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Harnessing renewable hydrogen-rich syngas from valorization of palm oil mill effluent (POME) using steam reforming technique

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  • Cheng, Yoke Wang
  • Khan, Maksudur R.
  • Ng, Kim Hoong
  • Wongsakulphasatch, Suwimol
  • Cheng, Chin Kui

Abstract

Valorization of palm oil mill effluent (POME) over a sol-gel synthesized lanthanum nickel trioxide (LaNiO3) catalyst via steam reforming pathway was investigated from 573 to 1173 K. The blank run (steam reforming) at 873–1173 K neutralized the acidic POME with complete total suspended solids (TSS) removal, which accomplished >88% chemical oxygen demand (COD) removal, >97% 5-days biochemical oxygen demand (BOD5) removal, and >95% decolourization. From 773 K onwards, LaNiO3 greatly enhanced syngas production from POME steam reforming. The principal role of LaNiO3 was to enhance the syngas production. The XRD, FESEM-EDX, and TPO results of spent LaNiO3 were also correlated with gaseous product profiles to scrutinize its catalytic effects. At an optimum temperature of 873 K, catalytic POME steam reforming over LaNiO3 generated 73.91 μmol/min of H2-rich syngas (H2:CO ratio of 107.88). Withal, the aforesaid system was able to neutralize the acidic POME feedstock and eliminate its TSS content while reduced 98.38% COD, 99.10% BOD5, and 99.52% colour intensity.

Suggested Citation

  • Cheng, Yoke Wang & Khan, Maksudur R. & Ng, Kim Hoong & Wongsakulphasatch, Suwimol & Cheng, Chin Kui, 2019. "Harnessing renewable hydrogen-rich syngas from valorization of palm oil mill effluent (POME) using steam reforming technique," Renewable Energy, Elsevier, vol. 138(C), pages 1114-1126.
    • Handle: RePEc:eee:renene:v:138:y:2019:i:c:p:1114-1126
    DOI: 10.1016/j.renene.2019.02.040
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    References listed on IDEAS

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    1. Guan, Guoqing & Kaewpanha, Malinee & Hao, Xiaogang & Abudula, Abuliti, 2016. "Catalytic steam reforming of biomass tar: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 450-461.
    2. Gobi, K. & Vadivelu, V.M., 2013. "By-products of palm oil mill effluent treatment plant – A step towards sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 788-803.
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    Cited by:

    1. Liu, Chenlong & Chen, Dong & Cao, Yongan & zhang, Tianxi & Mao, Yangyang & Wang, Wenju & Wang, Zhigang & Kawi, Sibudjing, 2020. "Catalytic steam reforming of in-situ tar from rice husk over MCM-41 supported LaNiO3 to produce hydrogen rich syngas," Renewable Energy, Elsevier, vol. 161(C), pages 408-418.
    2. Rocha, Cláudio & Soria, M.A. & Madeira, Luís M., 2021. "Screening of commercial catalysts for steam reforming of olive mill wastewater," Renewable Energy, Elsevier, vol. 169(C), pages 765-779.
    3. Cheng, Yoke Wang & Chong, Chi Cheng & Lee, Soon Poh & Lim, Jun Wei & Wu, Ta Yeong & Cheng, Chin Kui, 2020. "Syngas from palm oil mill effluent (POME) steam reforming over lanthanum cobaltite: Effects of net-basicity," Renewable Energy, Elsevier, vol. 148(C), pages 349-362.
    4. Ge, Shengbo & Yek, Peter Nai Yuh & Cheng, Yoke Wang & Xia, Changlei & Wan Mahari, Wan Adibah & Liew, Rock Keey & Peng, Wanxi & Yuan, Tong-Qi & Tabatabaei, Meisam & Aghbashlo, Mortaza & Sonne, Christia, 2021. "Progress in microwave pyrolysis conversion of agricultural waste to value-added biofuels: A batch to continuous approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).

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