IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v189y2019ics0360544219318547.html
   My bibliography  Save this article

A novel insight into biomass pyrolysis – The process analysis by identifying timescales of heat diffusion, heating rate and reaction rate

Author

Listed:
  • Kardaś, Dariusz
  • Hercel, Paulina
  • Polesek-Karczewska, Sylwia
  • Wardach-Świȩcicka, Izabela

Abstract

The complex nature of pyrolysis that involves coupled physical and chemical sub-processes is a bottleneck for its in-depth recognition. This is also due to physical-chemical parameters, which appear insufficiently identified, particularly for biomass. This study is motivated by the inconsistencies in the description of wood pyrolysis processes and primarily refers to the uncertainties in terms of kinetics of reaction. A new approach to analyze the biomass devolatilization was discussed. A strong emphasis was placed on the crucial role of thermal transport processes and their impact on the kinetics of pyrolysis of a single sample. Characteristic timescales influencing each other, namely: heating rate, heat transfer and reaction rates, were considered. The theoretical research was conducted with a use of a simple two-equation model. A standard heat transfer equation for the sample and a mass conservation equation with slightly different approach were implemented. Mass loss curves and temperature profiles were presented for very low heating rate (1.7K/min) and high heating rate (170K/min) for samples of size ranging from 0.49 mm to 15.4 mm, while assuming different reaction rates. Based on the calculation results, the possible role of the process timescales in analysing the kinetics of pyrolysis was outlined.

Suggested Citation

  • Kardaś, Dariusz & Hercel, Paulina & Polesek-Karczewska, Sylwia & Wardach-Świȩcicka, Izabela, 2019. "A novel insight into biomass pyrolysis – The process analysis by identifying timescales of heat diffusion, heating rate and reaction rate," Energy, Elsevier, vol. 189(C).
  • Handle: RePEc:eee:energy:v:189:y:2019:i:c:s0360544219318547
    DOI: 10.1016/j.energy.2019.116159
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219318547
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2019.116159?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Van de Velden, Manon & Baeyens, Jan & Brems, Anke & Janssens, Bart & Dewil, Raf, 2010. "Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction," Renewable Energy, Elsevier, vol. 35(1), pages 232-242.
    2. Ábrego, Javier & Plaza, Daniel & Luño, Francisco & Atienza-Martínez, María & Gea, Gloria, 2018. "Pyrolysis of cashew nutshells: Characterization of products and energy balance," Energy, Elsevier, vol. 158(C), pages 72-80.
    3. Wijaya, Willy Yanto & Kawasaki, Shunsuke & Watanabe, Hirotatsu & Okazaki, Ken, 2012. "Damköhler number as a descriptive parameter in methanol steam reforming and its integration with absorption heat pump system," Applied Energy, Elsevier, vol. 94(C), pages 141-147.
    4. Makkawi, Yassir & El Sayed, Yehya & Salih, Mubarak & Nancarrow, Paul & Banks, Scott & Bridgwater, Tony, 2019. "Fast pyrolysis of date palm (Phoenix dactylifera) waste in a bubbling fluidized bed reactor," Renewable Energy, Elsevier, vol. 143(C), pages 719-730.
    5. Liu, Jiazheng & Zhong, Fei & Niu, Wenjuan & Su, Jing & Gao, Ziqi & Zhang, Kai, 2019. "Effects of heating rate and gas atmosphere on the pyrolysis and combustion characteristics of different crop residues and the kinetics analysis," Energy, Elsevier, vol. 175(C), pages 320-332.
    6. Zhong, Hanbin & Xiong, Qingang & Zhu, Yuqin & Liang, Shengrong & Zhang, Juntao & Niu, Ben & Zhang, Xinyu, 2019. "CFD modeling of the effects of particle shrinkage and intra-particle heat conduction on biomass fast pyrolysis," Renewable Energy, Elsevier, vol. 141(C), pages 236-245.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wardach-Świȩcicka, Izabela & Kardaś, Dariusz, 2021. "Modelling thermal behaviour of a single solid particle pyrolysing in a hot gas flow," Energy, Elsevier, vol. 221(C).
    2. Xiao, Ruirui & Yang, Wei & Cong, Xingshun & Dong, Kai & Xu, Jie & Wang, Dengfeng & Yang, Xin, 2020. "Thermogravimetric analysis and reaction kinetics of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 201(C).
    3. Kardaś, Dariusz & Hercel, Paulina & Wardach-Świȩcicka, Izabela & Polesek-Karczewska, Sylwia, 2021. "On the kinetic rate of biomass particle decomposition - Experimental and numerical analysis," Energy, Elsevier, vol. 219(C).
    4. Kantorek, Marcin & Jesionek, Krzysztof & Polesek-Karczewska, Sylwia & Ziółkowski, Paweł & Stajnke, Michał & Badur, Janusz, 2021. "Thermal utilization of meat-and-bone meal using the rotary kiln pyrolyzer and the fluidized bed boiler – The performance of pilot-scale installation," Renewable Energy, Elsevier, vol. 164(C), pages 1447-1456.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Kardaś, Dariusz & Hercel, Paulina & Wardach-Świȩcicka, Izabela & Polesek-Karczewska, Sylwia, 2021. "On the kinetic rate of biomass particle decomposition - Experimental and numerical analysis," Energy, Elsevier, vol. 219(C).
    2. Ábrego, J. & Atienza-Martínez, M. & Plou, F. & Arauzo, J., 2019. "Heat requirement for fixed bed pyrolysis of beechwood chips," Energy, Elsevier, vol. 178(C), pages 145-157.
    3. Brillard, A. & Brilhac, J.F., 2020. "Improvements of global models for the determination of the kinetic parameters associated to the thermal degradation of lignocellulosic materials under low heating rates," Renewable Energy, Elsevier, vol. 146(C), pages 1498-1509.
    4. López-González, D. & Puig-Gamero, M. & Acién, F.G. & García-Cuadra, F. & Valverde, J.L. & Sanchez-Silva, L., 2015. "Energetic, economic and environmental assessment of the pyrolysis and combustion of microalgae and their oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1752-1770.
    5. M. N. Uddin & Kuaanan Techato & Juntakan Taweekun & Md Mofijur Rahman & M. G. Rasul & T. M. I. Mahlia & S. M. Ashrafur, 2018. "An Overview of Recent Developments in Biomass Pyrolysis Technologies," Energies, MDPI, vol. 11(11), pages 1-24, November.
    6. Wang, Guoqiang & Wang, Feng & Li, Longjian & Zhang, Guofu, 2013. "Experiment of catalyst activity distribution effect on methanol steam reforming performance in the packed bed plate-type reactor," Energy, Elsevier, vol. 51(C), pages 267-272.
    7. Mouna Gmar & Hassine Bouafif & Besma Bouslimi & Flavia L. Braghiroli & Ahmed Koubaa, 2022. "Pyrolysis of Chromated Copper Arsenate-Treated Wood: Investigation of Temperature, Granulometry, Biochar Yield, and Metal Pathways," Energies, MDPI, vol. 15(14), pages 1-15, July.
    8. Amutio, M. & Lopez, G. & Artetxe, M. & Elordi, G. & Olazar, M. & Bilbao, J., 2012. "Influence of temperature on biomass pyrolysis in a conical spouted bed reactor," Resources, Conservation & Recycling, Elsevier, vol. 59(C), pages 23-31.
    9. Yimin Deng & Renaud Ansart & Jan Baeyens & Huili Zhang, 2019. "Flue Gas Desulphurization in Circulating Fluidized Beds," Energies, MDPI, vol. 12(20), pages 1-19, October.
    10. Juan Luis Aguirre & Juan Baena & María Teresa Martín & Leonor Nozal & Sergio González & José Luis Manjón & Manuel Peinado, 2020. "Composition, Ageing and Herbicidal Properties of Wood Vinegar Obtained through Fast Biomass Pyrolysis," Energies, MDPI, vol. 13(10), pages 1-17, May.
    11. Liu, Hui & Liu, Jingyong & Huang, Hongyi & Evrendilek, Fatih & Wen, Shaoting & Li, Weixin, 2021. "Optimizing bioenergy and by-product outputs from durian shell pyrolysis," Renewable Energy, Elsevier, vol. 164(C), pages 407-418.
    12. Campuzano, Felipe & Brown, Robert C. & Martínez, Juan Daniel, 2019. "Auger reactors for pyrolysis of biomass and wastes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 102(C), pages 372-409.
    13. Collazo, Joaquín & Pazó, José Antonio & Granada, Enrique & Saavedra, Ángeles & Eguía, Pablo, 2012. "Determination of the specific heat of biomass materials and the combustion energy of coke by DSC analysis," Energy, Elsevier, vol. 45(1), pages 746-752.
    14. Xing, Jiangkuan & Wang, Haiou & Luo, Kun & Wang, Shuai & Bai, Yun & Fan, Jianren, 2019. "Predictive single-step kinetic model of biomass devolatilization for CFD applications: A comparison study of empirical correlations (EC), artificial neural networks (ANN) and random forest (RF)," Renewable Energy, Elsevier, vol. 136(C), pages 104-114.
    15. Xin, Yu & Xing, Xueli & Li, Xiang & Hong, Hui, 2024. "A biomass–solar hybrid gasification system by solar pyrolysis and PV– Solid oxide electrolysis cell for sustainable fuel production," Applied Energy, Elsevier, vol. 356(C).
    16. Gojiya, Anil & Deb, Dipankar & Iyer, Kannan K.R., 2019. "Feasibility study of power generation from agricultural residue in comparison with soil incorporation of residue," Renewable Energy, Elsevier, vol. 134(C), pages 416-425.
    17. Wang, Cui & Zhu, Chao & Huang, Jianbing & Li, Linfeng & Jin, Hui, 2021. "Enhancement of depolymerization slag gasification in supercritical water and its gasification performance in fluidized bed reactor," Renewable Energy, Elsevier, vol. 168(C), pages 829-837.
    18. Ortiz, Leandro Rodriguez & Torres, Erick & Zalazar, Daniela & Zhang, Huili & Rodriguez, Rosa & Mazza, Germán, 2020. "Influence of pyrolysis temperature and bio-waste composition on biochar characteristics," Renewable Energy, Elsevier, vol. 155(C), pages 837-847.
    19. Dong, Leilei & Alexiadis, Alessio, 2023. "Simulation of char burnout characteristics of biomass/coal blend with a simplified single particle reaction model," Energy, Elsevier, vol. 264(C).
    20. Lupa, Christopher J. & Wylie, Steve R. & Shaw, Andrew & Al-Shamma'a, Ahmed & Sweetman, Andrew J. & Herbert, Ben M.J., 2013. "Gas evolution and syngas heating value from advanced thermal treatment of waste using microwave-induced plasma," Renewable Energy, Elsevier, vol. 50(C), pages 1065-1072.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:189:y:2019:i:c:s0360544219318547. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.