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Hydrogen production for micro-fuel-cell from activated Al–Sn–Zn–X (X: hydride or halide) mixture in water

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  • Fan, Mei Qiang
  • Sun, Li Xian
  • Xu, Fen

Abstract

A systematic investigation of hydrogen production from milled Al–Sn–Zn–X (X: hydride or halide) mixtures in pure water was performed at room temperature. The hydrolysis mechanism of the mixtures was based on the work of micro-galvanic cell between aluminum and tin in water where aluminum reacted with water to generate AlOOH (Boehmite) and hydrogen. It was found that many effects such as milling time, temperature, additives and mass ratio had a significant role in the hydrogen production rate, especially that of the additives (hydride or halide) led to reduction of crystallite size and accumulation of uniform mixing. They also produced a lot of heat and the conductive ions which simulated the work of micro-galvanic cell. The milled Al–Sn–Zn–X (X: hydride or halide) mixtures had high reactivity and Al–Sn–Zn–MgH2 mixture produced 790 mL g−1 hydrogen in 5 min of the hydrolysis reaction with the activation energy of 17.570 kJ mol−1, corresponding to 7.04 wt.% hydrogen excluding water mass. Therefore, a new method of CO2 free and safe hydrogen production for micro-fuel-cell was obtained from the activated aluminum alloys in water.

Suggested Citation

  • Fan, Mei Qiang & Sun, Li Xian & Xu, Fen, 2011. "Hydrogen production for micro-fuel-cell from activated Al–Sn–Zn–X (X: hydride or halide) mixture in water," Renewable Energy, Elsevier, vol. 36(2), pages 519-524.
    • Handle: RePEc:eee:renene:v:36:y:2011:i:2:p:519-524
    DOI: 10.1016/j.renene.2010.07.006
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    References listed on IDEAS

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    1. Youn, Min Hye & Seo, Jeong Gil & Park, Sunyoung & Park, Dong Ryul & Jung, Ji Chul & Kim, Pil & Song, In Kyu, 2009. "Hydrogen production by auto-thermal reforming of ethanol over Ni-Ti-Zr metal oxide catalysts," Renewable Energy, Elsevier, vol. 34(3), pages 731-735.
    2. Kim, S.C. & Chun, Y.N., 2008. "Production of hydrogen by partial oxidation with thermal plasma," Renewable Energy, Elsevier, vol. 33(7), pages 1564-1569.
    3. Ahmad, G.E. & El Shenawy, E.T., 2006. "Optimized photovoltiac system for hydrogen production," Renewable Energy, Elsevier, vol. 31(7), pages 1043-1054.
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    1. Su, Ming & Hu, Haiping & Gan, Jianchang & Ye, Wenhua & Zhang, Wenhua & Wang, Huihu, 2021. "Thermodynamics, kinetics and reaction mechanism of hydrogen production from a novel Al alloy/NaCl/g-C3N4 composite by low temperature hydrolysis," Energy, Elsevier, vol. 218(C).
    2. Fan, Mei-Qiang & Mei, De-Sheng & Chen, Da & Lv, Chun-Ju & Shu, Kang-ying, 2011. "Portable hydrogen generation from activated Al–Li–Bi alloys in water," Renewable Energy, Elsevier, vol. 36(11), pages 3061-3067.
    3. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Effect of salts addition on the hydrogen generation of Al–LiH composite elaborated by ball milling," Energy, Elsevier, vol. 89(C), pages 907-913.
    4. Martínez-Salazar, A.L. & Melo-Banda, J.A. & Coronel-García, M.A. & González-Barbosa, J.J. & Domínguez-Esquivel, J.M., 2020. "Hydrogen generation by aluminum alloy corrosion in aqueous acid solutions promoted by nanometal: Kinetics study," Renewable Energy, Elsevier, vol. 146(C), pages 2517-2523.
    5. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Cao, Guozhou & Yan, Mi, 2014. "Hydrogen generation from Mg–LiBH4 hydrolysis improved by AlCl3 addition," Energy, Elsevier, vol. 68(C), pages 548-554.

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