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Synthesis and properties of novel cross-linked composite sulfonated poly (aryl ether ketone sulfone) containing multiple sulfonic side chains for high-performance proton exchange membranes

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  • Xu, Jingmei
  • Zhang, Zhenguo
  • Yang, Kai
  • Zhang, Huixuan
  • Wang, Zhe

Abstract

The synthesis and properties of novel cross-linked composite sulfonated poly (aryl ether ketone sulfone) containing multiple sulfonic side chains as proton exchange membranes were investigated. The multiple side-chain membranes were prepared by direct polycondensation and simple free radical reaction. The cross-linked composite membranes were prepared by solvent coating method. The prepared membranes showed lower water absorption and swelling ratio than that of Nafion 117. The S-Am-2.0/C exhibited the highest proton conductivity of 0.135 S cm−1 at 80 °C, while its swelling ratio was only 3.59% at the same temperature. Much lower methanol permeability coefficients in the range of 3.11 × 10−8 cm2 s−1–7.25 × 10−7 cm2 s−1 compared to Nafion 117 (2.29 × 10−6 cm2 s−1) were also observed for the prepared membranes. Moreover, the S-Am-2.0/C exhibited higher peak power density (121.09 mW cm−2) than that of main-chain type C-SPAEKS membrane (66.65 mW cm−2). The results indicate that the cross-linked composite membranes are good candidate for fuel cells.

Suggested Citation

  • Xu, Jingmei & Zhang, Zhenguo & Yang, Kai & Zhang, Huixuan & Wang, Zhe, 2019. "Synthesis and properties of novel cross-linked composite sulfonated poly (aryl ether ketone sulfone) containing multiple sulfonic side chains for high-performance proton exchange membranes," Renewable Energy, Elsevier, vol. 138(C), pages 1104-1113.
    • Handle: RePEc:eee:renene:v:138:y:2019:i:c:p:1104-1113
    DOI: 10.1016/j.renene.2019.02.042
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    References listed on IDEAS

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    1. Ahmadian-Alam, Leila & Mahdavi, Hossein, 2018. "A novel polysulfone-based ternary nanocomposite membrane consisting of metal-organic framework and silica nanoparticles: As proton exchange membrane for polymer electrolyte fuel cells," Renewable Energy, Elsevier, vol. 126(C), pages 630-639.
    2. Li, Jing & Xu, Guoxiao & Luo, Xingying & Xiong, Jie & Liu, Zhao & Cai, Weiwei, 2018. "Effect of nano-size of functionalized silica on overall performance of swelling-filling modified Nafion membrane for direct methanol fuel cell application," Applied Energy, Elsevier, vol. 213(C), pages 408-414.
    3. Ozden, Adnan & Shahgaldi, Samaneh & Li, Xianguo & Hamdullahpur, Feridun, 2018. "A graphene-based microporous layer for proton exchange membrane fuel cells: Characterization and performance comparison," Renewable Energy, Elsevier, vol. 126(C), pages 485-494.
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