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Alkenones as renewable phase change materials

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  • O'Neil, Gregory W.
  • Yen, Tian Qing
  • Leitch, Michael A.
  • Wilson, Gary R.
  • Brown, Emily A.
  • Rider, David A.
  • Reddy, Christopher M.

Abstract

Unique algal lipids known as alkenones were evaluated as potential phase change materials (PCMs). Alkenones were isolated and purified from commercial Isochrysis algal biomass and their thermal properties evaluated by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). Alkenone crystallinity appears to impact latent heat of fusion (ΔHfus), however both the ΔHfus and melting temperature (∼65 °C) of two different alkenone compositions obtained from separate commercial Isochrysis suppliers were nearly identical. Compared to a synthetic bis-fatty acid PCM, alkenones showed improved thermal stability by TGA and comparable ΔHfus (up to 275 J/g) by DSC. Overall the results demonstrate competitive properties for alkenones to other renewable and non-renewable PCMs such that alkenones represent a promising and potentially superior alternative for various ‘green’ PCM technologies.

Suggested Citation

  • O'Neil, Gregory W. & Yen, Tian Qing & Leitch, Michael A. & Wilson, Gary R. & Brown, Emily A. & Rider, David A. & Reddy, Christopher M., 2019. "Alkenones as renewable phase change materials," Renewable Energy, Elsevier, vol. 134(C), pages 89-94.
    • Handle: RePEc:eee:renene:v:134:y:2019:i:c:p:89-94
    DOI: 10.1016/j.renene.2018.11.001
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    References listed on IDEAS

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    1. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    2. Chandel, S.S. & Agarwal, Tanya, 2017. "Review of current state of research on energy storage, toxicity, health hazards and commercialization of phase changing materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 581-596.
    3. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
    4. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
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    1. Ran, Fengming & Chen, Yunkang & Cong, Rongshuai & Fang, Guiyin, 2020. "Flow and heat transfer characteristics of microencapsulated phase change slurry in thermal energy systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).

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