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HCFO-1224yd(Z) as HFC-245fa drop-in alternative in low temperature ORC systems: Experimental analysis in a waste heat recovery real facility

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  • Navarro-Esbrí, Joaquín
  • Amat-Albuixech, Marta
  • Molés, Francisco
  • Mateu-Royo, Carlos
  • Mota-Babiloni, Adrián
  • Collado, Roberto

Abstract

The organic Rankine cycle (ORC) has been growing in importance as a technology for producing electricity from low temperature waste and renewable heat sources. In small-scale applications, the most used working fluid has been HFC-245fa, although this is being substituted for low GWP alternatives. A new HCFO working fluid, HCFO-1224yd(Z), has appeared as a possible alternative for HFC-245fa. In this study, this alternative working fluid is analysed and, finally, the working fluid is experimentally tested as drop-in alternative in a commercial ORC system. The main purpose is to determine the feasibility of using HCFO-1224yd(Z) as a drop-in replacement for HFC-245fa in a real facility that was initially designed to operate with HFC-245fa. The results show how the use of HCFO-1224yd(Z) offers power output that ranges from 7.5% to 17.4% lower than that provided by HFC-245fa. Although HFC-245fa offers higher power output, the results show that HCFO-1224yd(Z) offers up to 7.7% higher cycle net efficiency; this is due to the higher input thermal rate required by HFC-245fa. Finally, HCFO-1224yd(Z) has been stated as a suitable alternative to HFC-245fa as a drop-in replacement in a small-scale, low-temperature ORC, which increases its attractiveness for heat source with higher temperatures.

Suggested Citation

  • Navarro-Esbrí, Joaquín & Amat-Albuixech, Marta & Molés, Francisco & Mateu-Royo, Carlos & Mota-Babiloni, Adrián & Collado, Roberto, 2020. "HCFO-1224yd(Z) as HFC-245fa drop-in alternative in low temperature ORC systems: Experimental analysis in a waste heat recovery real facility," Energy, Elsevier, vol. 193(C).
    • Handle: RePEc:eee:energy:v:193:y:2020:i:c:s0360544219323965
    DOI: 10.1016/j.energy.2019.116701
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    1. Dawo, Fabian & Fleischmann, Jonas & Kaufmann, Florian & Schifflechner, Christopher & Eyerer, Sebastian & Wieland, Christoph & Spliethoff, Hartmut, 2021. "R1224yd(Z), R1233zd(E) and R1336mzz(Z) as replacements for R245fa: Experimental performance, interaction with lubricants and environmental impact," Applied Energy, Elsevier, vol. 288(C).
    2. Giménez-Prades, P. & Navarro-Esbrí, J. & Arpagaus, C. & Fernández-Moreno, A. & Mota-Babiloni, A., 2022. "Novel molecules as working fluids for refrigeration, heat pump and organic Rankine cycle systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    3. Al-Sayyab, Ali Khalid Shaker & Mota-Babiloni, Adrián & Navarro-Esbrí, Joaquín, 2023. "Performance evaluation of modified compound organic Rankine-vapour compression cycle with two cooling levels, heating, and power generation," Applied Energy, Elsevier, vol. 334(C).

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