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Evolution of solid residue composition during inert and oxidative biomass torrefaction

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  • Soria-Verdugo, Antonio
  • Guil-Pedrosa, José Félix
  • García-Hernando, Néstor
  • Ghoniem, Ahmed F.

Abstract

Biomass torrefaction is a thermochemical pretreatment that can be used to improve biomass properties, contributing to the energy densification of biomass or increasing its grindability, burning and gasification characteristics, porous structure, etc. While it is typically carried out under inert conditions, oxygen-lean torrefaction of biomass can reduce the process cost and complexity. This work proposes a novel extended 2-step kinetics mechanism capable of accurately predicting the evolution of the chemical composition of torrefied biomass. The model parameters are obtained from data collected from an extensive experimental campaign in which the chemical composition of torrefied biomass was measured at different temperatures, residence times, and oxygen fractions. The carbon mass fraction of the torrefied products was found to increase by up to 50 % under severe inert torrefaction conditions, i.e., high temperatures and long residence times, whereas the hydrogen fraction decreased. In the presence of oxygen during torrefaction, the carbon and hydrogen contents in the solid residue decrease compared with those produced under inert torrefaction. The extended 2-step model can also be used to determine the high heating value and energy densification of the torrefied biomass, with the latter ranging from 1 to 1.4 for the operating conditions tested.

Suggested Citation

  • Soria-Verdugo, Antonio & Guil-Pedrosa, José Félix & García-Hernando, Néstor & Ghoniem, Ahmed F., 2024. "Evolution of solid residue composition during inert and oxidative biomass torrefaction," Energy, Elsevier, vol. 312(C).
    • Handle: RePEc:eee:energy:v:312:y:2024:i:c:s0360544224032626
    DOI: 10.1016/j.energy.2024.133486
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    1. Pentananunt, Ranu & Rahman, A.N.M.Mizanur & Bhattacharya, S.C., 1990. "Upgrading of biomass by means of torrefaction," Energy, Elsevier, vol. 15(12), pages 1175-1179.
    2. Zhang, Congyu & Ho, Shih-Hsin & Chen, Wei-Hsin & Fu, Yujie & Chang, Jo-Shu & Bi, Xiaotao, 2019. "Oxidative torrefaction of biomass nutshells: Evaluations of energy efficiency as well as biochar transportation and storage," Applied Energy, Elsevier, vol. 235(C), pages 428-441.
    3. Chen, Wei-Hsin & Lu, Ke-Miao & Lee, Wen-Jhy & Liu, Shih-Hsien & Lin, Ta-Chang, 2014. "Non-oxidative and oxidative torrefaction characterization and SEM observations of fibrous and ligneous biomass," Applied Energy, Elsevier, vol. 114(C), pages 104-113.
    4. Prins, Mark J. & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G., 2006. "More efficient biomass gasification via torrefaction," Energy, Elsevier, vol. 31(15), pages 3458-3470.
    5. Yang, Yang & Sun, Mingman & Zhang, Meng & Zhang, Ke & Wang, Donghai & Lei, Catherine, 2019. "A fundamental research on synchronized torrefaction and pelleting of biomass," Renewable Energy, Elsevier, vol. 142(C), pages 668-676.
    6. Kung, Kevin S. & Thengane, Sonal K. & Shanbhogue, Santosh & Ghoniem, Ahmed F., 2019. "Parametric analysis of torrefaction reactor operating under oxygen-lean conditions," Energy, Elsevier, vol. 181(C), pages 603-614.
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    1. Yantao Yang & Lei Song & Yuanna Li & Yilin Shen & Mei Yang & Yunbo Wang & Hesheng Zheng & Wei Qi & Tingzhou Lei, 2025. "Effects of Different Biomass Types on Pellet Qualities and Processing Energy Consumption," Agriculture, MDPI, vol. 15(3), pages 1-19, January.

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