IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v263y2023ipas0360544222024008.html
   My bibliography  Save this article

Effect of multi-component gases on the behavior and mechanism of carbon deposition in hydrogen-rich blast furnaces

Author

Listed:
  • Jiao, Kexin
  • Feng, Guangxiang
  • Zhang, Jianliang
  • Wang, Cui
  • Zhang, Lei

Abstract

Hydrogen-rich blast furnace is considered an advanced technology in the iron and steel industry for reducing carbon emissions at the source. The CO utilization is instead reduced due to the severe carbon deposition behavior after hydrogen enrichment. This paper quantitatively investigated the effect of CO–H2–H2O–N2 multi-component on carbon deposition behavior, and a formation mechanism of deposited carbon was proposed finally. The results revealed that the optimum temperature range for carbon deposition was about 470–900 °C, and the maximum rate of carbon deposition was reached at 550–700 °C. At 600 °C, the carbon deposition rate for 100%CO and 40%CO–60%N2 were 0.54 g/d and 0.13 g/d, respectively. The aggravating effect of H2 to carbon deposition was 5.2 times that of H2O. Whereas the carbon deposition will be constrained in low CO and high H2 environment. The SEM showed that the morphology of the deposited carbon was filamentous, its formation mechanism on the iron surface is: (a) Adsorption of gases on the iron surface, (b) Formation of Fe3C layer, (c) Deposition of graphite layer, (d) Decomposition of Fe3C layer, (e) Formation of Fe3C–Fe + C (diss.) catalytic particles, (f) Formation of filamentous carbon, (g) Carbon activity in metallic Fe-filamentous carbon.

Suggested Citation

  • Jiao, Kexin & Feng, Guangxiang & Zhang, Jianliang & Wang, Cui & Zhang, Lei, 2023. "Effect of multi-component gases on the behavior and mechanism of carbon deposition in hydrogen-rich blast furnaces," Energy, Elsevier, vol. 263(PA).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pa:s0360544222024008
    DOI: 10.1016/j.energy.2022.125518
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544222024008
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2022.125518?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Li, Lin & Tang, Dawei & Song, Yongchen & Jiang, Bo & Zhang, Qian, 2018. "Hydrogen production from ethanol steam reforming on Ni-Ce/MMT catalysts," Energy, Elsevier, vol. 149(C), pages 937-943.
    2. Zhang, Qi & Xu, Jin & Wang, Yujie & Hasanbeigi, Ali & Zhang, Wei & Lu, Hongyou & Arens, Marlene, 2018. "Comprehensive assessment of energy conservation and CO2 emissions mitigation in China’s iron and steel industry based on dynamic material flows," Applied Energy, Elsevier, vol. 209(C), pages 251-265.
    3. An, Runying & Yu, Biying & Li, Ru & Wei, Yi-Ming, 2018. "Potential of energy savings and CO2 emission reduction in China’s iron and steel industry," Applied Energy, Elsevier, vol. 226(C), pages 862-880.
    4. Rosha, Pali & Mohapatra, Saroj Kumar & Mahla, Sunil Kumar & Dhir, Amit, 2019. "Hydrogen enrichment of biogas via dry and autothermal-dry reforming with pure nickel (Ni) nanoparticle," Energy, Elsevier, vol. 172(C), pages 733-739.
    5. Chen, Wei-Hsin & Hsu, Chih-Liang & Du, Shan-Wen, 2015. "Thermodynamic analysis of the partial oxidation of coke oven gas for indirect reduction of iron oxides in a blast furnace," Energy, Elsevier, vol. 86(C), pages 758-771.
    6. Tian, Beile & Mao, Songbo & Guo, Feiqiang & Bai, Jiaming & Shu, Rui & Qian, Lin & Liu, Qi, 2022. "Monolithic biochar-supported cobalt-based catalysts with high-activity and superior-stability for biomass tar reforming," Energy, Elsevier, vol. 242(C).
    7. Pashchenko, Dmitry & Makarov, Ivan, 2021. "Carbon deposition in steam methane reforming over a Ni-based catalyst: Experimental and thermodynamic analysis," Energy, Elsevier, vol. 222(C).
    8. Sun, Minmin & Zhang, Jianliang & Li, Kejiang & Barati, Mansoor & Liu, Zhibin, 2022. "Co-gasification characteristics of coke blended with hydro-char and pyro-char from bamboo," Energy, Elsevier, vol. 241(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, You & Yuan, Zengwei & Margni, Manuele & Bulle, Cécile & Hua, Hui & Jiang, Songyan & Liu, Xuewei, 2019. "Intensive carbon dioxide emission of coal chemical industry in China," Applied Energy, Elsevier, vol. 236(C), pages 540-550.
    2. Elshkaki, Ayman, 2019. "Material-energy-water-carbon nexus in China’s electricity generation system up to 2050," Energy, Elsevier, vol. 189(C).
    3. Wang, Yihan & Chen, Chen & Tao, Yuan & Wen, Zongguo & Chen, Bin & Zhang, Hong, 2019. "A many-objective optimization of industrial environmental management using NSGA-III: A case of China’s iron and steel industry," Applied Energy, Elsevier, vol. 242(C), pages 46-56.
    4. Yue, Hui & Worrell, Ernst & Crijns-Graus, Wina, 2021. "Impacts of regional industrial electricity savings on the development of future coal capacity per electricity grid and related air pollution emissions – A case study for China," Applied Energy, Elsevier, vol. 282(PB).
    5. Vögele, Stefan & Grajewski, Matthias & Govorukha, Kristina & Rübbelke, Dirk, 2020. "Challenges for the European steel industry: Analysis, possible consequences and impacts on sustainable development," Applied Energy, Elsevier, vol. 264(C).
    6. Ren, Lei & Zhou, Sheng & Peng, Tianduo & Ou, Xunmin, 2021. "A review of CO2 emissions reduction technologies and low-carbon development in the iron and steel industry focusing on China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    7. Li, Yibo & Li, Juan & Sun, Mei & Guo, Yanzi & Cheng, Faxin & Gao, Cuixia, 2024. "Analysis of carbon neutrality technology path selection in the steel industry under policy incentives," Energy, Elsevier, vol. 292(C).
    8. Chen, Wei-Hsin & Hsu, Chih-Liang & Wang, Xiao-Dong, 2016. "Thermodynamic approach and comparison of two-step and single step DME (dimethyl ether) syntheses with carbon dioxide utilization," Energy, Elsevier, vol. 109(C), pages 326-340.
    9. Li, Xi & Yu, Biying, 2019. "Peaking CO2 emissions for China's urban passenger transport sector," Energy Policy, Elsevier, vol. 133(C).
    10. Yang, Honghua & Ma, Linwei & Li, Zheng, 2023. "Tracing China's steel use from steel flows in the production system to steel footprints in the consumption system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 172(C).
    11. An, Runying & Yu, Biying & Li, Ru & Wei, Yi-Ming, 2018. "Potential of energy savings and CO2 emission reduction in China’s iron and steel industry," Applied Energy, Elsevier, vol. 226(C), pages 862-880.
    12. Park, Min-Ju & Kim, Hak-Min & Gu, Yun-Jeong & Jeong, Dae-Woon, 2023. "Optimization of biogas-reforming conditions considering carbon formation, hydrogen production, and energy efficiencies," Energy, Elsevier, vol. 265(C).
    13. Song, Weiming & Zhou, Jianan & Li, Yujie & Yang, Jian & Cheng, Rijin, 2021. "New technology for producing high-quality combustible gas by high-temperature reaction of dust-removal coke powder in mixed atmosphere," Energy, Elsevier, vol. 233(C).
    14. Shao, Tianming & Pan, Xunzhang & Li, Xiang & Zhou, Sheng & Zhang, Shu & Chen, Wenying, 2022. "China's industrial decarbonization in the context of carbon neutrality: A sub-sectoral analysis based on integrated modelling," Renewable and Sustainable Energy Reviews, Elsevier, vol. 170(C).
    15. Shuntian Xu & Huaxuan Wang & Xin Tian & Tao Wang & Hiroki Tanikawa, 2022. "From efficiency to equity: Changing patterns of China's regional transportation systems from an in‐use steel stocks perspective," Journal of Industrial Ecology, Yale University, vol. 26(2), pages 548-561, April.
    16. Wang, Juan & Hu, Mingming & Rodrigues, João F.D., 2018. "The evolution and driving forces of industrial aggregate energy intensity in China: An extended decomposition analysis," Applied Energy, Elsevier, vol. 228(C), pages 2195-2206.
    17. Biying Yu & Guangpu Zhao & Runying An, 2019. "Framing the picture of energy consumption in China," Natural Hazards: Journal of the International Society for the Prevention and Mitigation of Natural Hazards, Springer;International Society for the Prevention and Mitigation of Natural Hazards, vol. 99(3), pages 1469-1490, December.
    18. Dong, Kangyin & Sun, Renjin & Hochman, Gal & Li, Hui, 2018. "Energy intensity and energy conservation potential in China: A regional comparison perspective," Energy, Elsevier, vol. 155(C), pages 782-795.
    19. Jiang, Jingjing & Ye, Bin & Liu, Junguo, 2019. "Peak of CO2 emissions in various sectors and provinces of China: Recent progress and avenues for further research," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 813-833.
    20. Yi, Qun & Gong, Min-Hui & Huang, Yi & Feng, Jie & Hao, Yan-Hong & Zhang, Ji-Long & Li, Wen-Ying, 2016. "Process development of coke oven gas to methanol integrated with CO2 recycle for satisfactory techno-economic performance," Energy, Elsevier, vol. 112(C), pages 618-628.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:263:y:2023:i:pa:s0360544222024008. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.