IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v150y2020icp777-785.html
   My bibliography  Save this article

Insight into structural features of soluble portions from cellulose, cellobiose and monosaccharide methanolysis by GC/MS and ESI FTICRMS

Author

Listed:
  • Li, Zhan-Ku
  • Yan, Hong-Lei
  • Yan, Jing-Chong
  • Lei, Zhi-Ping
  • Ren, Shi-Biao
  • Wang, Zhi-Cai
  • Kang, Shi-Gang
  • Tian, Yu-Jiao
  • Pan, Chun-Xiu
  • Shui, Heng-Fu

Abstract

Methanolysis of biomass has attracted increasing attention due to it has some advantages, such as low critical points and strong hydrogen donation ability. In this paper, methanolysis of cellulose, cellobiose (sucrose), and monosaccharide (glucose) were performed to obtain methanol-soluble portions (MSPs). The relatively volatile or less polar species in the MSPs were analyzed with a gas chromatograph/mass spectrometer (GC/MS), and the polar species were identified with a negative-ion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometer (FTICRMS). According to analysis with GC/MS, the MSPs include ethers, esters, ketones, acids, sugars, phenols, and furans. The analysis with FTICRMS shows that the polar compounds in the MSPs are O1–O15 class species with 1–14 double bond equivalent (DBE) and 5–35 carbon atom number (CAN). The most abundant class species in MSPs from cellulose, sucrose, and glucose methanolysis are O5, O7, and O7, respectively. The species in MSPs from sucrose and glucose methanolysis center at higher DBE value and more CAN than those in MSP from cellulose methanolysis. Meanwhile, the oxygen atom number of O4–O10 class species in the MSPs were negatively correlated with the average DBE value. The results indicate that condensation intensively proceeded with the specific regularity during sucrose and glucose methanolysis.

Suggested Citation

  • Li, Zhan-Ku & Yan, Hong-Lei & Yan, Jing-Chong & Lei, Zhi-Ping & Ren, Shi-Biao & Wang, Zhi-Cai & Kang, Shi-Gang & Tian, Yu-Jiao & Pan, Chun-Xiu & Shui, Heng-Fu, 2020. "Insight into structural features of soluble portions from cellulose, cellobiose and monosaccharide methanolysis by GC/MS and ESI FTICRMS," Renewable Energy, Elsevier, vol. 150(C), pages 777-785.
    • Handle: RePEc:eee:renene:v:150:y:2020:i:c:p:777-785
    DOI: 10.1016/j.renene.2020.01.032
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120300331
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.01.032?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Gao, Ying & Wang, Xian-Hua & Yang, Hai-Ping & Chen, Han-Ping, 2012. "Characterization of products from hydrothermal treatments of cellulose," Energy, Elsevier, vol. 42(1), pages 457-465.
    2. Li, Wei-Gang & Zhao, Wei & Liu, Hao-Miao & Ao, Lei & Liu, Kai-Shuai & Guan, Yin-Shuang & Zai, Shi-Feng & Chen, Shang-Long & Zong, Zhi-Min & Wei, Xian-Yong, 2018. "Supercritical ethanolysis of wheat stalk over calcium oxide," Renewable Energy, Elsevier, vol. 120(C), pages 300-305.
    3. Gollakota, A.R.K. & Kishore, Nanda & Gu, Sai, 2018. "A review on hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1378-1392.
    4. Brand, Steffen & Kim, Jaehoon, 2015. "Liquefaction of major lignocellulosic biomass constituents in supercritical ethanol," Energy, Elsevier, vol. 80(C), pages 64-74.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Zhan-Ku & Cheng, Jin-Yuan & Yan, Hong-Lei & Yan, Jing-Chong & Lei, Zhi-Ping & Ren, Shi-Biao & Wang, Zhi-Cai & Kang, Shi-Gang & Shui, Heng-Fu, 2021. "Pretreatment of sweet sorghum stalk with aqueous hydrogen peroxide for enhancing methanolysis and property of the bio-oil," Renewable Energy, Elsevier, vol. 175(C), pages 1127-1136.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ankit Mathanker & Snehlata Das & Deepak Pudasainee & Monir Khan & Amit Kumar & Rajender Gupta, 2021. "A Review of Hydrothermal Liquefaction of Biomass for Biofuels Production with a Special Focus on the Effect of Process Parameters, Co-Solvents, and Extraction Solvents," Energies, MDPI, vol. 14(16), pages 1-60, August.
    2. Prajitno, Hermawan & Park, Jongkeun & Ryu, Changkook & Park, Ho Young & Lim, Hyun Soo & Kim, Jaehoon, 2018. "Effects of solvent participation and controlled product separation on biomass liquefaction: A case study of sewage sludge," Applied Energy, Elsevier, vol. 218(C), pages 402-416.
    3. Wu, Xiao-Fei & Yin, Shuang-Shuang & Zhou, Qian & Li, Ming-Fei & Peng, Feng & Xiao, Xiao, 2019. "Subcritical liquefaction of lignocellulose for the production of bio-oils in ethanol/water system," Renewable Energy, Elsevier, vol. 136(C), pages 865-872.
    4. Li, Qingyin & Zhang, Shu & Wang, Yi & Xiang, Jun & Hu, Song & Yuan, Xiangzhou & Gholizadeh, Mortaza & Hu, Xun, 2021. "Ionic liquid coupled with nickel salt for enhancing the hydro-liquefaction efficiency of the major biomass components," Renewable Energy, Elsevier, vol. 175(C), pages 296-306.
    5. Genel, Salih & Durak, Halil & Durak, Emre Demirer & Güneş, Hasret & Genel, Yaşar, 2023. "Hydrothermal liquefaction of biomass with molybdenum, aluminum, cobalt metal powder catalysts and evaluation of wastewater by fungus cultivation," Renewable Energy, Elsevier, vol. 203(C), pages 20-32.
    6. Gao, Pin & Zhou, Yiyuan & Meng, Fang & Zhang, Yihui & Liu, Zhenhong & Zhang, Wenqi & Xue, Gang, 2016. "Preparation and characterization of hydrochar from waste eucalyptus bark by hydrothermal carbonization," Energy, Elsevier, vol. 97(C), pages 238-245.
    7. Mei Yin Ong & Nor-Insyirah Syahira Abdul Latif & Hui Yi Leong & Bello Salman & Pau Loke Show & Saifuddin Nomanbhay, 2019. "Characterization and Analysis of Malaysian Macroalgae Biomass as Potential Feedstock for Bio-Oil Production," Energies, MDPI, vol. 12(18), pages 1-14, September.
    8. Sharma, Nishesh & Jaiswal, Krishna Kumar & Kumar, Vinod & Vlaskin, Mikhail S. & Nanda, Manisha & Rautela, Indra & Tomar, Mahipal Singh & Ahmad, Waseem, 2021. "Effect of catalyst and temperature on the quality and productivity of HTL bio-oil from microalgae: A review," Renewable Energy, Elsevier, vol. 174(C), pages 810-822.
    9. Jiheon Jun & Yi-Feng Su & James R. Keiser & John E. Wade & Michael D. Kass & Jack R. Ferrell & Earl Christensen & Mariefel V. Olarte & Dino Sulejmanovic, 2022. "Corrosion Compatibility of Stainless Steels and Nickel in Pyrolysis Biomass-Derived Oil at Elevated Storage Temperatures," Sustainability, MDPI, vol. 15(1), pages 1-16, December.
    10. Awasthi, Mukesh Kumar & Sarsaiya, Surendra & Wainaina, Steven & Rajendran, Karthik & Kumar, Sumit & Quan, Wang & Duan, Yumin & Awasthi, Sanjeev Kumar & Chen, Hongyu & Pandey, Ashok & Zhang, Zengqiang , 2019. "A critical review of organic manure biorefinery models toward sustainable circular bioeconomy: Technological challenges, advancements, innovations, and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 115-131.
    11. Kumar, R. & Strezov, V., 2021. "Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    12. Ibrahim Shaba Mohammed & Risu Na & Keisuke Kushima & Naoto Shimizu, 2020. "Investigating the Effect of Processing Parameters on the Products of Hydrothermal Carbonization of Corn Stover," Sustainability, MDPI, vol. 12(12), pages 1-21, June.
    13. Kawale, Harshal D. & Kishore, Nanda, 2019. "Production of hydrocarbons from a green algae (Oscillatoria) with exploration of its fuel characteristics over different reaction atmospheres," Energy, Elsevier, vol. 178(C), pages 344-355.
    14. Tahir H. Seehar & Saqib S. Toor & Ayaz A. Shah & Thomas H. Pedersen & Lasse A. Rosendahl, 2020. "Biocrude Production from Wheat Straw at Sub and Supercritical Hydrothermal Liquefaction," Energies, MDPI, vol. 13(12), pages 1-18, June.
    15. Andrade Díaz, Christhel & Albers, Ariane & Zamora-Ledezma, Ezequiel & Hamelin, Lorie, 2024. "The interplay between bioeconomy and the maintenance of long-term soil organic carbon stock in agricultural soils: A systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    16. Siti Zaharah Roslan & Siti Fairuz Zainudin & Alijah Mohd Aris & Khor Bee Chin & Mohibah Musa & Ahmad Rafizan Mohamad Daud & Syed Shatir A. Syed Hassan, 2023. "Hydrothermal Carbonization of Sewage Sludge into Solid Biofuel: Influences of Process Conditions on the Energetic Properties of Hydrochar," Energies, MDPI, vol. 16(5), pages 1-16, March.
    17. Djukić-Vuković, A. & Mladenović, D. & Ivanović, J. & Pejin, J. & Mojović, L., 2019. "Towards sustainability of lactic acid and poly-lactic acid polymers production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 238-252.
    18. Liu, Quan & Zhang, Guanyu & Liu, Mingyang & Kong, Ge & Xu, Ruolan & Han, Lujia & Zhang, Xuesong, 2022. "Fast hydrothermal liquefaction coupled with homogeneous catalysts to valorize livestock manure for enhanced biocrude oil and hydrochar production," Renewable Energy, Elsevier, vol. 198(C), pages 521-533.
    19. Mariusz Wądrzyk & Łukasz Korzeniowski & Marek Plata & Rafał Janus & Marek Lewandowski & Grzegorz Borówka & Przemysław Maziarka, 2023. "Solvothermal Liquefaction of Blackcurrant Pomace in the Water-Monohydroxy Alcohol Solvent System," Energies, MDPI, vol. 16(3), pages 1-15, January.
    20. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:150:y:2020:i:c:p:777-785. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.