IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v196y2020ics0360544220301997.html
   My bibliography  Save this article

Experimental exergy analysis of transesterification in biodiesel production

Author

Listed:
  • Khoobbakht, Golmohammad
  • Kheiralipour, Kamran
  • Rasouli, Hamed
  • Rafiee, Mojtaba
  • Hadipour, Mehrdad
  • Karimi, Mahmoud

Abstract

Exergy flow analysis is applied to account wastes, determine the exergetic efficiency, compare substitutes and other types of energy sources and also define economic and environmental policies for resource use. The present study focuses on the exergy flow analysis of biodiesel production by esterification and transesterification of waste cooking canola oil to achieve benefits such as reducing material and energy consumptions and improving energy and exergy efficiencies. The input amounts of esterification for all the runs were kept constant, while the runs of transesterification were carried out in a variety of mass and energy input values as the experimental variables. The thermodynamics analysis was applied to determine exergy input and output of the system for the experimental runs. Impacts of experiment variables, including methanol:oil molar ratio, potassium hydroxide concentration and the reaction temperature of transesterification were evaluated on exergy efficiency and exergy loss in the transesterification. The maximum exergy efficiency (91.7%) and the minimum exergy loss (4320 kJ/kg biodiesel) were achieved at methanol:oil molar ratio of 8:1, potassium hydroxide concentration of 1 wt% and the reaction temperature of 55 °C. Excessive use of methanol and catalyst reduced the yield and the exergy efficiency through increasing exergy loss by waste materials.

Suggested Citation

  • Khoobbakht, Golmohammad & Kheiralipour, Kamran & Rasouli, Hamed & Rafiee, Mojtaba & Hadipour, Mehrdad & Karimi, Mahmoud, 2020. "Experimental exergy analysis of transesterification in biodiesel production," Energy, Elsevier, vol. 196(C).
    • Handle: RePEc:eee:energy:v:196:y:2020:i:c:s0360544220301997
    DOI: 10.1016/j.energy.2020.117092
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544220301997
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2020.117092?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Talens, Laura & Villalba, Gara & Gabarrell, Xavier, 2007. "Exergy analysis applied to biodiesel production," Resources, Conservation & Recycling, Elsevier, vol. 51(2), pages 397-407.
    2. Peralta-Ruiz, Y. & González-Delgado, A.-D. & Kafarov, V., 2013. "Evaluation of alternatives for microalgae oil extraction based on exergy analysis," Applied Energy, Elsevier, vol. 101(C), pages 226-236.
    3. Szargut, Jan, 1989. "Chemical exergies of the elements," Applied Energy, Elsevier, vol. 32(4), pages 269-286.
    4. Karimi, Mahmoud & Jenkins, Bryan & Stroeve, Pieter, 2014. "Ultrasound irradiation in the production of ethanol from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 400-421.
    5. Robert U. Ayres & Leslie W. Ayres, 1999. "Accounting for Resources, 2," Books, Edward Elgar Publishing, number 1621.
    6. Velásquez-Arredondo, H.I. & De Oliveira Junior, S. & Benjumea, P., 2012. "Exergy efficiency analysis of chemical and biochemical stages involved in liquid biofuels production processes," Energy, Elsevier, vol. 41(1), pages 138-145.
    7. Nguyen, Nghi & Demirel, Yaşar, 2010. "Retrofit of distillation columns in biodiesel production plants," Energy, Elsevier, vol. 35(4), pages 1625-1632.
    8. Blanco-Marigorta, A.M. & Suárez-Medina, J. & Vera-Castellano, A., 2013. "Exergetic analysis of a biodiesel production process from Jatropha curcas," Applied Energy, Elsevier, vol. 101(C), pages 218-225.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Camilo Andrés Guerrero-Martin & Juan Sebastián Fernández-Ramírez & Jaime Eduardo Arturo-Calvache & Harvey Andrés Milquez-Sanabria & Fernando Antonio da Silva Fernandes & Vando José Costa Gomes & Wanes, 2023. "Exergy Load Distribution Analysis Applied to the Dehydration of Ethanol by Extractive Distillation," Energies, MDPI, vol. 16(8), pages 1-14, April.
    2. José A. León & Gisela Montero & Marcos A. Coronado & José R. Ayala & Daniela G. Montes & Laura J. Pérez & Lisandra Quintana & Jesús M. Armenta, 2022. "Thermodynamic Analysis of Waste Vegetable Oil Conversion to Biodiesel with Solar Energy," Energies, MDPI, vol. 15(5), pages 1-17, March.
    3. Kheiralipour, Kamran & Khoobbakht, Mohammad & Karimi, Mahmoud, 2024. "Effect of biodiesel on environmental impacts of diesel mechanical power generation by life cycle assessment," Energy, Elsevier, vol. 289(C).
    4. Gollangi, Raju & K, NagamalleswaraRao, 2022. "Energy, exergy analysis of conceptually designed monochloromethane production process from hydrochlorination of methanol," Energy, Elsevier, vol. 239(PA).
    5. Wang, Qingqiang & Hou, Jili & Wei, Xing & Jin, Nan & Ma, Yue & Li, Shuyuan & Zhao, Yuchao, 2022. "Advanced exergoenvironmental analysis of the oil shale retorting process with SJ-type rectangular retort," Energy, Elsevier, vol. 260(C).
    6. Lim, Chun Hsion & Lim, Steven & How, Bing Shen & Ng, Wendy Pei Qin & Ngan, Sue Lin & Leong, Wei Dong & Lam, Hon Loong, 2021. "A review of industry 4.0 revolution potential in a sustainable and renewable palm oil industry: HAZOP approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    7. Elena Khan & Kadir Ozaltin & Damiano Spagnuolo & Andres Bernal-Ballen & Maxim V. Piskunov & Antonio Di Martino, 2023. "Biodiesel from Rapeseed and Sunflower Oil: Effect of the Transesterification Conditions and Oxidation Stability," Energies, MDPI, vol. 16(2), pages 1-13, January.
    8. Acaroglu, Mustafa & Baser, Eyup & Aydogan, Hasan & Canli, Eyüb, 2022. "A new energy crop onopordum spp.: A research on biofuel properties," Energy, Elsevier, vol. 261(PB).
    9. Khoobbakht, Golmohammad & Kheiralipour, Kamran & Yuan, Wenqiao & Seifi, Mohammad Reza & Karimi, Mahmoud, 2020. "Desirability function approach for optimization of enzymatic transesterification catalyzed by lipase immobilized on mesoporous magnetic nanoparticles," Renewable Energy, Elsevier, vol. 158(C), pages 253-262.
    10. Petchsoongsakul, Nattawat & Ngaosuwan, Kanokwan & Kiatkittipong, Worapon & Wongsawaeng, Doonyapong & Assabumrungrat, Suttichai, 2020. "Different water removal methods for facilitating biodiesel production from low-cost waste cooking oil containing high water content in hybridized reactive distillation," Renewable Energy, Elsevier, vol. 162(C), pages 1906-1918.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Amelio, A. & Van de Voorde, T. & Creemers, C. & Degrève, J. & Darvishmanesh, S. & Luis, P. & Van der Bruggen, B., 2016. "Comparison between exergy and energy analysis for biodiesel production," Energy, Elsevier, vol. 98(C), pages 135-145.
    2. Olusegun David Samuel & Peter A. Aigba & Thien Khanh Tran & H. Fayaz & Carlo Pastore & Oguzhan Der & Ali Erçetin & Christopher C. Enweremadu & Ahmad Mustafa, 2023. "Comparison of the Techno-Economic and Environmental Assessment of Hydrodynamic Cavitation and Mechanical Stirring Reactors for the Production of Sustainable Hevea brasiliensis Ethyl Ester," Sustainability, MDPI, vol. 15(23), pages 1-27, November.
    3. Khalili-Garakani, Amirhossein & Ivakpour, Javad & Kasiri, Norollah, 2016. "Evolutionary synthesis of optimum light ends recovery unit with exergy analysis application," Applied Energy, Elsevier, vol. 168(C), pages 507-522.
    4. Talens Peiró, L. & Villalba Méndez, G. & Sciubba, E. & Gabarrell i Durany, X., 2010. "Extended exergy accounting applied to biodiesel production," Energy, Elsevier, vol. 35(7), pages 2861-2869.
    5. Vargas-Parra, M. Violeta & Villalba, Gara & Gabarrell, Xavier, 2013. "Applying exergy analysis to rainwater harvesting systems to assess resource efficiency," Resources, Conservation & Recycling, Elsevier, vol. 72(C), pages 50-59.
    6. Gholami, Ali & Hajinezhad, Ahmad & Pourfayaz, Fathollah & Ahmadi, Mohammad Hossein, 2018. "The effect of hydrodynamic and ultrasonic cavitation on biodiesel production: An exergy analysis approach," Energy, Elsevier, vol. 160(C), pages 478-489.
    7. Liu, Fang & Chen, Guanyi & Yan, Beibei & Ma, Wenchao & Cheng, Zhanjun & Hou, Li'an, 2017. "Exergy analysis of a new lignocellulosic biomass-based polygeneration system," Energy, Elsevier, vol. 140(P1), pages 1087-1095.
    8. Ojeda, Karina & Sánchez, Eduardo & Kafarov, Viatcheslav, 2011. "Sustainable ethanol production from lignocellulosic biomass – Application of exergy analysis," Energy, Elsevier, vol. 36(4), pages 2119-2128.
    9. Teles dos Santos, Moisés & Park, Song Won, 2013. "Sustainability and biophysics basis of technical and economic processes: A survey of the reconciliation by thermodynamics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 261-271.
    10. Stanek, Wojciech & Czarnowska, Lucyna, 2018. "Thermo-ecological cost – Szargut's proposal on exergy and ecology connection," Energy, Elsevier, vol. 165(PB), pages 1050-1059.
    11. Liu, X.G. & He, C. & He, C.C. & Chen, J.J. & Zhang, B.J. & Chen, Q.L., 2017. "A new retrofit approach to the absorption-stabilization process for improving energy efficiency in refineries," Energy, Elsevier, vol. 118(C), pages 1131-1145.
    12. Genc, S. & Sorguven, E. & Ozilgen, M. & Aksan Kurnaz, I., 2013. "Unsteady exergy destruction of the neuron under dynamic stress conditions," Energy, Elsevier, vol. 59(C), pages 422-431.
    13. Peralta-Ruiz, Y. & González-Delgado, A.-D. & Kafarov, V., 2013. "Evaluation of alternatives for microalgae oil extraction based on exergy analysis," Applied Energy, Elsevier, vol. 101(C), pages 226-236.
    14. Chen, B. & Chen, G.Q., 2007. "Modified ecological footprint accounting and analysis based on embodied exergy--a case study of the Chinese society 1981-2001," Ecological Economics, Elsevier, vol. 61(2-3), pages 355-376, March.
    15. Waheed, M.A. & Oni, A.O. & Adejuyigbe, S.B. & Adewumi, B.A. & Fadare, D.A., 2014. "Performance enhancement of vapor recompression heat pump," Applied Energy, Elsevier, vol. 114(C), pages 69-79.
    16. Hao, Xiaoqing & An, Haizhong & Qi, Hai & Gao, Xiangyun, 2016. "Evolution of the exergy flow network embodied in the global fossil energy trade: Based on complex network," Applied Energy, Elsevier, vol. 162(C), pages 1515-1522.
    17. Chen, G.Q. & Qi, Z.H., 2007. "Systems account of societal exergy utilization: China 2003," Ecological Modelling, Elsevier, vol. 208(2), pages 102-118.
    18. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    19. Peters, Jens F. & Petrakopoulou, Fontina & Dufour, Javier, 2015. "Exergy analysis of synthetic biofuel production via fast pyrolysis and hydroupgrading," Energy, Elsevier, vol. 79(C), pages 325-336.
    20. Küçük, Kübra & Tevatia, Rahul & Sorgüven, Esra & Demirel, Yaşar & Özilgen, Mustafa, 2015. "Bioenergetics of growth and lipid production in Chlamydomonas reinhardtii," Energy, Elsevier, vol. 83(C), pages 503-510.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:196:y:2020:i:c:s0360544220301997. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.