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Determination of time constants of diffusion and electrochemical processes in Polymer Electrolyte Membrane Fuel Cells

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  • Iranzo, Alfredo
  • Navas, Sergio J.
  • Rosa, Felipe
  • Berber, Mohamed R.

Abstract

This work presents an experimental analysis of the time constants associated to diffusion and electrochemical processes in a 50 cm2 Polymer Electrolyte Membrane (PEM) fuel cell. The experimental techniques and results include polarization curves and Electrochemical Impedance Spectroscopy (EIS) analysis of the fuel cell, where the time constants are determined from the analysis of the Distribution of Relaxation Times (DRT). EIS results are also used to determine the cell ohmic resistance, where High Frequency Resistance (HFR) values are calculated from the Nyquist plots. A wide range of operating conditions of the fuel cell are analysed, including back pressure (0.5 bar–1 bar), cell temperature (55 °C, 65 °C, 75 °C), reactant gases relative humidity (30%, 60%, 90%), cathode stoichiometry (λc 2.5–3.5), and oxygen concentration (air and pure oxygen). The effect of the operating conditions on the time constants are discussed, and Damköhler number is introduced and discussed.

Suggested Citation

  • Iranzo, Alfredo & Navas, Sergio J. & Rosa, Felipe & Berber, Mohamed R., 2021. "Determination of time constants of diffusion and electrochemical processes in Polymer Electrolyte Membrane Fuel Cells," Energy, Elsevier, vol. 221(C).
    • Handle: RePEc:eee:energy:v:221:y:2021:i:c:s0360544221000827
    DOI: 10.1016/j.energy.2021.119833
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    References listed on IDEAS

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    Cited by:

    1. Suárez, Christian & Iranzo, Alfredo & Toharias, Baltasar & Rosa, Felipe, 2022. "Experimental and numerical Investigation on the design of a bioinspired PEM fuel cell," Energy, Elsevier, vol. 257(C).
    2. Cabello González, G.M. & Toharias, Baltasar & Iranzo, Alfredo & Suárez, Christian & Rosa, Felipe, 2023. "Voltage distribution analysis and non-uniformity assessment in a 100 cm2 PEM fuel cell stack," Energy, Elsevier, vol. 282(C).
    3. Li, Hui & Eghbalian, Nasrin, 2021. "Numerical studies of effect of integrated through-plane array flow field on novel PEFC performance using BWO algorithm under uncertainties," Energy, Elsevier, vol. 231(C).
    4. Liu, Jiaran & Tan, Jinzhu & Yang, Weizhan & Li, Yang & Wang, Chao, 2021. "Better electrochemical performance of PEMFC under a novel pneumatic clamping mechanism," Energy, Elsevier, vol. 229(C).

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