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Biodiesel production by transesterification catalyzed by an efficient choline ionic liquid catalyst

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  • Fan, Mingming
  • Huang, Jianglei
  • Yang, Jing
  • Zhang, Pingbo

Abstract

The catalytic synthesis of biodiesel from soybean oil by transesterification over basic ionic liquid catalysts had been studied at atmospheric pressure. Choline hydroxide (ChOH) catalyst exhibited better catalytic activity compared with other basic ionic liquid catalysts, and methanol is the best alcohol for biodiesel synthesis. The suitable molar ratio of methanol and soybean oil was 9:1, and the optimum catalyst dosage existed for catalytic activity, which was about 4wt.% (without soap formation). The study also revealed that the appropriate reaction temperature was about 60°C, and the suitable reaction time was 2.5h on the basis of biodiesel yield. The reusability test showed that ChOH catalyst had perfect utility for repeated use. By basicity test, it was found that the basic ionic liquid ChOH possessed better basicity in methanol solution. The catalytic reaction mechanism was illuminated by the interaction between the methoxyl group after activating and the carbonyl group of the triglyceride, which has been investigated using quasi in situ infrared spectroscopy.

Suggested Citation

  • Fan, Mingming & Huang, Jianglei & Yang, Jing & Zhang, Pingbo, 2013. "Biodiesel production by transesterification catalyzed by an efficient choline ionic liquid catalyst," Applied Energy, Elsevier, vol. 108(C), pages 333-339.
    • Handle: RePEc:eee:appene:v:108:y:2013:i:c:p:333-339
    DOI: 10.1016/j.apenergy.2013.03.063
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    3. Gholami, Ali & Pourfayaz, Fathollah & Hajinezhad, Ahmad & Mohadesi, Majid, 2019. "Biodiesel production from Norouzak (Salvia leriifolia) oil using choline hydroxide catalyst in a microchannel reactor," Renewable Energy, Elsevier, vol. 136(C), pages 993-1001.
    4. Cao, Leichang & Wang, Jieni & Liu, Kuojin & Han, Sheng, 2014. "Ethyl acetoacetate: A potential bio-based diluent for improving the cold flow properties of biodiesel from waste cooking oil," Applied Energy, Elsevier, vol. 114(C), pages 18-21.
    5. Zhang, Pingbo & Liu, Peng & Fan, Mingming & Jiang, Pingping & Haryono, Agus, 2021. "High-performance magnetite nanoparticles catalyst for biodiesel production: Immobilization of 12-tungstophosphoric acid on SBA-15 works effectively," Renewable Energy, Elsevier, vol. 175(C), pages 244-252.
    6. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    7. Zhang, Pingbo & Liu, Yanlei & Fan, Mingming & Jiang, Pingping, 2016. "Catalytic performance of a novel amphiphilic alkaline ionic liquid for biodiesel production: Influence of basicity and conductivity," Renewable Energy, Elsevier, vol. 86(C), pages 99-105.
    8. Phromphithak, Sanphawat & Meepowpan, Puttinan & Shimpalee, Sirivatch & Tippayawong, Nakorn, 2020. "Transesterification of palm oil into biodiesel using ChOH ionic liquid in a microwave heated continuous flow reactor," Renewable Energy, Elsevier, vol. 154(C), pages 925-936.
    9. Qian, Kun & Shen, Xiang & Wang, Yanxin & Gao, Qiang & Ding, Hongwei, 2015. "In-situ transesterification of Jatropha oil over an efficient solid alkali using low leaching component supported on industrial silica gel," Energy, Elsevier, vol. 93(P2), pages 2251-2257.
    10. A. K. Azad, 2017. "Biodiesel from Mandarin Seed Oil: A Surprising Source of Alternative Fuel," Energies, MDPI, vol. 10(11), pages 1-22, October.
    11. Troter, Dragan Z. & Todorović, Zoran B. & Đokić-Stojanović, Dušica R. & Stamenković, Olivera S. & Veljković, Vlada B., 2016. "Application of ionic liquids and deep eutectic solvents in biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 473-500.
    12. Ibrahim, Muna Hassan & Hayyan, Maan & Hashim, Mohd Ali & Hayyan, Adeeb, 2017. "The role of ionic liquids in desulfurization of fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 1534-1549.

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