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Catalytic gasification of tobacco rob in steam–nitrogen mixture: Kinetic study and fuel gas analysis

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  • Yang, Yi
  • Jin, Shiping
  • Lin, Yixin
  • Huang, Suyi
  • Yang, Haiping

Abstract

Tobacco rob (TR) gasification experiments were carried out using thermogravimetric analyzer and gas chromatographic analyzer (TG–GC). Under the catalytic and non-catalytic condition, the pyrolysis characteristics, gasification characteristics and kinetics of TR were investigated in nitrogen-steam atmosphere. In the gasification process, the volumetric model was used in modeling pyrolysis of TR and the shrinking model was applied for investigating the gasification of pyrolysis chars. The experimental results showed that the TR gasification started above 750 °C without catalysts. Both NiO and dolomite could decrease the gasification temperature and enhance water gas shift reactions. The composition of gasification production was detected by gas chromatograph. The H2 yield (34 mol/kg) of TR gasification with NiO was the most. The dolomite had more remarkable effect on improving CO yield (23 mol/kg).

Suggested Citation

  • Yang, Yi & Jin, Shiping & Lin, Yixin & Huang, Suyi & Yang, Haiping, 2012. "Catalytic gasification of tobacco rob in steam–nitrogen mixture: Kinetic study and fuel gas analysis," Energy, Elsevier, vol. 44(1), pages 509-514.
  • Handle: RePEc:eee:energy:v:44:y:2012:i:1:p:509-514
    DOI: 10.1016/j.energy.2012.05.051
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    References listed on IDEAS

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    1. Luo, S.Y. & Xiao, B. & Hu, Z.Q. & Liu, S.M. & Guan, Y.W., 2009. "Experimental study on oxygen-enriched combustion of biomass micro fuel," Energy, Elsevier, vol. 34(11), pages 1880-1884.
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    1. Cho, Min-Hwan & Mun, Tae-Young & Choi, Young-Kon & Kim, Joo-Sik, 2014. "Two-stage air gasification of mixed plastic waste: Olivine as the bed material and effects of various additives and a nickel-plated distributor on the tar removal," Energy, Elsevier, vol. 70(C), pages 128-134.
    2. Huang, Zhen & He, Fang & Zheng, Anqing & Zhao, Kun & Chang, Sheng & Zhao, Zengli & Li, Haibin, 2013. "Synthesis gas production from biomass gasification using steam coupling with natural hematite as oxygen carrier," Energy, Elsevier, vol. 53(C), pages 244-251.
    3. Gai, Chao & Dong, Yuping & Zhang, Tonghui, 2014. "Downdraft gasification of corn straw as a non-woody biomass: Effects of operating conditions on chlorides distribution," Energy, Elsevier, vol. 71(C), pages 638-644.

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