IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v127y2017icp419-427.html
   My bibliography  Save this article

Poly (pyrrole-co-aniline) hollow nanosphere supported Pd nanoflowers as high-performance catalyst for methanol electrooxidation in alkaline media

Author

Listed:
  • Fard, Leyla Abolghasemi
  • Ojani, Reza
  • Raoof, Jahan Bakhsh
  • Zare, Ehsan Nazarzadeh
  • Lakouraj, Moslem Mansour

Abstract

In this work, first poly (pyrrole-co-aniline) (PPCA) hollow nanosphere (HN) as a catalyst support material is fabricated through in-situ emulsion polymerization. Then we reported a one-step and template-free approach to fabricate Pd NFs on a PPCA HN coated glassy carbon electrode by a facile electrochemical approach. Several techniques such as FTIR (Fourier transform infrared spectroscopy), SEM (scanning electron microscopy) and EDS (energy dispersive spectroscopy) were utilized for the characterization of the synthesized materials. The catalytic performance of Pd NFs/PPCA HN catalyst is evaluated by cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy toward methanol oxidation as a model reaction in alkaline media. The comparison of specific activities for Pd NFs/PPCA HN (1.79 mA cm−2), Pd NFs/PPy (1.28 mA cm−2), Pd NFs/PANI (0.93 mA cm−2) and Pd NFs (0.78 mA cm−2) shows that the PPCA supported Pd NFs with high surface area exhibits the excellent electrocatalytic activity than other electrodes for the electro-oxidation reaction in alkaline media. This might be due to the easier charge transfer at conductive copolymer interfaces, higher electrochemically accessible surface areas and electronic conductivity. This strategy provides a promising platform for direct methanol fuel cells.

Suggested Citation

  • Fard, Leyla Abolghasemi & Ojani, Reza & Raoof, Jahan Bakhsh & Zare, Ehsan Nazarzadeh & Lakouraj, Moslem Mansour, 2017. "Poly (pyrrole-co-aniline) hollow nanosphere supported Pd nanoflowers as high-performance catalyst for methanol electrooxidation in alkaline media," Energy, Elsevier, vol. 127(C), pages 419-427.
    • Handle: RePEc:eee:energy:v:127:y:2017:i:c:p:419-427
    DOI: 10.1016/j.energy.2017.03.159
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217305571
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.03.159?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ojani, Reza & Hasheminejad, Ehteram & Raoof, Jahan Bakhsh, 2015. "Direct growth of 3D flower-like Pt nanostructures by a template-free electrochemical route as an efficient electrocatalyst for methanol oxidation reaction," Energy, Elsevier, vol. 90(P1), pages 1122-1131.
    2. Barbir, Frano, 2009. "Transition to renewable energy systems with hydrogen as an energy carrier," Energy, Elsevier, vol. 34(3), pages 308-312.
    3. Döner, Ali & Solmaz, Ramazan & Kardaş, Gülfeza, 2015. "Fabrication and characterization of alkaline leached CuZn/Cu electrode as anode material for direct methanol fuel cell," Energy, Elsevier, vol. 90(P1), pages 1144-1151.
    4. Ju, Jianfeng & Chen, Xi & Shi, Yujun & Wu, Donghui & Hua, Ping, 2013. "A novel TiO2 nanofiber supported PdAg catalyst for methanol electro-oxidation," Energy, Elsevier, vol. 59(C), pages 478-483.
    5. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    2. Ojani, Reza & Hasheminejad, Ehteram & Raoof, Jahan Bakhsh, 2015. "Direct growth of 3D flower-like Pt nanostructures by a template-free electrochemical route as an efficient electrocatalyst for methanol oxidation reaction," Energy, Elsevier, vol. 90(P1), pages 1122-1131.
    3. Hosseini, M.G. & Mahmoodi, R. & Sadeghi Amjadi, M., 2017. "Carbon supported Ni1Pt1 nanocatalyst as superior electrocatalyst with increased power density in direct borohydride-hydrogen peroxide and investigation of cell impedance at different temperatures and ," Energy, Elsevier, vol. 131(C), pages 137-148.
    4. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    5. Song, Xingjuan & Zhang, Dongming, 2014. "Bimetallic Ag–Ni/C particles as cathode catalyst in AFCs (alkaline fuel cells)," Energy, Elsevier, vol. 70(C), pages 223-230.
    6. Sieben, J.M. & Morallón, E. & Cazorla-Amorós, D., 2013. "Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods," Energy, Elsevier, vol. 58(C), pages 519-526.
    7. Ju, Rongyuan & Wang, Jinhua & Zhang, Meng & Mu, Haibao & Zhang, Guanjun & Yu, Jinlu & Huang, Zuohua, 2023. "Stability and emission characteristics of ammonia/air premixed swirling flames with rotating gliding arc discharge plasma," Energy, Elsevier, vol. 277(C).
    8. Yuan, Zhenyu & Yang, Jie & Li, Xiaoyang & Wang, Shikai, 2016. "The micro-scale analysis of the micro direct methanol fuel cell," Energy, Elsevier, vol. 100(C), pages 10-17.
    9. Weng, Baicheng & Wu, Zhu & Li, Zhilin & Yang, Hui, 2012. "Hydrogen generation from hydrolysis of MNH2BH3 and NH3BH3/MH (M=Li, Na) for fuel cells based unmanned submarine vehicles application," Energy, Elsevier, vol. 38(1), pages 205-211.
    10. Sun, Shaohui & Yan, Wei & Sun, Peiqin & Chen, Junwu, 2012. "Thermodynamic analysis of ethanol reforming for hydrogen production," Energy, Elsevier, vol. 44(1), pages 911-924.
    11. Ji, Zhaoqi & Perez-Page, Maria & Chen, Jianuo & Rodriguez, Romeo Gonzalez & Cai, Rongsheng & Haigh, Sarah J. & Holmes, Stuart M., 2021. "A structured catalyst support combining electrochemically exfoliated graphene oxide and carbon black for enhanced performance and durability in low-temperature hydrogen fuel cells," Energy, Elsevier, vol. 226(C).
    12. García, Lázaro & González, Daniel & García, Carlos & García, Laura & Brayner, Carlos, 2013. "Efficiency of the sulfur–iodine thermochemical water splitting process for hydrogen production based on ADS (accelerator driven system)," Energy, Elsevier, vol. 57(C), pages 469-477.
    13. Ye, Tuo & Zhao, Songyu & Lau, Chi Keung Marco & Chau, Frankie, 2024. "Social media sentiment of hydrogen fuel cell vehicles in China: Evidence from artificial intelligence algorithms," Energy Economics, Elsevier, vol. 133(C).
    14. Mohammad Fazle Rabbi & József Popp & Domicián Máté & Sándor Kovács, 2022. "Energy Security and Energy Transition to Achieve Carbon Neutrality," Energies, MDPI, vol. 15(21), pages 1-18, October.
    15. Lin, Kuang C. & Lin, Yuan-Chung & Hsiao, Yi-Hsing, 2014. "Microwave plasma studies of Spirulina algae pyrolysis with relevance to hydrogen production," Energy, Elsevier, vol. 64(C), pages 567-574.
    16. Yang, Zijun & Wang, Bowen & Jiao, Kui, 2020. "Life cycle assessment of fuel cell, electric and internal combustion engine vehicles under different fuel scenarios and driving mileages in China," Energy, Elsevier, vol. 198(C).
    17. Singh, Neeraj Kumar & Kumari, Priyanka & Singh, Rajesh, 2021. "Intensified hydrogen yield using hydrogenase rich sulfate-reducing bacteria in bio-electrochemical system," Energy, Elsevier, vol. 219(C).
    18. Marino, C. & Nucara, A. & Panzera, M.F. & Pietrafesa, M. & Varano, V., 2019. "Energetic and economic analysis of a stand alone photovoltaic system with hydrogen storage," Renewable Energy, Elsevier, vol. 142(C), pages 316-329.
    19. Guo, Yuwei & Li, Yun & Li, Shuguang & Zhang, Lei & Li, Ying & Wang, Jun, 2015. "Enhancement of visible-light photocatalytic activity of Pt supported potassium niobate (Pt-KNbO3) by up-conversion luminescence agent (Er3+:Y3Al5O12) for hydrogen evolution from aqueous methanol solut," Energy, Elsevier, vol. 82(C), pages 72-79.
    20. Mirzaei, Farokh & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2017. "Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell," Energy, Elsevier, vol. 138(C), pages 696-705.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:127:y:2017:i:c:p:419-427. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.