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Development of a robust refrigerant mixture for liquefaction of highly uncertain natural gas compositions

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  • Mortazavi, Amir
  • Alabdulkarem, Abdullah
  • Hwang, Yunho
  • Radermacher, Reinhard

Abstract

To export natural gas to overseas, it has to be liquefied and transported by the LNG tankers. Some LNG plants will receive their natural gas from different shale gas reservoirs so that one of the key challenges in developing a refrigerant mixture is the variation the of natural gas compositions. Previous attempts to create refrigerant mixtures for LNG plants were focused on implementing deterministic optimization methods. However, we demonstrate in this paper that these optimized refrigerants are so sensitive to natural gas composition that a slight variation in natural gas composition makes them unsuitable for the liquefaction process. To demonstrate the Gradient Assisted Robust Optimization technique capabilities, we developed a refrigerant mixture for propane precooled mixed refrigerant natural gas liquefaction cycles with an exaggerated variation in feed gas composition. This refrigerant is relatively unaffected by the variation of the natural gas compositions. We compared the performance of the new refrigerant to five other refrigerants found in literature and found the newly developed refrigerant is the only one satisfying the design constraints for all of the tested natural gas mixture compositions. This technique can be used for developing refrigerant for any LNG cycle that has a variation in feed composition.

Suggested Citation

  • Mortazavi, Amir & Alabdulkarem, Abdullah & Hwang, Yunho & Radermacher, Reinhard, 2016. "Development of a robust refrigerant mixture for liquefaction of highly uncertain natural gas compositions," Energy, Elsevier, vol. 113(C), pages 1042-1050.
  • Handle: RePEc:eee:energy:v:113:y:2016:i:c:p:1042-1050
    DOI: 10.1016/j.energy.2016.07.147
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    References listed on IDEAS

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    1. Mortazavi, A. & Somers, C. & Hwang, Y. & Radermacher, R. & Rodgers, P. & Al-Hashimi, S., 2012. "Performance enhancement of propane pre-cooled mixed refrigerant LNG plant," Applied Energy, Elsevier, vol. 93(C), pages 125-131.
    2. Mokarizadeh Haghighi Shirazi, M. & Mowla, D., 2010. "Energy optimization for liquefaction process of natural gas in peak shaving plant," Energy, Elsevier, vol. 35(7), pages 2878-2885.
    3. Mortazavi, Amir & Somers, Christopher & Alabdulkarem, Abdullah & Hwang, Yunho & Radermacher, Reinhard, 2010. "Enhancement of APCI cycle efficiency with absorption chillers," Energy, Elsevier, vol. 35(9), pages 3877-3882.
    4. Chelouah, Rachid & Siarry, Patrick, 2005. "A hybrid method combining continuous tabu search and Nelder-Mead simplex algorithms for the global optimization of multiminima functions," European Journal of Operational Research, Elsevier, vol. 161(3), pages 636-654, March.
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    Cited by:

    1. Chulmin Hwang & Taejong Yu & Youngsub Lim, 2021. "Optimal Process Design of Small Scale SMR Process for LNG Vessel," Energies, MDPI, vol. 14(12), pages 1-12, June.
    2. Ghorbani, Bahram & Shirmohammadi, Reza & Mehrpooya, Mehdi & Hamedi, Mohammad-Hossein, 2018. "Structural, operational and economic optimization of cryogenic natural gas plant using NSGAII two-objective genetic algorithm," Energy, Elsevier, vol. 159(C), pages 410-428.
    3. Zhang, Shouxin & Zou, Zimo & Klemeš, Jiří Jaromír & Varbanov, Petar Sabev & Shahzad, Khurram & Ali, Arshid Mahmood & Wang, Bo-Hong, 2023. "A new strategy for mixed refrigerant composition optimisation in the propane precooled mixed refrigerant natural gas liquefaction process," Energy, Elsevier, vol. 274(C).
    4. Song, Rui & Cui, Mengmeng & Liu, Jianjun, 2017. "Single and multiple objective optimization of a natural gas liquefaction process," Energy, Elsevier, vol. 124(C), pages 19-28.
    5. Lei Gao & Jiaxin Wang & Maxime Binama & Qian Li & Weihua Cai, 2022. "The Design and Optimization of Natural Gas Liquefaction Processes: A Review," Energies, MDPI, vol. 15(21), pages 1-56, October.
    6. Lee, Jaejun & Son, Heechang & Yu, Taejong & Oh, Juyoung & Park, Min Gyun & Lim, Youngsub, 2023. "Process design of advanced LNG subcooling system combined with a mixed refrigerant cycle," Energy, Elsevier, vol. 278(PA).

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