IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v175y2021icp1127-1136.html
   My bibliography  Save this article

Pretreatment of sweet sorghum stalk with aqueous hydrogen peroxide for enhancing methanolysis and property of the bio-oil

Author

Listed:
  • Li, Zhan-Ku
  • Cheng, Jin-Yuan
  • Yan, Hong-Lei
  • Yan, Jing-Chong
  • Lei, Zhi-Ping
  • Ren, Shi-Biao
  • Wang, Zhi-Cai
  • Kang, Shi-Gang
  • Shui, Heng-Fu

Abstract

Alcoholysis is a promising approach for converting biomass into fuels and/or chemicals under mild conditions. However, the effect of pretreatment on biomass alcoholysis was rarely reported. Herein, the effect of pretreatment with H2O2 on sweet sorghum stalk (SSS) methanolysis was examined. The results show that the pretreatment could markedly improve the bio-oil (BO) yield and decrease the appropriate temperature for obtaining maximum BO yield. The appropriate temperature for pretreated SSS methanolysis was determined to be 280 °C and the maximum BO yield is 44 wt%. In addition, higher heating values of the BOs were also enhanced based on elemental analysis. According to analysis with gas chromatograph/mass spectrometer, phenolic compounds, esters, and sugars are predominant in the BOs, and the yield of phenolic compounds significantly increased from 91.75 to 111.68 mg . g−1 by the pretreatment. Moreover, polar species in the BOs decreased and deoxygenation occurred during pretreated SSS methanolysis. Analyses with scanning electron microscope and N2 physisorption reveal that pretreated SSS has more grooves and higher specific surface area and anomalous porosity than SSS. According to analyses with Fourier transform infrared spectrometer and X-ray photoelectron spectrometer, oxygen functional groups mainly in the forms of CO and COO were introduced into SSS by the pretreatment. The changes of physical and chemical structures should be responsible for enhancing SSS methanolysis and property of the BO.

Suggested Citation

  • Li, Zhan-Ku & Cheng, Jin-Yuan & Yan, Hong-Lei & Yan, Jing-Chong & Lei, Zhi-Ping & Ren, Shi-Biao & Wang, Zhi-Cai & Kang, Shi-Gang & Shui, Heng-Fu, 2021. "Pretreatment of sweet sorghum stalk with aqueous hydrogen peroxide for enhancing methanolysis and property of the bio-oil," Renewable Energy, Elsevier, vol. 175(C), pages 1127-1136.
    • Handle: RePEc:eee:renene:v:175:y:2021:i:c:p:1127-1136
    DOI: 10.1016/j.renene.2021.05.052
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S096014812100728X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.05.052?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ortiz, Leandro Rodriguez & Torres, Erick & Zalazar, Daniela & Zhang, Huili & Rodriguez, Rosa & Mazza, Germán, 2020. "Influence of pyrolysis temperature and bio-waste composition on biochar characteristics," Renewable Energy, Elsevier, vol. 155(C), pages 837-847.
    2. Morone, Amruta & Sharma, Ganesh & Sharma, Abhinav & Chakrabarti, Tapan & Pandey, R.A., 2018. "Evaluation, applicability and optimization of advanced oxidation process for pretreatment of rice straw and its effect on cellulose digestibility," Renewable Energy, Elsevier, vol. 120(C), pages 88-97.
    3. Li, Zhan-Ku & Yan, Hong-Lei & Yan, Jing-Chong & Lei, Zhi-Ping & Ren, Shi-Biao & Wang, Zhi-Cai & Kang, Shi-Gang & Tian, Yu-Jiao & Pan, Chun-Xiu & Shui, Heng-Fu, 2020. "Insight into structural features of soluble portions from cellulose, cellobiose and monosaccharide methanolysis by GC/MS and ESI FTICRMS," Renewable Energy, Elsevier, vol. 150(C), pages 777-785.
    4. Li, Wei-Gang & Zhao, Wei & Liu, Hao-Miao & Ao, Lei & Liu, Kai-Shuai & Guan, Yin-Shuang & Zai, Shi-Feng & Chen, Shang-Long & Zong, Zhi-Min & Wei, Xian-Yong, 2018. "Supercritical ethanolysis of wheat stalk over calcium oxide," Renewable Energy, Elsevier, vol. 120(C), pages 300-305.
    5. Perkins, Greg & Batalha, Nuno & Kumar, Adarsh & Bhaskar, Thallada & Konarova, Muxina, 2019. "Recent advances in liquefaction technologies for production of liquid hydrocarbon fuels from biomass and carbonaceous wastes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    6. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Pio, D.T. & Tarelho, L.A.C. & Pinto, P.C.R., 2020. "Gasification-based biorefinery integration in the pulp and paper industry: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    2. Zalazar-Garcia, Daniela & Fernandez, Anabel & Rodriguez-Ortiz, Leandro & Torres, Erick & Reyes-Urrutia, Andrés & Echegaray, Marcelo & Rodriguez, Rosa & Mazza, Germán, 2022. "Exergo-ecological analysis and life cycle assessment of agro-wastes using a combined simulation approach based on Cape-Open to Cape-Open (COCO) and SimaPro free-software," Renewable Energy, Elsevier, vol. 201(P1), pages 60-71.
    3. Torres, Erick & Rodriguez-Ortiz, Leandro A. & Zalazar, Daniela & Echegaray, Marcelo & Rodriguez, Rosa & Zhang, Huili & Mazza, Germán, 2020. "4-E (environmental, economic, energetic and exergetic) analysis of slow pyrolysis of lignocellulosic waste," Renewable Energy, Elsevier, vol. 162(C), pages 296-307.
    4. Zhao, Xiqiang & Zhou, Xing & Wang, Guoxiu & Zhou, Ping & Wang, Wenlong & Song, Zhanlong, 2022. "Evaluating the effect of torrefaction on the pyrolysis of biomass and the biochar catalytic performance on dry reforming of methane," Renewable Energy, Elsevier, vol. 192(C), pages 313-325.
    5. Ayub, Yousaf & Ren, Jingzheng & Shi, Tao & Shen, Weifeng & He, Chang, 2023. "Poultry litter valorization: Development and optimization of an electro-chemical and thermal tri-generation process using an extreme gradient boosting algorithm," Energy, Elsevier, vol. 263(PC).
    6. Elhambakhsh, Abbas & Van Duc Long, Nguyen & Lamichhane, Pradeep & Hessel, Volker, 2023. "Recent progress and future directions in plasma-assisted biomass conversion to hydrogen," Renewable Energy, Elsevier, vol. 218(C).
    7. Zhao, Ming & Memon, Muhammad Zaki & Ji, Guozhao & Yang, Xiaoxiao & Vuppaladadiyam, Arun K. & Song, Yinqiang & Raheem, Abdul & Li, Jinhui & Wang, Wei & Zhou, Hui, 2020. "Alkali metal bifunctional catalyst-sorbents enabled biomass pyrolysis for enhanced hydrogen production," Renewable Energy, Elsevier, vol. 148(C), pages 168-175.
    8. Zang, Guiyan & Zhang, Jianan & Jia, Junxi & Lora, Electo Silva & Ratner, Albert, 2020. "Life cycle assessment of power-generation systems based on biomass integrated gasification combined cycles," Renewable Energy, Elsevier, vol. 149(C), pages 336-346.
    9. Kumar, R. & Strezov, V., 2021. "Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    10. Gupta, Shubhi & Gupta, Goutam Kishore & Mondal, Monoj Kumar, 2019. "Slow pyrolysis of chemically treated walnut shell for valuable products: Effect of process parameters and in-depth product analysis," Energy, Elsevier, vol. 181(C), pages 665-676.
    11. Adnan, Muflih A. & Hossain, Mohammad M. & Kibria, Md Golam, 2020. "Biomass upgrading to high-value chemicals via gasification and electrolysis: A thermodynamic analysis," Renewable Energy, Elsevier, vol. 162(C), pages 1367-1379.
    12. Lech Nowicki & Dorota Siuta & Maciej Markowski, 2020. "Pyrolysis of Rapeseed Oil Press Cake and Steam Gasification of Solid Residues," Energies, MDPI, vol. 13(17), pages 1-12, August.
    13. Pérez, Nestor Proenza & Pedroso, Daniel Travieso & Machin, Einara Blanco & Antunes, Julio Santana & Tuna, Celso Eduardo & Silveira, José Luz, 2019. "Geometrical characteristics of sugarcane bagasse for being used as fuel in fluidized bed technologies," Renewable Energy, Elsevier, vol. 143(C), pages 1210-1224.
    14. Liu, Hui & Liu, Jingyong & Huang, Hongyi & Evrendilek, Fatih & Wen, Shaoting & Li, Weixin, 2021. "Optimizing bioenergy and by-product outputs from durian shell pyrolysis," Renewable Energy, Elsevier, vol. 164(C), pages 407-418.
    15. Pang, Yunji & Wu, Yuting & Chen, Yisheng & Luo, Fuliang & Chen, Junjun, 2020. "Degradation effect of Ce/Al2O3 catalyst on pyrolysis volatility of pine," Renewable Energy, Elsevier, vol. 162(C), pages 134-143.
    16. Burov, Nikita O. & Savelenko, Vsevolod D. & Ershov, Mikhail A. & Vikhritskaya, Anastasia O. & Tikhomirova, Ekaterina O. & Klimov, Nikita A. & Kapustin, Vladimir M. & Chernysheva, Elena A. & Sereda, Al, 2023. "Knowledge contribution from science to technology in the conceptualization model to produce sustainable aviation fuels from lignocellulosic biomass," Renewable Energy, Elsevier, vol. 215(C).
    17. Lacrimioara Senila & Ioan Tenu & Petru Carlescu & Daniela Alexandra Scurtu & Eniko Kovacs & Marin Senila & Oana Cadar & Marius Roman & Diana Elena Dumitras & Cecilia Roman, 2022. "Characterization of Biobriquettes Produced from Vineyard Wastes as a Solid Biofuel Resource," Agriculture, MDPI, vol. 12(3), pages 1-13, February.
    18. Kim, D. & Hadigheh, S.A., 2024. "Oxidative pyrolysis of biosolid: Air concentration effects on biochar formation and kinetics," Renewable Energy, Elsevier, vol. 224(C).
    19. Tahereh Soleymani Angili & Katarzyna Grzesik & Wojciech Jerzak, 2023. "Comparative Life Cycle Assessment of Catalytic Intermediate Pyrolysis of Rapeseed Meal," Energies, MDPI, vol. 16(4), pages 1-16, February.
    20. Polin, Joseph P. & Peterson, Chad A. & Whitmer, Lysle E. & Smith, Ryan G. & Brown, Robert C., 2019. "Process intensification of biomass fast pyrolysis through autothermal operation of a fluidized bed reactor," Applied Energy, Elsevier, vol. 249(C), pages 276-285.

    More about this item

    Keywords

    Biomass; Pretreatment; H2O2; Methanolysis; Bio-oil;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:175:y:2021:i:c:p:1127-1136. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.