), giving the methyl esters content almost 90% in EN 14103 standard test. In addition, most properties of the biodiesel considered were observed to meet the fuel specifications from the ASTM D6751 and Thai standards (community use). Reusability of the ionic liquid for several times was demonstrated before it was contaminated and decomposed, leading to a marked drop in catalytic activity.

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  • Phromphithak, Sanphawat & Meepowpan, Puttinan & Shimpalee, Sirivatch & Tippayawong, Nakorn, 2020. "Transesterification of palm oil into biodiesel using ChOH ionic liquid in a microwave heated continuous flow reactor," Renewable Energy, Elsevier, vol. 154(C), pages 925-936.
  • Handle: RePEc:eee:renene:v:154:y:2020:i:c:p:925-936
    DOI: 10.1016/j.renene.2020.03.080
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    1. Dehghan, Leila & Golmakani, Mohammad-Taghi & Hosseini, Seyed Mohammad Hashem, 2019. "Optimization of microwave-assisted accelerated transesterification of inedible olive oil for biodiesel production," Renewable Energy, Elsevier, vol. 138(C), pages 915-922.
    2. Nayak, Milap G. & Vyas, Amish P., 2019. "Optimization of microwave-assisted biodiesel production from Papaya oil using response surface methodology," Renewable Energy, Elsevier, vol. 138(C), pages 18-28.
    3. Venu, Harish & Subramani, Lingesan & Raju, V. Dhana, 2019. "Emission reduction in a DI diesel engine using exhaust gas recirculation (EGR) of palm biodiesel blended with TiO2 nano additives," Renewable Energy, Elsevier, vol. 140(C), pages 245-263.
    4. Motasemi, F. & Ani, F.N., 2012. "A review on microwave-assisted production of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4719-4733.
    5. Murillo, Gabriel & Ali, Sameh S. & Sun, Jianzhong & Yan, Yunjun & Bartocci, Pietro & El-Zawawy, Nessma & Azab, Maha & He, Yaojia & Fantozzi, Francesco, 2019. "Ultrasonic emulsification assisted immobilized Burkholderia cepacia lipase catalyzed transesterification of soybean oil for biodiesel production in a novel reactor design," Renewable Energy, Elsevier, vol. 135(C), pages 1025-1034.
    6. Troter, Dragan Z. & Todorović, Zoran B. & Đokić-Stojanović, Dušica R. & Stamenković, Olivera S. & Veljković, Vlada B., 2016. "Application of ionic liquids and deep eutectic solvents in biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 473-500.
    7. Chakraborty, Rajat & Gupta, Abhishek.K. & Chowdhury, Ratul, 2014. "Conversion of slaughterhouse and poultry farm animal fats and wastes to biodiesel: Parametric sensitivity and fuel quality assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 120-134.
    8. Ding, Hui & Ye, Wei & Wang, Yongqiang & Wang, Xianqin & Li, Lujun & Liu, Dan & Gui, Jianzhou & Song, Chunfeng & Ji, Na, 2018. "Process intensification of transesterification for biodiesel production from palm oil: Microwave irradiation on transesterification reaction catalyzed by acidic imidazolium ionic liquids," Energy, Elsevier, vol. 144(C), pages 957-967.
    9. Fan, Mingming & Huang, Jianglei & Yang, Jing & Zhang, Pingbo, 2013. "Biodiesel production by transesterification catalyzed by an efficient choline ionic liquid catalyst," Applied Energy, Elsevier, vol. 108(C), pages 333-339.
    10. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
    11. Murugesan, A. & Umarani, C. & Subramanian, R. & Nedunchezhian, N., 2009. "Bio-diesel as an alternative fuel for diesel engines--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(3), pages 653-662, April.
    12. Mohadesi, Majid & Aghel, Babak & Maleki, Mahmoud & Ansari, Ahmadreza, 2019. "Production of biodiesel from waste cooking oil using a homogeneous catalyst: Study of semi-industrial pilot of microreactor," Renewable Energy, Elsevier, vol. 136(C), pages 677-682.
    13. Choedkiatsakul, I. & Ngaosuwan, K. & Assabumrungrat, S. & Mantegna, S. & Cravotto, G., 2015. "Biodiesel production in a novel continuous flow microwave reactor," Renewable Energy, Elsevier, vol. 83(C), pages 25-29.
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