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New nanocomposite membranes based on sulfonated poly (phthalazinone ether ketone) and Fe3O4@SiO2@ resorcinol–aldehyde–SO3H for PEMFCs

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  • Hooshyari, Khadijeh
  • Heydari, Samira
  • Beydaghi, Hossein
  • Rajabi, Hamid Reza

Abstract

The aim of this study is improving the proton conductivity and fuel cell performance of sulfonated poly (phthalazinone ether ketone) (SPPEK) based membranes through using the spherically shaped core@double-shell acidic nanoparticles (Fe3O4@SiO2@RF–SO3H) [RF:resorcinol–formaldehyde resin]. The Fe3O4@SiO2@RF–SO3H nanoparticles will affect the phase separation, and finally, act as crosslinkers to promote the membrane stability and water retention. The electrochemical and mechanical performances of produced membranes are remarkable, exhibiting high proton conductivity and power density with great life time over a wide temperature range. The nanocomposite membranes showed the highest proton conductivity of 127 mS/cm at 90 °C and 98% RH. This result due to the -SO3H groups of Fe3O4@SiO2@RF–SO3H nanoparticles and formation of more hydrogen bonds, which led to improve proton transfer through membrane via both Grotthus and Vehicle mechanism. The desirable power density of 0.52 W/cm2 at 0.5 V and 90 °C in optimum nanocomposite membrane approve their potential application in the fuel cells.

Suggested Citation

  • Hooshyari, Khadijeh & Heydari, Samira & Beydaghi, Hossein & Rajabi, Hamid Reza, 2022. "New nanocomposite membranes based on sulfonated poly (phthalazinone ether ketone) and Fe3O4@SiO2@ resorcinol–aldehyde–SO3H for PEMFCs," Renewable Energy, Elsevier, vol. 186(C), pages 115-125.
    • Handle: RePEc:eee:renene:v:186:y:2022:i:c:p:115-125
    DOI: 10.1016/j.renene.2021.12.074
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    References listed on IDEAS

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    1. Yun-Xiao Wang & Jianping Yang & Shu-Lei Chou & Hua Kun Liu & Wei-xian Zhang & Dongyuan Zhao & Shi Xue Dou, 2015. "Uniform yolk-shell iron sulfide–carbon nanospheres for superior sodium–iron sulfide batteries," Nature Communications, Nature, vol. 6(1), pages 1-9, December.
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    3. Xu, Guoxiao & Wu, Zhiguang & Wei, Zenglv & Zhang, Wenjie & Wu, Junli & Li, Ying & Li, Jing & Qu, Konggang & Cai, Weiwei, 2020. "Non-destructive fabrication of Nafion/silica composite membrane via swelling-filling modification strategy for high temperature and low humidity PEM fuel cell," Renewable Energy, Elsevier, vol. 153(C), pages 935-939.
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    Cited by:

    1. Fan, Lixin & Liu, Yang & Luo, Xiaobing & Tu, Zhengkai & Chan, Siew Hwa, 2023. "Comparison and evaluation of mega watts proton exchange membrane fuel cell combined heat and power system under different waste heat recovery methods," Renewable Energy, Elsevier, vol. 210(C), pages 295-305.

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