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Pyrolysis kinetics, thermodynamics of PTA sludge and product characterization of cyclic in-situ catalytic pyrolysis by using recycled char as a catalyst

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  • Xing, Xinxin
  • Zhao, Hongyu
  • Zhou, Lili
  • Wang, Yangang
  • Chen, Haijun
  • Gao, Ying
  • Wang, Yinfeng
  • Zhu, Yuezhao

Abstract

Pyrolysis is an effective way for the sludge harmless, reduction treatment and resource utilization. In this study, the pyrolysis kinetics and thermodynamics of PTA sludge was evaluated. Afterword, a cyclic in-situ catalytic pyrolysis of PTA sludge by using recycled char as a catalyst was conducted. The product characterization, e.g. pyrolysis syngas as well as the catalytic effect of pyrolysis char, were analyzed. The results demonstrated that the Kissinger-Akahira-Sunose (KAS), Ozawa-Flynn-Wall (OFW), and Starink model-free methods have good agreement on kinetic parameters, the average activation energy was calculated at 295.18, 286.62, and 290.55 kJ/mol, respectively. Meanwhile, thermodynamic parameters, e.g. the variations in enthalpy (ΔH), entropy (ΔS), and Gibbs free energy (ΔG), were evaluated based on the deduced kinetic results, whereby the suitable pyrolysis temperature was determined at 973 K. The results of cyclic in-situ catalytic pyrolysis showed that the pyrolysis char could promote tar cracking, which greatly increased the yield of pyrolysis syngas. After five rounds of in-situ catalytic pyrolysis, the yield of pyrolysis syngas increased from 0.089 L/g to 0.176 L/g and the carbon conversion increased from 24.8% to 36.5%, respectively.

Suggested Citation

  • Xing, Xinxin & Zhao, Hongyu & Zhou, Lili & Wang, Yangang & Chen, Haijun & Gao, Ying & Wang, Yinfeng & Zhu, Yuezhao, 2022. "Pyrolysis kinetics, thermodynamics of PTA sludge and product characterization of cyclic in-situ catalytic pyrolysis by using recycled char as a catalyst," Energy, Elsevier, vol. 251(C).
    • Handle: RePEc:eee:energy:v:251:y:2022:i:c:s0360544222007241
    DOI: 10.1016/j.energy.2022.123821
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    2. Dai, Ying & Liu, Guojun & Liang, Hongxin & Fang, Hua & Chen, Jianbiao & Wang, Fenfen & Zhu, Jinjiao & Zhu, Yuezhao & Tan, Jinzhu, 2024. "Co-gasification characteristics of Ca-rich sludge and Fe-rich sludge under CO2 atmosphere, and potential utilization of gasification residues as renewable catalyst in biomass pyrolysis," Renewable Energy, Elsevier, vol. 224(C).
    3. Wu, Yan & Yu, Yue & Zhu, Ailing & Fu, Junjie & Xia, Yaping & Lan, Guoxing & Fu, Chuan & Ma, Zhicheng & Xue, Jianfu & Tao, Lin & Xie, Xinrui, 2024. "Effect of different digestate biochars as promoters via sludge anaerobic digestion on subsequent pyrolysis products: Focusing on the nitrogen, sulfur, and chlorine releasing characteristics," Renewable Energy, Elsevier, vol. 226(C).
    4. Wei Luo & Ming-Jun Chen & Ting Wang & Jin-Feng Feng & Zhi-Cheng Fu & Jin-Ni Deng & Yuan-Wei Yan & Yu-Zhong Wang & Hai-Bo Zhao, 2024. "Catalytic polymer self-cleavage for CO2 generation before combustion empowers materials with fire safety," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    5. Ma, Mingyan & Xu, Donghai & Gong, Xuehan & Diao, Yunfei & Feng, Peng & Kapusta, Krzysztof, 2023. "Municipal sewage sludge product recirculation catalytic pyrolysis mechanism from a kinetic perspective," Renewable Energy, Elsevier, vol. 215(C).

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