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Experimental exergy analysis of transesterification in biodiesel production

Author

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  • Khoobbakht, Golmohammad
  • Kheiralipour, Kamran
  • Rasouli, Hamed
  • Rafiee, Mojtaba
  • Hadipour, Mehrdad
  • Karimi, Mahmoud

Abstract

Exergy flow analysis is applied to account wastes, determine the exergetic efficiency, compare substitutes and other types of energy sources and also define economic and environmental policies for resource use. The present study focuses on the exergy flow analysis of biodiesel production by esterification and transesterification of waste cooking canola oil to achieve benefits such as reducing material and energy consumptions and improving energy and exergy efficiencies. The input amounts of esterification for all the runs were kept constant, while the runs of transesterification were carried out in a variety of mass and energy input values as the experimental variables. The thermodynamics analysis was applied to determine exergy input and output of the system for the experimental runs. Impacts of experiment variables, including methanol:oil molar ratio, potassium hydroxide concentration and the reaction temperature of transesterification were evaluated on exergy efficiency and exergy loss in the transesterification. The maximum exergy efficiency (91.7%) and the minimum exergy loss (4320 kJ/kg biodiesel) were achieved at methanol:oil molar ratio of 8:1, potassium hydroxide concentration of 1 wt% and the reaction temperature of 55 °C. Excessive use of methanol and catalyst reduced the yield and the exergy efficiency through increasing exergy loss by waste materials.

Suggested Citation

  • Khoobbakht, Golmohammad & Kheiralipour, Kamran & Rasouli, Hamed & Rafiee, Mojtaba & Hadipour, Mehrdad & Karimi, Mahmoud, 2020. "Experimental exergy analysis of transesterification in biodiesel production," Energy, Elsevier, vol. 196(C).
    • Handle: RePEc:eee:energy:v:196:y:2020:i:c:s0360544220301997
    DOI: 10.1016/j.energy.2020.117092
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    3. Kheiralipour, Kamran & Khoobbakht, Mohammad & Karimi, Mahmoud, 2024. "Effect of biodiesel on environmental impacts of diesel mechanical power generation by life cycle assessment," Energy, Elsevier, vol. 289(C).
    4. Gollangi, Raju & K, NagamalleswaraRao, 2022. "Energy, exergy analysis of conceptually designed monochloromethane production process from hydrochlorination of methanol," Energy, Elsevier, vol. 239(PA).
    5. Wang, Qingqiang & Hou, Jili & Wei, Xing & Jin, Nan & Ma, Yue & Li, Shuyuan & Zhao, Yuchao, 2022. "Advanced exergoenvironmental analysis of the oil shale retorting process with SJ-type rectangular retort," Energy, Elsevier, vol. 260(C).
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    7. Elena Khan & Kadir Ozaltin & Damiano Spagnuolo & Andres Bernal-Ballen & Maxim V. Piskunov & Antonio Di Martino, 2023. "Biodiesel from Rapeseed and Sunflower Oil: Effect of the Transesterification Conditions and Oxidation Stability," Energies, MDPI, vol. 16(2), pages 1-13, January.
    8. Acaroglu, Mustafa & Baser, Eyup & Aydogan, Hasan & Canli, Eyüb, 2022. "A new energy crop onopordum spp.: A research on biofuel properties," Energy, Elsevier, vol. 261(PB).
    9. Khoobbakht, Golmohammad & Kheiralipour, Kamran & Yuan, Wenqiao & Seifi, Mohammad Reza & Karimi, Mahmoud, 2020. "Desirability function approach for optimization of enzymatic transesterification catalyzed by lipase immobilized on mesoporous magnetic nanoparticles," Renewable Energy, Elsevier, vol. 158(C), pages 253-262.
    10. Petchsoongsakul, Nattawat & Ngaosuwan, Kanokwan & Kiatkittipong, Worapon & Wongsawaeng, Doonyapong & Assabumrungrat, Suttichai, 2020. "Different water removal methods for facilitating biodiesel production from low-cost waste cooking oil containing high water content in hybridized reactive distillation," Renewable Energy, Elsevier, vol. 162(C), pages 1906-1918.

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