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Systematic identification and distribution analysis of olefins in FCC slurry oil

Author

Listed:
  • Jiao, Shouhui
  • Wang, Feng
  • Wang, Lili
  • Biney, Bernard Wiafe
  • Liu, He
  • Chen, Kun
  • Guo, Aijun
  • Sun, Lanyi
  • Wang, Zongxian

Abstract

In response to the chemical industry's eco-friendly and high-value-added requirements, FCC slurry oil (SO) has been used as a raw material for novel solid carbon materials. As one of the most important chemically active intermediates and products in the FCC process, olefins may have a significant impact on the quality of the carbon materials produced. However, the existence and distribution of olefins have not been discussed. In this paper, olefinic hydrocarbons were first innovatively identified as important compounds that do exist in SO, and their distributions in sub-fractions below 500 °C, classified with the types and carbon numbers, were analyzed. However, there are great limitations for the existing analytical methods in the distribution detection of olefins in the whole fractions of heavy oils. In order to solve this problem, a newly-developed analytical method has been developed. Two different separation techniques were implemented to separate SO into six sub-fractions and eight group compositions, according to boiling point and molecular polarity respectively, before the analysis of olefin distribution for higher accuracy. The proposed method has been further verified by the GC × GC-TOFMS method and proved to have superior reliability. The olefinic carbons in the fraction of 350–400 °C possess the highest content among the detected narrow fractions, up to 1.55%, which decreases gradually with the increase of boiling points, and the first three sub-fractions between 350–470 °C take most of the olefinic carbons in SO, reaching around 74%.

Suggested Citation

  • Jiao, Shouhui & Wang, Feng & Wang, Lili & Biney, Bernard Wiafe & Liu, He & Chen, Kun & Guo, Aijun & Sun, Lanyi & Wang, Zongxian, 2022. "Systematic identification and distribution analysis of olefins in FCC slurry oil," Energy, Elsevier, vol. 239(PA).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pa:s0360544221022076
    DOI: 10.1016/j.energy.2021.121959
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    References listed on IDEAS

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    1. Ren, Tao & Patel, Martin & Blok, Kornelis, 2006. "Olefins from conventional and heavy feedstocks: Energy use in steam cracking and alternative processes," Energy, Elsevier, vol. 31(4), pages 425-451.
    2. Park, Ki-Bum & Oh, Seung-Jin & Begum, Guzelciftci & Kim, Joo-Sik, 2018. "Production of clean oil with low levels of chlorine and olefins in a continuous two-stage pyrolysis of a mixture of waste low-density polyethylene and polyvinyl chloride," Energy, Elsevier, vol. 157(C), pages 402-411.
    3. Silva, Wellington Costa & Castro, Maria Priscila Pessanha & Perez, Victor Haber & Machado, Francisco A. & Mota, Leonardo & Sthel, Marcelo Silva, 2016. "Thermal degradation of ethanolic biodiesel: Physicochemical and thermal properties evaluation," Energy, Elsevier, vol. 114(C), pages 1093-1099.
    4. Xu, Zhi-Xiang & Liu, Peng & Xu, Gui-Sheng & Liu, Qing & He, Zhi-Xia & Wang, Qian, 2017. "Bio-fuel oil characteristic from catalytic cracking of hydrogenated palm oil," Energy, Elsevier, vol. 133(C), pages 666-675.
    5. Chandran, Radhakrishnan & Kaliaperumal, Rajendran & Balakrishnan, Saravanakumar & Britten, Allen J. & MacInnis, Judy & Mkandawire, Martin, 2020. "Characteristics of bio-oil from continuous fast pyrolysis of Prosopis juliflora," Energy, Elsevier, vol. 190(C).
    6. Ahmad, Imtiaz & Shakirullah, Mohammad & ur Rehman, Habib & Ishaq, Mohammad & Khan, Mohammad Arsala & Shah, Amjad Ali, 2009. "NMR analysis of cracking products of asphalt and assessment of catalyst performance," Energy, Elsevier, vol. 34(2), pages 127-133.
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    1. Jiao, Shouhui & Li, Zeliang & Qiu, Zhipeng & Biney, Bernard Wiafe & Wang, Feng & Liu, He & Chen, Kun & Guo, Aijun & Wang, Zongxian, 2023. "Effects of olefinic compounds on the thermal transformation for FCC slurry oil: Evolution pattern and mechanism," Energy, Elsevier, vol. 262(PB).

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