IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v148y2018icp802-808.html
   My bibliography  Save this article

Characterization of products from Fe(CO)5 seeded CO diffusion flame

Author

Listed:
  • Kim, Kibum
  • Kim, Hae Kwang

Abstract

Although Iron Pentacarbonyl (Fe(CO)5), one of common metallic additives has been applied to soot emission suppression in a few decades, the correct mechanism on soot reduction is not well-understood and still far controversial. Particular species presented in the flame could provide valuable information on the mechanisms of chemical reactions. With the fact in mind, the state of the fuel additive was identified using a variety of laser-based diagnostics and spectroscopic methods such as in situ Raman spectroscopy, laser-induced fluorescence (LIF), laser-induced breakdown spectroscopy, absorption spectroscopy, and X-ray photoelectron spectroscopy. Preliminary sets of experiments were conducted with Fe(CO)5 seeded CO diffusion flame for eliminating the external environment interferences and variations due to soot particles that are normally produced from hydrocarbon fuel combustion. Any specific form of iron oxide was hardly detected while strong Fe signal was observed with in situ analyses. The analytical results indicate that elemental Fe play crucial role as heterogeneous catalyst on carbon oxidation in any carbon-based fuel diffusion flame.

Suggested Citation

  • Kim, Kibum & Kim, Hae Kwang, 2018. "Characterization of products from Fe(CO)5 seeded CO diffusion flame," Energy, Elsevier, vol. 148(C), pages 802-808.
  • Handle: RePEc:eee:energy:v:148:y:2018:i:c:p:802-808
    DOI: 10.1016/j.energy.2018.01.095
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218301130
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2018.01.095?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kim, Kibum & Hahn, David W., 2016. "Interaction between iron based compound and soot particles in diffusion flame," Energy, Elsevier, vol. 116(P1), pages 933-941.
    2. Ma, Yu & Zhu, Mingming & Zhang, Dongke, 2013. "The effect of a homogeneous combustion catalyst on exhaust emissions from a single cylinder diesel engine," Applied Energy, Elsevier, vol. 102(C), pages 556-562.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Sung-Hun Son & Kibum Kim, 2020. "Simulation Model of Regenerative LNG Refrigeration System for Re-Liquification of BOG," Energies, MDPI, vol. 13(15), pages 1-14, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Dun & Gao, Jianmin & Zhao, Ziqi & Du, Qian & Dong, Heming & Cui, Zhaoyang, 2022. "Effects of iron on coal pyrolysis-derived soot formation," Energy, Elsevier, vol. 249(C).
    2. Zhang, Zhi-Hui & Balasubramanian, Rajasekhar, 2015. "Influence of an iron-based fuel-borne catalyst on physicochemical and toxicological characteristics of particulate emissions from a diesel engine," Applied Energy, Elsevier, vol. 146(C), pages 270-278.
    3. Kang, Yinhu & Sun, Yuming & Lu, Xiaofeng & Gou, Xiaolong & Sun, Sicong & Yan, Jin & Song, Yangfan & Zhang, Pengyuan & Wang, Quanhai & Ji, Xuanyu, 2018. "Soot formation characteristics of ethylene premixed burner-stabilized stagnation flame with dimethyl ether addition," Energy, Elsevier, vol. 150(C), pages 709-721.
    4. Sarvestani, Nasrin Sabet & Tabasizadeh, Mohammad & Abbaspour Fard, Mohammad Hossein & Nayebzadeh, Hamed & Van, Thuy Chu & Jafari, Mohammad & Bodisco, Timothy A. & Ristovski, Zoran & Brown, Richard J., 2021. "Effects of enhanced fuel with Mg-doped Fe3O4 nanoparticles on combustion of a compression ignition engine: Influence of Mg cation concentration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    5. Chu, Huaqiang & Han, Weiwei & Cao, Wenjian & Gu, Mingyan & Xu, Guangju, 2019. "Effect of methane addition to ethylene on the morphology and size distribution of soot in a laminar co-flow diffusion flame," Energy, Elsevier, vol. 166(C), pages 392-400.
    6. Ma, Yu & Zhu, Mingming & Zhang, Dongke, 2014. "Effect of a homogeneous combustion catalyst on the characteristics of diesel soot emitted from a compression ignition engine," Applied Energy, Elsevier, vol. 113(C), pages 751-757.
    7. Luo, Minye & Liu, Dong, 2018. "Effects of dimethyl ether addition on soot formation, evolution and characteristics in flame-wall interactions," Energy, Elsevier, vol. 164(C), pages 642-654.
    8. Marcin Tkaczyk & Zbigniew J. Sroka & Konrad Krakowian & Radoslaw Wlostowski, 2020. "Experimental Study of the Effect of Fuel Catalytic Additive on Specific Fuel Consumption and Exhaust Emissions in Diesel Engine," Energies, MDPI, vol. 14(1), pages 1-14, December.
    9. Li, Dun & Gao, Jianmin & Du, Qian & Zhao, Ziqi & Dong, Heming & Cui, Zhaoyang, 2023. "Influence of an iron compound added to coal on soot formation," Energy, Elsevier, vol. 266(C).
    10. Saxena, Vishal & Kumar, Niraj & Saxena, Vinod Kumar, 2019. "Multi-objective optimization of modified nanofluid fuel blends at different TiO2 nanoparticle concentration in diesel engine: Experimental assessment and modeling," Applied Energy, Elsevier, vol. 248(C), pages 330-353.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:148:y:2018:i:c:p:802-808. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.