IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v34y2009i10p1652-1661.html
   My bibliography  Save this article

Development of copper-doped TiO2 photocatalyst for hydrogen production under visible light

Author

Listed:
  • Yoong, L.S.
  • Chong, F.K.
  • Dutta, Binay K.

Abstract

The advantage of copper doping onto TiO2 semiconductor photocatalyst for enhanced hydrogen generation under irradiation at the visible range of the electromagnetic spectrum has been investigated. Two methods of preparation for the copper-doped catalyst were selected – complex precipitation and wet impregnation methods – using copper nitrate trihydrate as the starting material. The dopant loading varied from 2 to 15%. Characterization of the photocatalysts was done by thermogravimetric analysis (TGA), temperature programmed reduction (TPR), diffuse reflectance UV-Vis (DR-UV-Vis), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). Photocatalytic activity towards hydrogen generation from water was investigated using a multiport photocatalytic reactor under visible light illumination with methanol added as a hole scavenger. Three calcination temperatures were selected – 300, 400 and 500°C. It was found that 10wt.% Cu/TiO2 calcined at 300°C for 30min yielded the maximum quantity of hydrogen. The reduction of band gap as a result of doping was estimated and the influence of the process parameters on catalytic activity is explained.

Suggested Citation

  • Yoong, L.S. & Chong, F.K. & Dutta, Binay K., 2009. "Development of copper-doped TiO2 photocatalyst for hydrogen production under visible light," Energy, Elsevier, vol. 34(10), pages 1652-1661.
    • Handle: RePEc:eee:energy:v:34:y:2009:i:10:p:1652-1661
    DOI: 10.1016/j.energy.2009.07.024
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544209003120
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2009.07.024?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Penner, S.S., 2006. "Steps toward the hydrogen economy," Energy, Elsevier, vol. 31(1), pages 33-43.
    2. Momirlan, M. & Veziroglu, T., 1999. "Recent directions of world hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 3(2-3), pages 219-231, June.
    3. Guo, L.J. & Zhao, L. & Jing, D.W. & Lu, Y.J. & Yang, H.H. & Bai, B.F. & Zhang, X.M. & Ma, L.J. & Wu, X.M., 2009. "Solar hydrogen production and its development in China," Energy, Elsevier, vol. 34(9), pages 1073-1090.
    4. Tseng, Phillip & Lee, John & Friley, Paul, 2005. "A hydrogen economy: opportunities and challenges," Energy, Elsevier, vol. 30(14), pages 2703-2720.
    5. Ni, Meng & Leung, Michael K.H. & Leung, Dennis Y.C. & Sumathy, K., 2007. "A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(3), pages 401-425, April.
    6. Bujak, J., 2008. "Mathematical modelling of a steam boiler room to research thermal efficiency," Energy, Elsevier, vol. 33(12), pages 1779-1787.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Nong, Guangzai & Li, Ming & Chen, Yiyi & Zhou, Zongwen & Wang, Shuangfei, 2015. "Simulation of energy conversion in a plant of photocatalysts water splitting for hydrogen fuel," Energy, Elsevier, vol. 81(C), pages 471-476.
    2. Bashiri, Robabeh & Mohamed, Norani Muti & Kait, Chong Fai & Sufian, Suriati & Kakooei, Saied & Khatani, Mehboob & Gholami, Zahra, 2016. "Optimization hydrogen production over visible light-driven titania-supported bimetallic photocatalyst from water photosplitting in tandem photoelectrochemical cell," Renewable Energy, Elsevier, vol. 99(C), pages 960-970.
    3. Nair, Ranjith G. & Tripathi, A.M. & Samdarshi, S.K., 2011. "Photocatalytic activity of predominantly rutile mixed phase Ag/TiV oxide nanoparticles under visible light irradiation," Energy, Elsevier, vol. 36(5), pages 3342-3347.
    4. El Naggar, Ahmed M.A. & Gobara, Heba M. & Nassar, Ibrahim M., 2015. "Novel nano-structured for the improvement of photo-catalyzed hydrogen production via water splitting with in-situ nano-carbon formation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1205-1216.
    5. Ruban, Priya & Sellappa, Kanmani, 2014. "Development and performance of bench-scale reactor for the photocatalytic generation of hydrogen," Energy, Elsevier, vol. 73(C), pages 926-932.
    6. Diker, Halide & Varlikli, Canan & Mizrak, Koray & Dana, Aykutlu, 2011. "Characterizations and photocatalytic activity comparisons of N-doped nc-TiO2 depending on synthetic conditions and structural differences of amine sources," Energy, Elsevier, vol. 36(2), pages 1243-1254.
    7. Alami, Abdul Hai & Rajab, Bilal & Abed, Jehad & Faraj, Mohammed & Hawili, Abdullah Abu & Alawadhi, Hussain, 2019. "Investigating various copper oxides-based counter electrodes for dye sensitized solar cell applications," Energy, Elsevier, vol. 174(C), pages 526-533.
    8. Tasleem, Sehar & Tahir, Muhammad, 2020. "Current trends in strategies to improve photocatalytic performance of perovskites materials for solar to hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 132(C).
    9. Samanta, Ritika & Chakraborty, Rajat, 2023. "Methyl levulinate synthesis from rice husk employing e-waste derived silica supported nano CuO–CdSO4 photocatalyst: Assessment of production environmental impacts, engine performance and emissions," Renewable Energy, Elsevier, vol. 210(C), pages 842-858.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yilmaz, Fatih & Balta, M. Tolga & Selbaş, Reşat, 2016. "A review of solar based hydrogen production methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 171-178.
    2. Ruban, Priya & Sellappa, Kanmani, 2014. "Development and performance of bench-scale reactor for the photocatalytic generation of hydrogen," Energy, Elsevier, vol. 73(C), pages 926-932.
    3. Bose, Probir Kumar & Deb, Madhujit & Banerjee, Rahul & Majumder, Arindam, 2013. "Multi objective optimization of performance parameters of a single cylinder diesel engine running with hydrogen using a Taguchi-fuzzy based approach," Energy, Elsevier, vol. 63(C), pages 375-386.
    4. Hosseini, Seyed Ehsan & Wahid, Mazlan Abdul, 2016. "Hydrogen production from renewable and sustainable energy resources: Promising green energy carrier for clean development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 850-866.
    5. Abánades, A. & Rubbia, C. & Salmieri, D., 2012. "Technological challenges for industrial development of hydrogen production based on methane cracking," Energy, Elsevier, vol. 46(1), pages 359-363.
    6. Sovacool, Benjamin K. & Brossmann, Brent, 2010. "Symbolic convergence and the hydrogen economy," Energy Policy, Elsevier, vol. 38(4), pages 1999-2012, April.
    7. Yasuda, Masahide & Matsumoto, Tomoko & Yamashita, Toshiaki, 2018. "Sacrificial hydrogen production over TiO2-based photocatalysts: Polyols, carboxylic acids, and saccharides," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1627-1635.
    8. Diego Bairrão & João Soares & José Almeida & John F. Franco & Zita Vale, 2023. "Green Hydrogen and Energy Transition: Current State and Prospects in Portugal," Energies, MDPI, vol. 16(1), pages 1-23, January.
    9. Lin, Zhenhong & Fan, Yueyue & Ogden, Joan M & Chen, Chien-Wei, 2008. "Optimized Pathways for Regional H2 Infrastructure Transitions: A Case Study for Southern California," Institute of Transportation Studies, Working Paper Series qt9mk5n8jn, Institute of Transportation Studies, UC Davis.
    10. Zhang, Peiye & Liu, Ming & Mu, Ruiqi & Yan, Junjie, 2024. "Exergy-based control strategy design and dynamic performance enhancement for parabolic trough solar receiver-reactor of methanol decomposition reaction," Renewable Energy, Elsevier, vol. 224(C).
    11. Sivasakthi, Sethuraman & Gurunathan, Karuppasamy, 2020. "Graphitic carbon nitride bedecked with CuO/ZnO hetero-interface microflower towards high photocatalytic performance," Renewable Energy, Elsevier, vol. 159(C), pages 786-800.
    12. Botterud, Audun & Yildiz, Bilge & Conzelmann, Guenter & Petri, Mark C., 2008. "Nuclear hydrogen: An assessment of product flexibility and market viability," Energy Policy, Elsevier, vol. 36(10), pages 3961-3973, October.
    13. Hafizi, A. & Rahimpour, M.R. & Hassanajili, Sh., 2016. "Hydrogen production via chemical looping steam methane reforming process: Effect of cerium and calcium promoters on the performance of Fe2O3/Al2O3 oxygen carrier," Applied Energy, Elsevier, vol. 165(C), pages 685-694.
    14. Michalsky, Ronald & Parman, Bryon J. & Amanor-Boadu, Vincent & Pfromm, Peter H., 2012. "Solar thermochemical production of ammonia from water, air and sunlight: Thermodynamic and economic analyses," Energy, Elsevier, vol. 42(1), pages 251-260.
    15. Yan, Jianhui & Yang, Haihua & Tang, Yougen & Lu, Zhouguang & Zheng, Shuqin & Yao, Maohai & Han, Yong, 2009. "Synthesis and photocatalytic activity of CuYyFe2−yO4–CuCo2O4 nanocomposites for H2 evolution under visible light irradiation," Renewable Energy, Elsevier, vol. 34(11), pages 2399-2403.
    16. Moharana, Manoj Kumar & Peela, Nageswara Rao & Khandekar, Sameer & Kunzru, Deepak, 2011. "Distributed hydrogen production from ethanol in a microfuel processor: Issues and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 524-533, January.
    17. Nzihou, Ange & Flamant, Gilles & Stanmore, Brian, 2012. "Synthetic fuels from biomass using concentrated solar energy – A review," Energy, Elsevier, vol. 42(1), pages 121-131.
    18. Marc A. Rosen, 2012. "Engineering Sustainability: A Technical Approach to Sustainability," Sustainability, MDPI, vol. 4(9), pages 1-23, September.
    19. Chen, Guanyi & Tao, Junyu & Liu, Caixia & Yan, Beibei & Li, Wanqing & Li, Xiangping, 2017. "Hydrogen production via acetic acid steam reforming: A critical review on catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1091-1098.
    20. Koroneos, C. & Dompros, A. & Roumbas, G. & Moussiopoulos, N., 2005. "Advantages of the use of hydrogen fuel as compared to kerosene," Resources, Conservation & Recycling, Elsevier, vol. 44(2), pages 99-113.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:34:y:2009:i:10:p:1652-1661. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.