IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v239y2022ipas0360544221021939.html
   My bibliography  Save this article

Direct measurement of the mass transport coefficient of water in silica-gel using the zero length column technique

Author

Listed:
  • Brandani, Stefano
  • Mangano, Enzo

Abstract

In all silica-gel adsorption processes driven by low-grade heat, the kinetics of adsorption of water on silica-gel is very important in order to optimize design and becomes an essential factor in ultra-low grade heat applications. A new approach for the determination of the mass transfer coefficient of water in commercial silica-gel is proposed and demonstrated with measurements on a single particle using the zero length column technique. Under equilibrium conditions the methodology offers the key advantage to acquire equilibrium isotherms with thousands of points in less than one day. This allows to obtain the relationship between vapour concentration and equilibrium adsorbed amount through numerical interpolation. At higher flowrates, the system operates under kinetic control therefore allowing the determination of the mass transfer coefficient. The novel approach calculates all the elements needed to obtain the mass transfer coefficient from the measured signals without the need to use a specific model. Adsorption and desorption experiments were carried out at different flowrates and three different temperatures. The kinetic responses can be used to determine an average mass transfer coefficient, which is consistent with literature values, but a complex behaviour is observed with surface diffusion as the main contribution to the transport process.

Suggested Citation

  • Brandani, Stefano & Mangano, Enzo, 2022. "Direct measurement of the mass transport coefficient of water in silica-gel using the zero length column technique," Energy, Elsevier, vol. 239(PA).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pa:s0360544221021939
    DOI: 10.1016/j.energy.2021.121945
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221021939
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.121945?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Alsaman, Ahmed S. & Askalany, Ahmed A. & Harby, K. & Ahmed, Mahmoud S., 2017. "Performance evaluation of a solar-driven adsorption desalination-cooling system," Energy, Elsevier, vol. 128(C), pages 196-207.
    2. Aristov, Yuri I., 2020. "Dynamics of adsorptive heat conversion systems: Review of basics and recent advances," Energy, Elsevier, vol. 205(C).
    3. Fong, K.F. & Lee, C.K., 2018. "Impact of adsorbent characteristics on performance of solid desiccant wheel," Energy, Elsevier, vol. 144(C), pages 1003-1012.
    4. Grabowska, K. & Sztekler, K. & Krzywanski, J. & Sosnowski, M. & Stefanski, S. & Nowak, W., 2021. "Construction of an innovative adsorbent bed configuration in the adsorption chiller part 2. experimental research of coated bed samples," Energy, Elsevier, vol. 215(PA).
    5. Wu, X.N. & Ge, T.S. & Dai, Y.J. & Wang, R.Z., 2019. "Investigation on novel desiccant wheel using wood pulp fiber paper with high coating ratio as matrix," Energy, Elsevier, vol. 176(C), pages 493-504.
    6. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.
    7. Frazzica, A. & Brancato, V. & Caprì, A. & Cannilla, C. & Gordeeva, L.G. & Aristov, Y.I., 2020. "Development of “salt in porous matrix” composites based on LiCl for sorption thermal energy storage," Energy, Elsevier, vol. 208(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Grabowska, K. & Sztekler, K. & Krzywanski, J. & Sosnowski, M. & Stefanski, S. & Nowak, W., 2021. "Construction of an innovative adsorbent bed configuration in the adsorption chiller part 2. experimental research of coated bed samples," Energy, Elsevier, vol. 215(PA).
    2. Askalany, Ahmed A. & Ernst, Sebastian-Johannes & Hügenell, Philipp P.C. & Bart, Hans-Jörg & Henninger, Stefan K. & Alsaman, Ahmed S., 2017. "High potential of employing bentonite in adsorption cooling systems driven by low grade heat source temperatures," Energy, Elsevier, vol. 141(C), pages 782-791.
    3. Askalany, Ahmed A. & Uddin, Kutub & Saha, Bidyut B. & Sultan, Muhammad & Santori, Giulio, 2022. "Water desalination by silica supported ionic liquid: Adsorption kinetics and system modeling," Energy, Elsevier, vol. 239(PD).
    4. Jingming Dong & Weining Wang & Zhitao Han & Hongbin Ma & Yangbo Deng & Fengmin Su & Xinxiang Pan, 2018. "Experimental Investigation of the Steam Ejector in a Single-Effect Thermal Vapor Compression Desalination System Driven by a Low-Temperature Heat Source," Energies, MDPI, vol. 11(9), pages 1-13, August.
    5. Long, Rui & Zhao, Yanan & Li, Mingliang & Pan, Yao & Liu, Zhichun & Liu, Wei, 2021. "Evaluations of adsorbents and salt-methanol solutions for low-grade heat driven osmotic heat engines," Energy, Elsevier, vol. 229(C).
    6. Crespo, Alicia & Fernández, Cèsar & Vérez, David & Tarragona, Joan & Borri, Emiliano & Frazzica, Andrea & Cabeza, Luisa F. & de Gracia, Alvaro, 2023. "Thermal performance assessment and control optimization of a solar-driven seasonal sorption storage system for residential application," Energy, Elsevier, vol. 263(PA).
    7. Palomba, Valeria & Sapienza, Alessio & Aristov, Yuri, 2019. "Dynamics and useful heat of the discharge stage of adsorptive cycles for long term thermal storage," Applied Energy, Elsevier, vol. 248(C), pages 299-309.
    8. Cabeza, Luisa F. & de Gracia, Alvaro & Zsembinszki, Gabriel & Borri, Emiliano, 2021. "Perspectives on thermal energy storage research," Energy, Elsevier, vol. 231(C).
    9. Alicia Crespo & Cèsar Fernández & Alvaro de Gracia & Andrea Frazzica, 2022. "Solar-Driven Sorption System for Seasonal Heat Storage under Optimal Control: Study for Different Climatic Zones," Energies, MDPI, vol. 15(15), pages 1-23, August.
    10. Gado, Mohamed G. & Ookawara, Shinichi & Nada, Sameh & El-Sharkawy, Ibrahim I., 2021. "Hybrid sorption-vapor compression cooling systems: A comprehensive overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    11. Aristov, Yu. I., 2022. "Adsorption heat conversion and storage in closed systems: What have we learned over the past decade of this century?," Energy, Elsevier, vol. 239(PB).
    12. Venegas, Tomas & Qu, Ming & Nawaz, Kashif & Wang, Lingshi, 2021. "Critical review and future prospects for desiccant coated heat exchangers: Materials, design, and manufacturing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    13. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2021. "Numerical analysis on the improved thermo-chemical behaviour of hierarchical energy materials as a cascaded thermal accumulator," Energy, Elsevier, vol. 232(C).
    14. Dorian Skrobek & Jaroslaw Krzywanski & Marcin Sosnowski & Anna Kulakowska & Anna Zylka & Karolina Grabowska & Katarzyna Ciesielska & Wojciech Nowak, 2020. "Prediction of Sorption Processes Using the Deep Learning Methods (Long Short-Term Memory)," Energies, MDPI, vol. 13(24), pages 1-16, December.
    15. Li, Qiyuan & Beier, Lisa-Jil & Tan, Joel & Brown, Celia & Lian, Boyue & Zhong, Wenwei & Wang, Yuan & Ji, Chao & Dai, Pan & Li, Tianyu & Le Clech, Pierre & Tyagi, Himanshu & Liu, Xuefei & Leslie, Greg , 2019. "An integrated, solar-driven membrane distillation system for water purification and energy generation," Applied Energy, Elsevier, vol. 237(C), pages 534-548.
    16. Xie, Guo & Sun, Licheng & Yan, Tiantong & Tang, Jiguo & Bao, Jingjing & Du, Min, 2018. "Model development and experimental verification for tubular solar still operating under vacuum condition," Energy, Elsevier, vol. 157(C), pages 115-130.
    17. Piero Bareschino & Francesco Pepe & Carlo Roselli & Maurizio Sasso & Francesco Tariello, 2019. "Desiccant-Based Air Handling Unit Alternatively Equipped with Three Hygroscopic Materials and Driven by Solar Energy," Energies, MDPI, vol. 12(8), pages 1-20, April.
    18. Aristov, Yu.I., 2021. "Adsorptive conversion of ultralow-temperature heat: Thermodynamic issues," Energy, Elsevier, vol. 236(C).
    19. Wu, X.N. & Ge, T.S. & Dai, Y.J. & Wang, R.Z., 2019. "Investigation on novel desiccant wheel using wood pulp fiber paper with high coating ratio as matrix," Energy, Elsevier, vol. 176(C), pages 493-504.
    20. Chao, Jingwei & Xu, Jiaxing & Yan, Taisen & Wang, Pengfei & Huo, Xiangyan & Wang, Ruzhu & Li, Tingxian, 2022. "Enhanced thermal conductivity and adsorption rate of zeolite 13X adsorbent by compression-induced molding method for sorption thermal battery," Energy, Elsevier, vol. 240(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:239:y:2022:i:pa:s0360544221021939. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.