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Modeling of CO2/H2O Co-electrolysis using solar-driven SOEC coupled with ammonia-based chemical heat pump

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  • Xia, Qi
  • Zhao, Jianguo
  • Chen, Chen
  • Jin, Weiya

Abstract

A novel solar-driven high-temperature co-electrolysis system is proposed, which consists of a solar photovoltaics module, a parabolic trough collector module, an ammonia-based chemical heat pump (CHP), and a solid oxide electrolyzer cell (SOEC) module. The ammonia-based CHP implemented with a hydrogen-permeant membrane reactor can upgrade solar heat. Numerical models to simulate the hydrogen-permeant membrane reactor, the SOEC, and the entire system have been developed. The models have been validated by comparing model-generated results with experimental data from references. The effects of critical operating parameters on the system performance have been investigated parametrically. Through an optimization, a maximum solar-to-fuel efficiency ηSTF = 25.4% has been achieved, which is 6.4% higher than a typical solar-driven high temperature co-electrolysis.

Suggested Citation

  • Xia, Qi & Zhao, Jianguo & Chen, Chen & Jin, Weiya, 2023. "Modeling of CO2/H2O Co-electrolysis using solar-driven SOEC coupled with ammonia-based chemical heat pump," Renewable Energy, Elsevier, vol. 212(C), pages 128-137.
    • Handle: RePEc:eee:renene:v:212:y:2023:i:c:p:128-137
    DOI: 10.1016/j.renene.2023.05.041
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