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Characterization of solid char produced from pyrolysis of the organic fraction of municipal solid waste, high volatile coal and their blends

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  • Tokmurzin, Diyar
  • Kuspangaliyeva, Botagoz
  • Aimbetov, Berik
  • Abylkhani, Bexultan
  • Inglezakis, Vassilis
  • Anthony, Edward J.
  • Sarbassov, Yerbol

Abstract

In this study, the organic fraction of municipal solid waste (Org-MSW) was blended with high-volatile coal (HVC) in proportions of 25/75%, 50/50%, 75/25% by weight. Pyrolysis of these mixtures was then investigated in a thermogravimetric analyzer (TGA) and a horizontal tube furnace under a nitrogen environment. The mass loss rate of samples, differential thermogravimetry (DTG) curves and kinetic analysis of the samples were compared for both blended and non-blended samples. Higher gas yields were seen with increasing pyrolysis temperature for both samples. In addition, the kinetic analysis indicated that the apparent activation energy values of org-MSW samples varied from 535 to 5284 kJ/kmol (over the temperature range of 100–887 °C), while the values for HVC were 247–962 kJ/kmol. The activation energy for HVC varied with temperature and the highest value of 2036 kJ/kmol was found in the temperature range of 336–490 °C. Comparable results were obtained between the TGA and fixed bed tests on the residual char fraction. The findings of this work will be very important in developing a co-firing technology for solid waste residuals and coal for energy production.

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  • Tokmurzin, Diyar & Kuspangaliyeva, Botagoz & Aimbetov, Berik & Abylkhani, Bexultan & Inglezakis, Vassilis & Anthony, Edward J. & Sarbassov, Yerbol, 2020. "Characterization of solid char produced from pyrolysis of the organic fraction of municipal solid waste, high volatile coal and their blends," Energy, Elsevier, vol. 191(C).
    • Handle: RePEc:eee:energy:v:191:y:2020:i:c:s0360544219322571
    DOI: 10.1016/j.energy.2019.116562
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    2. Sun, Hao & Bi, Haobo & Jiang, Chunlong & Ni, Zhanshi & Tian, Junjian & Zhou, Wenliang & Qiu, Zhicong & Lin, Qizhao, 2022. "Experimental study of the co-pyrolysis of sewage sludge and wet waste via TG-FTIR-GC and artificial neural network model: Synergistic effect, pyrolysis kinetics and gas products," Renewable Energy, Elsevier, vol. 184(C), pages 1-14.
    3. Duque, João Vitor F. & Bittencourt, Flávio L.F. & Martins, Márcio F. & Debenest, Gérald, 2021. "Developing a combustion-driven reactor for waste conversion," Energy, Elsevier, vol. 237(C).
    4. Zhang, Wenlong & Zhang, Juan & Ding, Yanming & Zhou, Ru & Mao, Shaohua, 2022. "The accuracy of multiple methods for estimating the reaction order of representative thermoplastic polymers waste for energy utilization," Energy, Elsevier, vol. 239(PB).
    5. Adnan, Muflih A. & Hossain, Mohammad M. & Golam Kibria, Md, 2022. "Converting waste into fuel via integrated thermal and electrochemical routes: An analysis of thermodynamic approach on thermal conversion," Applied Energy, Elsevier, vol. 311(C).

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