IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v286y2024ics0360544223030098.html
   My bibliography  Save this article

Single-step integrated CO2 absorption and mineralization using fly ash coupled mixed amine solution: Mineralization performance and reaction kinetics

Author

Listed:
  • Lu, Jingwen
  • Wang, Zhonghui
  • Su, Sheng
  • Liu, Hao
  • Ma, Zhiwei
  • Ren, Qiangqiang
  • Xu, Kai
  • Wang, Yi
  • Hu, Song
  • Xiang, Jun

Abstract

Single-step integrated CO2 absorption and mineralization (IAM) using fly ash and mixed amine can reduce high energy consumption of absorbent regeneration while enabling the treatment of solid waste, however, the mineralization performance and kinetics are still unclear. This study adopted monoethanolamine (MEA)/N-Methyldiethanolamine (MDEA) mixed amine solution (MAS) as CO2 absorbent and fly ash as mineralizing materials to complete the IAM process in single-step, while realizing the regeneration of mixed amine. The mineralization performance was studied, and the reaction kinetics were analyzed by surface coverage model. The results demonstrated that fly ash effectively mineralized the absorbed CO2 in MAS and mixed amine regenerated. The mineralization efficiency reached maximum of 64.8 % at 40 °C, solid-liquid (S/L) ratio of 100 g/L, stirring rate of 500 r/min and 90 min, reaching 60.3 % after 10 cycles. The kinetic results demonstrated that surface coverage model exhibited excellent predictive capability for mineralization process (correlation coefficient (R2) > 0.99), with identification of surface reaction governed by calcium leaching as the primary rate-limiting factor. The regeneration of mixed amine was achieved by forming carbamate and protonated amine. The CO32−/HCO3− effectively reacted with the active Ca2+ ions in fly ash to realize mineralization, and the mineralization solid products was mainly CaCO3.

Suggested Citation

  • Lu, Jingwen & Wang, Zhonghui & Su, Sheng & Liu, Hao & Ma, Zhiwei & Ren, Qiangqiang & Xu, Kai & Wang, Yi & Hu, Song & Xiang, Jun, 2024. "Single-step integrated CO2 absorption and mineralization using fly ash coupled mixed amine solution: Mineralization performance and reaction kinetics," Energy, Elsevier, vol. 286(C).
    • Handle: RePEc:eee:energy:v:286:y:2024:i:c:s0360544223030098
    DOI: 10.1016/j.energy.2023.129615
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223030098
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2023.129615?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Weifeng & Xu, Yuanlong & Wang, Qiuhua, 2022. "Coupled CO2 absorption and mineralization with low-concentration monoethanolamine," Energy, Elsevier, vol. 241(C).
    2. Xiao, Min & Liu, Helei & Idem, Raphael & Tontiwachwuthikul, Paitoon & Liang, Zhiwu, 2016. "A study of structure–activity relationships of commercial tertiary amines for post-combustion CO2 capture," Applied Energy, Elsevier, vol. 184(C), pages 219-229.
    3. Hang Deng & Jeffrey M. Bielicki & Michael Oppenheimer & Jeffrey P. Fitts & Catherine A. Peters, 2017. "Leakage risks of geologic CO2 storage and the impacts on the global energy system and climate change mitigation," Climatic Change, Springer, vol. 144(2), pages 151-163, September.
    4. Pan, Shu-Yuan & Chiang, Pen-Chi & Chen, Yi-Hung & Tan, Chung-Sung & Chang, E.-E., 2014. "Kinetics of carbonation reaction of basic oxygen furnace slags in a rotating packed bed using the surface coverage model: Maximization of carbonation conversion," Applied Energy, Elsevier, vol. 113(C), pages 267-276.
    5. Park, Sangwon & Lee, Min-Gu & Park, Jinwon, 2013. "CO2 (carbon dioxide) fixation by applying new chemical absorption-precipitation methods," Energy, Elsevier, vol. 59(C), pages 737-742.
    6. Li, Kangkang & Leigh, Wardhaugh & Feron, Paul & Yu, Hai & Tade, Moses, 2016. "Systematic study of aqueous monoethanolamine (MEA)-based CO2 capture process: Techno-economic assessment of the MEA process and its improvements," Applied Energy, Elsevier, vol. 165(C), pages 648-659.
    7. Ji, Long & Yu, Hai & Li, Kangkang & Yu, Bing & Grigore, Mihaela & Yang, Qi & Wang, Xiaolong & Chen, Zuliang & Zeng, Ming & Zhao, Shuaifei, 2018. "Integrated absorption-mineralisation for low-energy CO2 capture and sequestration," Applied Energy, Elsevier, vol. 225(C), pages 356-366.
    8. Meng, Fanzhi & Meng, Yuan & Ju, Tongyao & Han, Siyu & Lin, Li & Jiang, Jianguo, 2022. "Research progress of aqueous amine solution for CO2 capture: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Weifeng & Xu, Yuanlong & Wang, Qiuhua, 2022. "Coupled CO2 absorption and mineralization with low-concentration monoethanolamine," Energy, Elsevier, vol. 241(C).
    2. Ji, Long & Yu, Hai & Li, Kangkang & Yu, Bing & Grigore, Mihaela & Yang, Qi & Wang, Xiaolong & Chen, Zuliang & Zeng, Ming & Zhao, Shuaifei, 2018. "Integrated absorption-mineralisation for low-energy CO2 capture and sequestration," Applied Energy, Elsevier, vol. 225(C), pages 356-366.
    3. Putta, Koteswara Rao & Tobiesen, Finn Andrew & Svendsen, Hallvard F. & Knuutila, Hanna K., 2017. "Applicability of enhancement factor models for CO2 absorption into aqueous MEA solutions," Applied Energy, Elsevier, vol. 206(C), pages 765-783.
    4. Liu, Fei & Fang, Mengxiang & Dong, Wenfeng & Wang, Tao & Xia, Zhixiang & Wang, Qinhui & Luo, Zhongyang, 2019. "Carbon dioxide absorption in aqueous alkanolamine blends for biphasic solvents screening and evaluation," Applied Energy, Elsevier, vol. 233, pages 468-477.
    5. Yu, Bing & Yu, Hai & Li, Kangkang & Yang, Qi & Zhang, Rui & Li, Lichun & Chen, Zuliang, 2017. "Characterisation and kinetic study of carbon dioxide absorption by an aqueous diamine solution," Applied Energy, Elsevier, vol. 208(C), pages 1308-1317.
    6. Xiao, Min & Zheng, Wenchao & Liu, Helei & Luo, Xiao & Gao, Hongxia & Liang, Zhiwu, 2021. "Thermodynamic analysis of carbamate formation and carbon dioxide absorption in N-methylaminoethanol solution," Applied Energy, Elsevier, vol. 281(C).
    7. Zhang, Weifeng & Xu, Yuanlong & Deng, Zhaoxiong & Wang, Qiuhua, 2022. "Experiments on continuous chemical desorption of CO2-rich solutions," Energy, Elsevier, vol. 239(PD).
    8. Meng, Fanzhi & Meng, Yuan & Ju, Tongyao & Han, Siyu & Lin, Li & Jiang, Jianguo, 2022. "Research progress of aqueous amine solution for CO2 capture: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    9. Solomon Aforkoghene Aromada & Nils Henrik Eldrup & Fredrik Normann & Lars Erik Øi, 2020. "Techno-Economic Assessment of Different Heat Exchangers for CO 2 Capture," Energies, MDPI, vol. 13(23), pages 1-27, November.
    10. Zhang, Xiaowen & Zhang, Rui & Liu, Helei & Gao, Hongxia & Liang, Zhiwu, 2018. "Evaluating CO2 desorption performance in CO2-loaded aqueous tri-solvent blend amines with and without solid acid catalysts," Applied Energy, Elsevier, vol. 218(C), pages 417-429.
    11. Wang, Rujie & Zhao, Huajun & Qi, Cairao & Yang, Xiaotong & Zhang, Shihan & Li, Ming & Wang, Lidong, 2022. "Novel tertiary amine-based biphasic solvent for energy-efficient CO2 capture with low corrosivity," Energy, Elsevier, vol. 260(C).
    12. Li, Long & Liu, Weizao & Qin, Zhifeng & Zhang, Guoquan & Yue, Hairong & Liang, Bin & Tang, Shengwei & Luo, Dongmei, 2021. "Research on integrated CO2 absorption-mineralization and regeneration of absorbent process," Energy, Elsevier, vol. 222(C).
    13. Ren, Siyue & Feng, Xiao & Wang, Yufei, 2021. "Emergy evaluation of the integrated gasification combined cycle power generation systems with a carbon capture system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    14. Tu, Te & Yang, Xing & Cui, Qiufang & Shang, Yu & Yan, Shuiping, 2022. "CO2 regeneration energy requirement of carbon capture process with an enhanced waste heat recovery from stripped gas by advanced transport membrane condenser," Applied Energy, Elsevier, vol. 323(C).
    15. Masoud Ahmadinia & Seyed M. Shariatipour, 2021. "A study on the impact of storage boundary and caprock morphology on carbon sequestration in saline aquifers," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(1), pages 183-205, February.
    16. Ren, Shan & Aldahri, Tahani & Liu, Weizao & Liang, Bin, 2021. "CO2 mineral sequestration by using blast furnace slag: From batch to continuous experiments," Energy, Elsevier, vol. 214(C).
    17. Xie, Heping & Wu, Yifan & Liu, Tao & Wang, Fuhuan & Chen, Bin & Liang, Bin, 2020. "Low-energy-consumption electrochemical CO2 capture driven by biomimetic phenazine derivatives redox medium," Applied Energy, Elsevier, vol. 259(C).
    18. Zhang, Xiaowen & Zhang, Xin & Liu, Helei & Li, Wensheng & Xiao, Min & Gao, Hongxia & Liang, Zhiwu, 2017. "Reduction of energy requirement of CO2 desorption from a rich CO2-loaded MEA solution by using solid acid catalysts," Applied Energy, Elsevier, vol. 202(C), pages 673-684.
    19. Chauvy, Remi & Dubois, Lionel & Lybaert, Paul & Thomas, Diane & De Weireld, Guy, 2020. "Production of synthetic natural gas from industrial carbon dioxide," Applied Energy, Elsevier, vol. 260(C).
    20. Han, Siyu & Meng, Yuan & Aihemaiti, Aikelaimu & Gao, Yuchen & Ju, Tongyao & Xiang, Honglin & Jiang, Jianguo, 2022. "Biogas upgrading with various single and blended amines solutions: Capacities and kinetics," Energy, Elsevier, vol. 253(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:286:y:2024:i:c:s0360544223030098. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.