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Preparation and crystallization behavior of sensitive thermochromic microencapsulated phase change materials

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  • Zhang, Wenhui
  • Zhang, Hang
  • Liu, Shuhui
  • Zhang, Xingxiang
  • Li, Wei

Abstract

A novel sensitive thermo-chromic microcapsules with inorganic/organic nanoparticles-embedded composite shell was designed and synthesized, and the thermal properties, thermo-chromic performance, crystallization behavior of ethyl myristate (EM) in confined spaces were studied in this paper. As the reaction proceeded, the aminated silica (NH2-SiO2) nanoparticles modified outer shell in the aqueous phase and isophorone diisocyanate (IPDI) in the oil phase gradually self-assembled at the inner interface, leading to the formation of an inorganic/organic polymers composite shell. The effect of NH2-SiO2 nanoparticles content on the crystallization behavior, microstructure, morphology, and phase-change properties as well as the thermal stability of MPCMs were investigated in detail. Interestingly, the covalent attachment of NH2-SiO2 nanoparticles on the capsules surface offered long-term chemical stability compared to that of conventional physical adsorption. The NH2-SiO2 nanoparticles were found distributed uniformly on the surface of MPCMs, and the onset crystallization temperature of MPCMs increased by 7.3 °C with NH2-SiO2 nanoparticles addition of 15% content, which counteracts the super-cooling phenomenon. Microcapsule temperature change optical microscopy and non-isothermal crystallization kinetics revealed that the crystallization of RS-MPCMs were homogeneous as well. RS-MPCMs have significant potential in green energy applications due to their latent heat storage, thermal stability, thermal conductivity, leakage prevention, and mechanical properties.

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  • Zhang, Wenhui & Zhang, Hang & Liu, Shuhui & Zhang, Xingxiang & Li, Wei, 2024. "Preparation and crystallization behavior of sensitive thermochromic microencapsulated phase change materials," Applied Energy, Elsevier, vol. 362(C).
    • Handle: RePEc:eee:appene:v:362:y:2024:i:c:s0306261924003763
    DOI: 10.1016/j.apenergy.2024.122993
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