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The role of viscosity in the fluorescence behavior of the diesel/biodiesel blends

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  • Caires, Anderson R.L.
  • Scherer, Marisa D.
  • De Souza, José E.
  • Oliveira, Samuel L.
  • M'Peko, Jean-Claude

Abstract

Recently, the potentiality of fluorescence spectroscopy to be used in the quantification of biodiesel content in diesel/biodiesel blends (DBB) was demonstrated. However, the source of the fluorescence dependence of the DBB with biodiesel concentration remains unanswered. In the present paper, a close analysis of the optical properties of the DBB was performed over a wide composition range. The findings suggest that the alterations in the fluorescence intensity can be accounted for only after taking into account changes in viscosity as well as absorbance, in a model where the fluorophores were considered as molecular rotors.

Suggested Citation

  • Caires, Anderson R.L. & Scherer, Marisa D. & De Souza, José E. & Oliveira, Samuel L. & M'Peko, Jean-Claude, 2014. "The role of viscosity in the fluorescence behavior of the diesel/biodiesel blends," Renewable Energy, Elsevier, vol. 63(C), pages 388-391.
    • Handle: RePEc:eee:renene:v:63:y:2014:i:c:p:388-391
    DOI: 10.1016/j.renene.2013.09.041
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    References listed on IDEAS

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    1. Caires, A.R.L. & Lima, V.S. & Oliveira, S.L., 2012. "Quantification of biodiesel content in diesel/biodiesel blends by fluorescence spectroscopy: Evaluation of the dependence on biodiesel feedstock," Renewable Energy, Elsevier, vol. 46(C), pages 137-140.
    2. Pousa, Gabriella P.A.G. & Santos, Andre L.F. & Suarez, Paulo A.Z., 2007. "History and policy of biodiesel in Brazil," Energy Policy, Elsevier, vol. 35(11), pages 5393-5398, November.
    3. Bozbas, Kahraman, 2008. "Biodiesel as an alternative motor fuel: Production and policies in the European Union," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 542-552, February.
    4. Cheng, Jay J. & Timilsina, Govinda R., 2011. "Status and barriers of advanced biofuel technologies: A review," Renewable Energy, Elsevier, vol. 36(12), pages 3541-3549.
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    1. Passos, Wilson E. & Oliveira, Ivan P. & Michels, Flávio S. & Trindade, Magno A.G. & Falcão, Evaristo A. & Marangoni, Bruno S. & Oliveira, Samuel L. & Caires, Anderson R.L., 2021. "Quantification of water in bioethanol using rhodamine B as an efficient molecular optical probe," Renewable Energy, Elsevier, vol. 165(P2), pages 42-51.

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