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NiCo-loaded carbon nanofibers obtained by electrospinning: Bifunctional behavior as air electrodes

Author

Listed:
  • Alegre, C.
  • Modica, E.
  • Di Blasi, A.
  • Di Blasi, O.
  • Busacca, C.
  • Ferraro, M.
  • Aricò, A.S.
  • Antonucci, V.
  • Baglio, V.

Abstract

In this work, carbon nanofibers (CNF) synthesized by electrospinning are loaded with a combination of nickel and cobalt, both in the metallic and oxide forms (NiCo-loaded CNF), and studied as bifunctional air electrodes for metal-air batteries. The performance of the NiCo-loaded CNF sample is compared with a similarly prepared CoOCo/CNF catalyst both for oxygen reduction and evolution reactions. The combination of nickel and cobalt, both in metallic and oxide form, leads to a bifunctional catalyst with a half-wave potential for the ORR of 874 mV vs. RHE and a reversibility (ΔEOER-ORR) of 764 mV. The stability of the catalyst is assessed by means of a 24 h chronopotentiometric test at −80 mA cm−2 and charge-discharge cycles (30 min each) at ±20 mA cm−2. NiCo-loaded CNF shows a remarkable stability, maintaining a constant potential during both tests.

Suggested Citation

  • Alegre, C. & Modica, E. & Di Blasi, A. & Di Blasi, O. & Busacca, C. & Ferraro, M. & Aricò, A.S. & Antonucci, V. & Baglio, V., 2018. "NiCo-loaded carbon nanofibers obtained by electrospinning: Bifunctional behavior as air electrodes," Renewable Energy, Elsevier, vol. 125(C), pages 250-259.
  • Handle: RePEc:eee:renene:v:125:y:2018:i:c:p:250-259
    DOI: 10.1016/j.renene.2018.02.089
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    References listed on IDEAS

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    1. Opitz, A. & Badami, P. & Shen, L. & Vignarooban, K. & Kannan, A.M., 2017. "Can Li-Ion batteries be the panacea for automotive applications?," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 685-692.
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