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Synergies between Ni, Co, and Mn ions in trimetallic Ni1-xCoxMnO4 catalysts for effective hydrogen production from propane steam reforming

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  • Jo, Seung Won
  • Im, Younghwan
  • Do, Jeong Yeon
  • Park, No-Kuk
  • Lee, Tae Jin
  • Lee, Sang Tae
  • Cha, Moon Soon
  • Jeon, Min-Kyu
  • Kang, Misook

Abstract

To suppress the rapid degradation of Ni-based catalysts, Co along with Ni was used as a catalytic active species with a Mn oxide promoter that has excellent oxygen transfer ability. This study examines the optimal ratios between Ni and Co in the synthesized catalyst Ni1-xCoxMnO4 for high hydrogen production in the propane reforming reaction. The synthesized catalysts were characterized by XRD, TEM, XPS, and TPD of CO, C3H8, and H2O, and TPR of H2. In addition, the reaction mechanism of propane reforming and the behaviors of the gases adsorbed on the catalyst were investigated by NMR analysis. The results confirmed that the reduction of Ni mainly occurs before that of Co, which means that Ni acts as the main active species. In addition, gas adsorption increases over catalysts that contain both Ni and Co; the synthesized catalysts also showed improved catalytic activities. The optimum ratio of Ni:Co is 0.6:0.4, with high hydrogen evolution of >80%; complete propane conversion was obtained for the 30Ni00.6Co0.4MnO4/Al2O3 catalyst over 10 h.

Suggested Citation

  • Jo, Seung Won & Im, Younghwan & Do, Jeong Yeon & Park, No-Kuk & Lee, Tae Jin & Lee, Sang Tae & Cha, Moon Soon & Jeon, Min-Kyu & Kang, Misook, 2017. "Synergies between Ni, Co, and Mn ions in trimetallic Ni1-xCoxMnO4 catalysts for effective hydrogen production from propane steam reforming," Renewable Energy, Elsevier, vol. 113(C), pages 248-256.
    • Handle: RePEc:eee:renene:v:113:y:2017:i:c:p:248-256
    DOI: 10.1016/j.renene.2017.05.072
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    References listed on IDEAS

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    2. Hafizi, A. & Rahimpour, M.R. & Hassanajili, Sh., 2016. "Hydrogen production via chemical looping steam methane reforming process: Effect of cerium and calcium promoters on the performance of Fe2O3/Al2O3 oxygen carrier," Applied Energy, Elsevier, vol. 165(C), pages 685-694.
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