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Synthesis and progress of thermosensitive adsorbents in heat and humidity treatment: A review

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  • Wang, Weining
  • Zheng, Xu
  • Li, Dan
  • Cai, Jinliang
  • Pan, Quanwen

Abstract

The primary objective of this paper is to provide a comprehensive overview of recent developments in thermosensitive adsorbents, directing at synthesis, applications and discussion of equilibrium and dynamic adsorption/desorption properties, operation modes and regeneration methods. Synthesis methods are categorized into two mains (free radical polymerization method and the combination of RAFT with “click” chemistry) and their advantages and disadvantages are summarized. Applications of these adsorbents in the areas of dehumidification, air water harvesting, passive cooling, wastewater treatment, temperature sensors, flow control and drilling fluid fields are summed up. Regeneration methods including solar irradiation, electro-osmotic flow regeneration, electrical heaters, waste heat regeneration, microwave energy applications, and ultrasonic technology are analyzed. Equilibrium adsorption quantities of hygroscopic salt based thermosensitive adsorbents can be as high as 1.6 g/g to 3.8 g/g at 20–30 °C and 80–90 % RH. The thermosensitive property of PNIPAM can markedly diminish the energy demands associated with desorption, resulting in fast desorption rate. Adsorption kinetics needs further improvement, especially for applications with rapid switching of adsorption and regeneration processes. Solar irradiation is rated as one of the most promising ways of regeneration. This review identifies strategies for future research to boost thermosensitive composites' energy efficiency.

Suggested Citation

  • Wang, Weining & Zheng, Xu & Li, Dan & Cai, Jinliang & Pan, Quanwen, 2024. "Synthesis and progress of thermosensitive adsorbents in heat and humidity treatment: A review," Energy, Elsevier, vol. 311(C).
    • Handle: RePEc:eee:energy:v:311:y:2024:i:c:s0360544224031839
    DOI: 10.1016/j.energy.2024.133407
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    as
    1. Husam A. Almassad & Rada I. Abaza & Lama Siwwan & Bassem Al-Maythalony & Kyle E. Cordova, 2022. "Environmentally adaptive MOF-based device enables continuous self-optimizing atmospheric water harvesting," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Kazuya Matsumoto & Nobuki Sakikawa & Takashi Miyata, 2018. "Thermo-responsive gels that absorb moisture and ooze water," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
    3. Foong, Shin Ying & Liew, Rock Keey & Yek, Peter Nai Yuh & Han, Chai Sean & Phang, Xue Yee & Chen, Xiangmeng & Chong, William Woei Fong & Verma, Meenakshi & Lam, Su Shiung, 2023. "Microwave heating combined with activated carbon reaction bed: An energy-saving approach to convert seawater into freshwater," Energy, Elsevier, vol. 272(C).
    4. Shuo Liu & Chang-Ho Jeong & Myoung-Souk Yeo, 2020. "Effect of Evaporator Position on Heat Pump Assisted Solid Desiccant Cooling Systems," Energies, MDPI, vol. 13(22), pages 1-21, November.
    5. Shamim, Jubair A. & Hsu, Wei-Lun & Paul, Soumyadeep & Yu, Lili & Daiguji, Hirofumi, 2021. "A review of solid desiccant dehumidifiers: Current status and near-term development goals in the context of net zero energy buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    6. Wang, Cong & Yang, Bianfeng & Ji, Xu & Zhang, Ren & Wu, Hailong, 2022. "Study on activated carbon/silica gel/lithium chloride composite desiccant for solid dehumidification," Energy, Elsevier, vol. 251(C).
    7. Ozpinar, Pelin & Dogan, Ceren & Demiral, Hakan & Morali, Ugur & Erol, Salim & Samdan, Canan & Yildiz, Derya & Demiral, Ilknur, 2022. "Activated carbons prepared from hazelnut shell waste by phosphoric acid activation for supercapacitor electrode applications and comprehensive electrochemical analysis," Renewable Energy, Elsevier, vol. 189(C), pages 535-548.
    8. Vivekh, P. & Bui, D.T. & Wong, Y. & Kumja, M. & Chua, K.J., 2019. "Performance evaluation of PVA-LiCl coated heat exchangers for next-generation of energy-efficient dehumidification," Applied Energy, Elsevier, vol. 237(C), pages 733-750.
    9. Yao, Ye, 2016. "Research and applications of ultrasound in HVAC field: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 52-68.
    10. Frazzica, A. & Brancato, V. & Caprì, A. & Cannilla, C. & Gordeeva, L.G. & Aristov, Y.I., 2020. "Development of “salt in porous matrix” composites based on LiCl for sorption thermal energy storage," Energy, Elsevier, vol. 208(C).
    11. Vivekh, P. & Islam, M.R. & Chua, K.J., 2020. "Experimental performance evaluation of a composite superabsorbent polymer coated heat exchanger based air dehumidification system," Applied Energy, Elsevier, vol. 260(C).
    12. Hwang, Won-Baek & Choi, Sun & Lee, Dae-Young, 2017. "In-depth analysis of the performance of hybrid desiccant cooling system incorporated with an electric heat pump," Energy, Elsevier, vol. 118(C), pages 324-332.
    13. Jinlin Liu & Yu Wang & Zilong Zhong & Zhou Zhou & Dongliang Chen & Weijie Wang & Shuaixing Mai, 2023. "Study on Preparation and Properties of PNIPAm/PPy Hydrogel Hygroscopic Material for Solid Dehumidification System," Energies, MDPI, vol. 16(13), pages 1-15, July.
    14. Vivekh, P. & Bui, D.T. & Islam, M.R. & Zaw, K. & Chua, K.J., 2020. "Experimental performance and energy efficiency investigation of composite superabsorbent polymer and potassium formate coated heat exchangers," Applied Energy, Elsevier, vol. 275(C).
    15. Jackson Lord & Ashley Thomas & Neil Treat & Matthew Forkin & Robert Bain & Pierre Dulac & Cyrus H. Behroozi & Tilek Mamutov & Jillia Fongheiser & Nicole Kobilansky & Shane Washburn & Claudia Truesdell, 2021. "Global potential for harvesting drinking water from air using solar energy," Nature, Nature, vol. 598(7882), pages 611-617, October.
    16. Zhang, Yu & Wang, Weining & Zheng, Xu & Cai, Jinliang, 2024. "Recent progress on composite desiccants for adsorption-based dehumidification," Energy, Elsevier, vol. 302(C).
    17. Sun, X.Y. & Dai, Y.J. & Ge, T.S. & Zhao, Y. & Wang, R.Z., 2017. "Comparison of performance characteristics of desiccant coated air-water heat exchanger with conventional air-water heat exchanger – Experimental and analytical investigation," Energy, Elsevier, vol. 137(C), pages 399-411.
    18. Anca Mehedintu & Mihaela Sterpu & Georgeta Soava, 2018. "Estimation and Forecasts for the Share of Renewable Energy Consumption in Final Energy Consumption by 2020 in the European Union," Sustainability, MDPI, vol. 10(5), pages 1-22, May.
    19. Coppola, R.E. & Herranz, D. & Escudero-Cid, R. & Ming, N. & D’Accorso, N.B. & Ocón, P. & Abuin, G.C., 2020. "Polybenzimidazole-crosslinked-poly(vinyl benzyl chloride) as anion exchange membrane for alkaline electrolyzers," Renewable Energy, Elsevier, vol. 157(C), pages 71-82.
    20. Jiang, Qingquan & Khattak, Shoukat Iqbal & Rahman, Zia Ur, 2021. "Measuring the simultaneous effects of electricity consumption and production on carbon dioxide emissions (CO2e) in China: New evidence from an EKC-based assessment," Energy, Elsevier, vol. 229(C).
    21. Misha, S. & Mat, S. & Ruslan, M.H. & Sopian, K., 2012. "Review of solid/liquid desiccant in the drying applications and its regeneration methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4686-4707.
    22. Zheng, X. & Ge, T.S. & Wang, R.Z., 2014. "Recent progress on desiccant materials for solid desiccant cooling systems," Energy, Elsevier, vol. 74(C), pages 280-294.
    23. Wang, Guorong & Li, Yanbing & Xu, Lin & Jin, Zhiliang & Wang, Yanbin, 2020. "Facile synthesis of difunctional NiV LDH@ZIF-67 p-n junction: Serve as prominent photocatalyst for hydrogen evolution and supercapacitor electrode as well," Renewable Energy, Elsevier, vol. 162(C), pages 535-549.
    24. Zheng, X. & Wang, R.Z. & Ge, T.S. & Hu, L.M., 2015. "Performance study of SAPO-34 and FAPO-34 desiccants for desiccant coated heat exchanger systems," Energy, Elsevier, vol. 93(P1), pages 88-94.
    25. Park, Myeong Hyeon & Chung, Jun Yeob & Hong, Seong Ho & Shin, Hyun Ho & Lee, Dongchan & Kim, Yongchan, 2023. "Optimized geometric designs of desiccant wheels with metal-organic frameworks considering dehumidification capacity and energy," Energy, Elsevier, vol. 284(C).
    26. Zheng, Xu & Wan, Tinghao & Zhang, Yu & Ma, Qianling, 2024. "Experimental investigation of a thermo-responsive composite coated heat exchanger for ultra-low grade heat utilization," Energy, Elsevier, vol. 293(C).
    27. He Shan & Chunfeng Li & Zhihui Chen & Wenjun Ying & Primož Poredoš & Zhanyu Ye & Quanwen Pan & Jiayun Wang & Ruzhu Wang, 2022. "Exceptional water production yield enabled by batch-processed portable water harvester in semi-arid climate," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
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