IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v152y2018icp1-12.html
   My bibliography  Save this article

Enhanced devolatilization during torrefaction of blended biomass streams results in additive heating values and synergistic oxidation behavior of solid fuels

Author

Listed:
  • Xue, Junjie
  • Goldfarb, Jillian L.

Abstract

Torrefaction improves energy density, grindability, and hydrophobicity of raw biomass for gasification and combustion. While literature focuses on single biomass torrefaction, industrial production is likely to be from biomass mixtures. To address this knowledge gap, we torrefied three raw biomasses (pistachio nutshells, feed corn stover, cherry pits) at 250 °C, as “pure” biomasses and in multiple component mixtures to understand if synergistic interactions during torrefaction impact oxidation behavior of resulting solid fuels. The combustion enthalpies of blended biomasses were well predicted by an additive function, whereby a blend's property was the mass-weighted average of each biomass' torrefied property. However, synergistic effects that enhanced devolatilization when biomasses were comingled during torrefaction led to systemically lower volatile matter contents and higher surface areas of resulting solid fuels. This synergistic behavior continues in terms of activation energy of oxidation of the torrefied samples. Co-torrefaction of biomass may lead to a solid fuel with predictable heat content, but synergistic effects lead to oxidation of blended streams at different rates and activation energies, with blends often having lower reactivities and higher activation energies than an “additive” prediction of pure fuel components. This is attributed to enhanced devolatilization among biomasses, leading to more condensed carbonaceous solids.

Suggested Citation

  • Xue, Junjie & Goldfarb, Jillian L., 2018. "Enhanced devolatilization during torrefaction of blended biomass streams results in additive heating values and synergistic oxidation behavior of solid fuels," Energy, Elsevier, vol. 152(C), pages 1-12.
    • Handle: RePEc:eee:energy:v:152:y:2018:i:c:p:1-12
    DOI: 10.1016/j.energy.2018.03.037
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218304390
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.03.037?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Li, Jun & Brzdekiewicz, Artur & Yang, Weihong & Blasiak, Wlodzimierz, 2012. "Co-firing based on biomass torrefaction in a pulverized coal boiler with aim of 100% fuel switching," Applied Energy, Elsevier, vol. 99(C), pages 344-354.
    2. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as torrefaction of some basic constituents in biomass," Energy, Elsevier, vol. 36(2), pages 803-811.
    3. Proskurina, Svetlana & Heinimö, Jussi & Schipfer, Fabian & Vakkilainen, Esa, 2017. "Biomass for industrial applications: The role of torrefaction," Renewable Energy, Elsevier, vol. 111(C), pages 265-274.
    4. Xue, Junjie & Chellappa, Thiago & Ceylan, Selim & Goldfarb, Jillian L., 2018. "Enhancing biomass + coal Co-firing scenarios via biomass torrefaction and carbonization: Case study of avocado pit biomass and Illinois No. 6 coal," Renewable Energy, Elsevier, vol. 122(C), pages 152-162.
    5. Granados, D.A. & Velásquez, H.I. & Chejne, F., 2014. "Energetic and exergetic evaluation of residual biomass in a torrefaction process," Energy, Elsevier, vol. 74(C), pages 181-189.
    6. Kajina, Wanida & Rousset, Patrick & Chen, Wei-Hsin & Sornpitak, Thitima & Commandré, Jean Michel, 2018. "Coupled effect of torrefaction and blending on chemical and energy properties for combustion of major open burned agriculture residues in Thailand," Renewable Energy, Elsevier, vol. 118(C), pages 113-121.
    7. Kambo, Harpreet Singh & Dutta, Animesh, 2014. "Strength, storage, and combustion characteristics of densified lignocellulosic biomass produced via torrefaction and hydrothermal carbonization," Applied Energy, Elsevier, vol. 135(C), pages 182-191.
    8. Park, Sang-Woo & Jang, Cheol-Hyeon & Baek, Kyung-Ryul & Yang, Jae-Kyung, 2012. "Torrefaction and low-temperature carbonization of woody biomass: Evaluation of fuel characteristics of the products," Energy, Elsevier, vol. 45(1), pages 676-685.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wang, Ziliang & Lim, C. Jim & Grace, John R., 2019. "A comprehensive study of sawdust torrefaction in a dual-compartment slot-rectangular spouted bed reactor," Energy, Elsevier, vol. 189(C).
    2. Bajwa, Dilpreet S. & Peterson, Tyler & Sharma, Neeta & Shojaeiarani, Jamileh & Bajwa, Sreekala G., 2018. "A review of densified solid biomass for energy production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 96(C), pages 296-305.
    3. Zhang, Congyu & Ho, Shih-Hsin & Chen, Wei-Hsin & Fu, Yujie & Chang, Jo-Shu & Bi, Xiaotao, 2019. "Oxidative torrefaction of biomass nutshells: Evaluations of energy efficiency as well as biochar transportation and storage," Applied Energy, Elsevier, vol. 235(C), pages 428-441.
    4. A. Silveira, Edgar & Santanna Chaves, Bruno & Macedo, Lucélia & Ghesti, Grace F. & Evaristo, Rafael B.W. & Cruz Lamas, Giulia & Luz, Sandra M. & Protásio, Thiago de Paula & Rousset, Patrick, 2023. "A hybrid optimization approach towards energy recovery from torrefied waste blends," Renewable Energy, Elsevier, vol. 212(C), pages 151-165.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Batidzirai, B. & Mignot, A.P.R. & Schakel, W.B. & Junginger, H.M. & Faaij, A.P.C., 2013. "Biomass torrefaction technology: Techno-economic status and future prospects," Energy, Elsevier, vol. 62(C), pages 196-214.
    2. Tran, Khanh-Quang & Luo, Xun & Seisenbaeva, Gulaim & Jirjis, Raida, 2013. "Stump torrefaction for bioenergy application," Applied Energy, Elsevier, vol. 112(C), pages 539-546.
    3. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    4. Seok-Jun Kim & Kwang-Cheol Oh & Sun-Yong Park & Young-Min Ju & La-Hoon Cho & Chung-Geon Lee & Min-Jun Kim & In-Seon Jeong & Dae-Hyun Kim, 2021. "Development and Validation of Mass Reduction Prediction Model and Analysis of Fuel Properties for Agro-Byproduct Torrefaction," Energies, MDPI, vol. 14(19), pages 1-14, September.
    5. Abdulyekeen, Kabir Abogunde & Umar, Ahmad Abulfathi & Patah, Muhamad Fazly Abdul & Daud, Wan Mohd Ashri Wan, 2021. "Torrefaction of biomass: Production of enhanced solid biofuel from municipal solid waste and other types of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    6. Qi, Jianhui & Zhao, Jianli & Xu, Yang & Wang, Yongjia & Han, Kuihua, 2018. "Segmented heating carbonization of biomass: Yields, property and estimation of heating value of chars," Energy, Elsevier, vol. 144(C), pages 301-311.
    7. Po-Chih Kuo & Wei Wu, 2014. "Design, Optimization and Energetic Efficiency of Producing Hydrogen-Rich Gas from Biomass Steam Gasification," Energies, MDPI, vol. 8(1), pages 1-17, December.
    8. Jaime Martín-Pascual & Joaquín Jódar & Miguel L. Rodríguez & Montserrat Zamorano, 2020. "Determination of the Optimal Operative Conditions for the Torrefaction of Olive Waste Biomass," Sustainability, MDPI, vol. 12(16), pages 1-11, August.
    9. Jorge Miguel Carneiro Ribeiro & Radu Godina & João Carlos de Oliveira Matias & Leonel Jorge Ribeiro Nunes, 2018. "Future Perspectives of Biomass Torrefaction: Review of the Current State-Of-The-Art and Research Development," Sustainability, MDPI, vol. 10(7), pages 1-17, July.
    10. Xue, Junjie & Chellappa, Thiago & Ceylan, Selim & Goldfarb, Jillian L., 2018. "Enhancing biomass + coal Co-firing scenarios via biomass torrefaction and carbonization: Case study of avocado pit biomass and Illinois No. 6 coal," Renewable Energy, Elsevier, vol. 122(C), pages 152-162.
    11. Gangil, Sandip & Bhargav, Vinod Kumar, 2018. "Influence of torrefaction on intrinsic bioconstituents of cotton stalk: TG-insights," Energy, Elsevier, vol. 142(C), pages 1066-1073.
    12. Adeleke, Adekunle A. & Ikubanni, Peter P. & Emmanuel, Stephen S. & Fajobi, Moses O. & Nwachukwu, Praise & Adesibikan, Ademidun A. & Odusote, Jamiu K. & Adeyemi, Emmanuel O. & Abioye, Oluwaseyi M. & Ok, 2024. "A comprehensive review on the similarity and disparity of torrefied biomass and coal properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    13. Sermyagina, Ekaterina & Saari, Jussi & Zakeri, Behnam & Kaikko, Juha & Vakkilainen, Esa, 2015. "Effect of heat integration method and torrefaction temperature on the performance of an integrated CHP-torrefaction plant," Applied Energy, Elsevier, vol. 149(C), pages 24-34.
    14. Yek, Peter Nai Yuh & Chen, Xiangmeng & Peng, Wanxi & Liew, Rock Keey & Cheng, Chin Kui & Sonne, Christian & Sii, How Sing & Lam, Su Shiung, 2021. "Microwave co-torrefaction of waste oil and biomass pellets for simultaneous recovery of waste and co-firing fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    15. Chen, Yun-Chun & Chen, Wei-Hsin & Lin, Bo-Jhih & Chang, Jo-Shu & Ong, Hwai Chyuan, 2016. "Impact of torrefaction on the composition, structure and reactivity of a microalga residue," Applied Energy, Elsevier, vol. 181(C), pages 110-119.
    16. Brojolall, Neeha & Surroop, Dinesh, 2022. "Improving fuel characteristics through torrefaction," Energy, Elsevier, vol. 246(C).
    17. Wilk, Małgorzata & Magdziarz, Aneta & Kalemba, Izabela, 2015. "Characterisation of renewable fuels' torrefaction process with different instrumental techniques," Energy, Elsevier, vol. 87(C), pages 259-269.
    18. Wang, Shurong & Dai, Gongxin & Ru, Bin & Zhao, Yuan & Wang, Xiaoliu & Xiao, Gang & Luo, Zhongyang, 2017. "Influence of torrefaction on the characteristics and pyrolysis behavior of cellulose," Energy, Elsevier, vol. 120(C), pages 864-871.
    19. Granados, D.A. & Ruiz, R.A. & Vega, L.Y. & Chejne, F., 2017. "Study of reactivity reduction in sugarcane bagasse as consequence of a torrefaction process," Energy, Elsevier, vol. 139(C), pages 818-827.
    20. Muhammet Enes Önür & Kamil Ekinci & Mihriban Civan & Mehmet Emin Bilgili & Sema Yurdakul, 2023. "Quality Properties and Torrefaction Characteristics of Pellets: Rose Oil Distillation Solid Waste and Red Pine Sawdust," Sustainability, MDPI, vol. 15(14), pages 1-16, July.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:152:y:2018:i:c:p:1-12. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.