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Optimization of esterification reaction over niobium phosphate in a packed bed tubular reactor

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  • Rade, Letícia Leandro
  • Lemos, Caroline Ortega Terra
  • Barrozo, Marcos Antônio de Souza
  • Ribas, Rogério Marques
  • Monteiro, Robson de Souza
  • Hori, Carla Eponina

Abstract

The aim of this work was to investigate the effect of the calcination temperature on the textural properties, structure and acidity of niobium phosphate and the relationship between those properties and the catalytic activity for the continuous esterification reaction using oleic acid and ethanol. For this purpose, samples of niobium phosphate were prepared by calcination at 300, 350, 400, 450, 500 and 600 °C. Despite the good thermal stability presented by niobium phosphate, best results were achieved for samples pretreated at 300 °C, which presented higher acidity, surface area and catalytic activity. For this sample, the experimental conditions of temperature (from 220 to 290 °C), amount of catalyst (from 0 to 0.8 g) and ethanol:oleic acid molar ratio (from 2:1 to 14:1) were studied using design of experiments (DOE) and optimized with canonical analysis. The esterification reaction of oleic acid led to yields of esters up to 70% and conversion up to 90% at optimized conditions.

Suggested Citation

  • Rade, Letícia Leandro & Lemos, Caroline Ortega Terra & Barrozo, Marcos Antônio de Souza & Ribas, Rogério Marques & Monteiro, Robson de Souza & Hori, Carla Eponina, 2019. "Optimization of esterification reaction over niobium phosphate in a packed bed tubular reactor," Renewable Energy, Elsevier, vol. 131(C), pages 348-355.
    • Handle: RePEc:eee:renene:v:131:y:2019:i:c:p:348-355
    DOI: 10.1016/j.renene.2018.07.041
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    References listed on IDEAS

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    1. Rade, Letícia L. & Lemos, Caroline O.T. & Barrozo, Marcos Antônio S. & Ribas, Rogério M. & Monteiro, Robson S. & Hori, Carla E., 2018. "Optimization of continuous esterification of oleic acid with ethanol over niobic acid," Renewable Energy, Elsevier, vol. 115(C), pages 208-216.
    2. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
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    1. Daniel Carreira Batalha & Márcio José da Silva, 2021. "Biodiesel Production over Niobium-Containing Catalysts: A Review," Energies, MDPI, vol. 14(17), pages 1-33, September.

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