IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v189y2019ics0360544219318560.html
   My bibliography  Save this article

Catalytic reforming of biomass pyrolysis tar using the low-cost steel slag as catalyst

Author

Listed:
  • Guo, Feiqiang
  • Liang, Shuang
  • Zhao, Xingmin
  • Jia, Xiaopeng
  • Peng, Kuangye
  • Jiang, Xiaochen
  • Qian, Lin

Abstract

In this work, the possibility of steel slag as an effective and low-cost catalyst for the decomposition of biomass pyrolysis tar has been explored based on the high content of iron oxides for sustainable syngas production from biomass. By simple calcination treatment at 800 °C, the loose structure of the steel slag was formed with the main chemical composition of Fe2O3 and MgFe2O4. The steel slag exhibited good catalytic activity on the cracking of biomass pyrolysis tar, and even higher tar conversion efficiency can be obtained by reusing the steel slag, leading to the increase in syngas yield. The presence of additional steam can further promote the tar reforming reactions, leading to the significant increase in H2 and CO. At 800 °C, the tar conversion efficiency reached 94.1% with a high gas yield of 493.5 mL/g. The interaction between steel slag and reductive gases resulted in the reduction of iron oxides into Fe3O4, and more pores were formed for the spent steel slag, which can enhance the contact between active sites and reactants. These characteristics indicate that steel slag has the potential to be used as an efficient catalyst with excellent stability in the long-term biomass tar removal applications.

Suggested Citation

  • Guo, Feiqiang & Liang, Shuang & Zhao, Xingmin & Jia, Xiaopeng & Peng, Kuangye & Jiang, Xiaochen & Qian, Lin, 2019. "Catalytic reforming of biomass pyrolysis tar using the low-cost steel slag as catalyst," Energy, Elsevier, vol. 189(C).
  • Handle: RePEc:eee:energy:v:189:y:2019:i:c:s0360544219318560
    DOI: 10.1016/j.energy.2019.116161
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219318560
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2019.116161?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zabed, H. & Sahu, J.N. & Boyce, A.N. & Faruq, G., 2016. "Fuel ethanol production from lignocellulosic biomass: An overview on feedstocks and technological approaches," Renewable and Sustainable Energy Reviews, Elsevier, vol. 66(C), pages 751-774.
    2. Guo, Feiqiang & Peng, Kuangye & Liang, Shuang & Jia, Xiaopeng & Jiang, Xiaochen & Qian, Lin, 2019. "One-step synthesis of biomass activated char supported copper nanoparticles for catalytic cracking of biomass primary tar," Energy, Elsevier, vol. 180(C), pages 584-593.
    3. Guan, Guoqing & Kaewpanha, Malinee & Hao, Xiaogang & Abudula, Abuliti, 2016. "Catalytic steam reforming of biomass tar: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 450-461.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wan, Zhanghao & Hu, Jianhang & Qi, Xianjin, 2021. "Numerical analysis of hydrodynamics and thermochemical property of biomass gasification in a pilot-scale circulating fluidized bed," Energy, Elsevier, vol. 225(C).
    2. Du, Shilin & Shu, Rui & Guo, Feiqiang & Mao, Songbo & Bai, Jiaming & Qian, Lin & Xin, Chengyun, 2022. "Porous coal char-based catalyst from coal gangue and lignite with high metal contents in the catalytic cracking of biomass tar," Energy, Elsevier, vol. 249(C).
    3. Zhang, Huining & Dong, Jianping & Wei, Chao & Cao, Caifang & Zhang, Zuotai, 2022. "Future trend of terminal energy conservation in steelmaking plant: Integration of molten slag heat recovery-combustible gas preparation from waste plastics and CO2 emission reduction," Energy, Elsevier, vol. 239(PE).
    4. Tian, Beile & Mao, Songbo & Guo, Feiqiang & Bai, Jiaming & Shu, Rui & Qian, Lin & Liu, Qi, 2022. "Monolithic biochar-supported cobalt-based catalysts with high-activity and superior-stability for biomass tar reforming," Energy, Elsevier, vol. 242(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Shuxiao & Shan, Rui & Lu, Tao & Zhang, Yuyuan & Yuan, Haoran & Chen, Yong, 2020. "Pyrolysis char derived from waste peat for catalytic reforming of tar model compound," Applied Energy, Elsevier, vol. 263(C).
    2. Zhou, Qiaoqiao & Liu, Zhenyu & Wu, Ta Yeong & Zhang, Lian, 2023. "Furfural from pyrolysis of agroforestry waste: Critical factors for utilisation of C5 and C6 sugars," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
    3. Gu, Jing & Wang, Shuxiao & Lu, Tao & Wu, Yufeng & Yuan, Haoran & Chen, Yong, 2020. "Synthesis and evaluation of pyrolysis waste peat char supported catalyst for steam reforming of toluene," Renewable Energy, Elsevier, vol. 160(C), pages 964-973.
    4. Du, Shilin & Shu, Rui & Guo, Feiqiang & Mao, Songbo & Bai, Jiaming & Qian, Lin & Xin, Chengyun, 2022. "Porous coal char-based catalyst from coal gangue and lignite with high metal contents in the catalytic cracking of biomass tar," Energy, Elsevier, vol. 249(C).
    5. Buentello-Montoya, D.A. & Duarte-Ruiz, C.A. & Maldonado-Escalante, J.F., 2023. "Co-gasification of waste PET, PP and biomass for energy recovery: A thermodynamic model to assess the produced syngas quality," Energy, Elsevier, vol. 266(C).
    6. Ko, Ja Kyong & Lee, Jae Hoon & Jung, Je Hyeong & Lee, Sun-Mi, 2020. "Recent advances and future directions in plant and yeast engineering to improve lignocellulosic biofuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    7. Mariana S. T. Amândio & Joana M. Pereira & Jorge M. S. Rocha & Luísa S. Serafim & Ana M. R. B. Xavier, 2022. "Getting Value from Pulp and Paper Industry Wastes: On the Way to Sustainability and Circular Economy," Energies, MDPI, vol. 15(11), pages 1-31, June.
    8. Gomes, Michelle Garcia & Gurgel, Leandro Vinícius Alves & Baffi, Milla Alves & Pasquini, Daniel, 2020. "Pretreatment of sugarcane bagasse using citric acid and its use in enzymatic hydrolysis," Renewable Energy, Elsevier, vol. 157(C), pages 332-341.
    9. Jiří Jaromír Klemeš & Petar Sabev Varbanov & Paweł Ocłoń & Hon Huin Chin, 2019. "Towards Efficient and Clean Process Integration: Utilisation of Renewable Resources and Energy-Saving Technologies," Energies, MDPI, vol. 12(21), pages 1-32, October.
    10. Cheng, Yoke Wang & Khan, Maksudur R. & Ng, Kim Hoong & Wongsakulphasatch, Suwimol & Cheng, Chin Kui, 2019. "Harnessing renewable hydrogen-rich syngas from valorization of palm oil mill effluent (POME) using steam reforming technique," Renewable Energy, Elsevier, vol. 138(C), pages 1114-1126.
    11. Ruivo, Luís & Silva, Tiago & Neves, Daniel & Tarelho, Luís & Frade, Jorge, 2023. "Thermodynamic guidelines for improved operation of iron-based catalysts in gasification of biomass," Energy, Elsevier, vol. 268(C).
    12. Tae Hoon Kim & Dongjoong Im & Kyeong Keun Oh & Tae Hyun Kim, 2018. "Effects of Organosolv Pretreatment Using Temperature-Controlled Bench-Scale Ball Milling on Enzymatic Saccharification of Miscanthus × giganteus," Energies, MDPI, vol. 11(10), pages 1-13, October.
    13. Rooni, Vahur & Raud, Merlin & Kikas, Timo, 2017. "The freezing pre-treatment of lignocellulosic material: A cheap alternative for Nordic countries," Energy, Elsevier, vol. 139(C), pages 1-7.
    14. Bechara, Rami & Gomez, Adrien & Saint-Antonin, Valérie & Schweitzer, Jean-Marc & Maréchal, François & Ensinas, Adriano, 2018. "Review of design works for the conversion of sugarcane to first and second-generation ethanol and electricity," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 152-164.
    15. Yang, Jinhang & Wang, Xin & Shen, Boxiong & Hu, Zhenzhong & Xu, Lianfei & Yang, Shuo, 2020. "Lignin from energy plant (Arundo donax): Pyrolysis kinetics, mechanism and pathway evaluation," Renewable Energy, Elsevier, vol. 161(C), pages 963-971.
    16. Patange, Omkar S. & Garg, Amit & Jayaswal, Sachin, 2022. "An integrated bottom-up optimization to investigate the role of BECCS in transitioning towards a net-zero energy system: A case study from Gujarat, India," Energy, Elsevier, vol. 255(C).
    17. Al-Rahbi, Amal S. & Williams, Paul T., 2017. "Hydrogen-rich syngas production and tar removal from biomass gasification using sacrificial tyre pyrolysis char," Applied Energy, Elsevier, vol. 190(C), pages 501-509.
    18. Michał Wojcieszyk & Lotta Knuutila & Yuri Kroyan & Mário de Pinto Balsemão & Rupali Tripathi & Juha Keskivali & Anna Karvo & Annukka Santasalo-Aarnio & Otto Blomstedt & Martti Larmi, 2021. "Performance of Anisole and Isobutanol as Gasoline Bio-Blendstocks for Spark Ignition Engines," Sustainability, MDPI, vol. 13(16), pages 1-19, August.
    19. Chen, Guanyi & Li, Jian & Cheng, Zhanjun & Yan, Beibei & Ma, Wenchao & Yao, Jingang, 2018. "Investigation on model compound of biomass gasification tar cracking in microwave furnace: Comparative research," Applied Energy, Elsevier, vol. 217(C), pages 249-257.
    20. Nayak, Abhishek & Pulidindi, Indra Neel & Rao, Chinta Sankar, 2020. "Novel strategies for glucose production from biomass using heteropoly acid catalyst," Renewable Energy, Elsevier, vol. 159(C), pages 215-220.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:189:y:2019:i:c:s0360544219318560. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.