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Production of hydrogen and sulfur from hydrogen sulfide assisted by nonthermal plasma

Author

Listed:
  • Linga Reddy, E.
  • Biju, V.M.
  • Subrahmanyam, Ch.

Abstract

Hydrogen production by nonthermal plasma (NTP) assisted direct decomposition of hydrogen sulfide was studied in a dielectric barrier discharge (DBD) reactor operated under ambient conditions. It may be concluded that NTP is effective in direct decomposition of H2S into H2 and S. Changing ground electrode material from silver paste to either copper wire or aluminium foil only increased the energy demand, but did not show any significant improvement in conversion. Influence of various parameters like ground electrode, discharge gap, residence time and H2S concentration were studied to achieve hydrogen production under energetically feasible conditions. It has been observed that H2S conversion into H2 and S may be efficient at high residence time and low concentrations. By optimizing the reaction conditions, H2 production may be produced at 160kJ/mol (∼1.6eV/H2) that is less than the energy demand in steam methane reforming (354kJ/mol H2 or 3.7eV/H2).

Suggested Citation

  • Linga Reddy, E. & Biju, V.M. & Subrahmanyam, Ch., 2012. "Production of hydrogen and sulfur from hydrogen sulfide assisted by nonthermal plasma," Applied Energy, Elsevier, vol. 95(C), pages 87-92.
    • Handle: RePEc:eee:appene:v:95:y:2012:i:c:p:87-92
    DOI: 10.1016/j.apenergy.2012.02.010
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    References listed on IDEAS

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    1. Escher, W.J.D., 1994. "Hydrogen as a transportation fuel," Applied Energy, Elsevier, vol. 47(2-3), pages 201-226.
    2. El-Osta, W. & Zeghlam, J., 2000. "Hydrogen as a fuel for the transportation sector: possibilities and views for future applications in Libya," Applied Energy, Elsevier, vol. 65(1-4), pages 165-171, April.
    3. Dell, R. M. & Bridger, N. J., 1975. "Hydrogen--The ultimate fuel," Applied Energy, Elsevier, vol. 1(4), pages 279-292, October.
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    1. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Liu, Hui & Liu, Yongjun, 2016. "Effects of plate electrode materials on hydrogen production by pulsed discharge in ethanol solution," Applied Energy, Elsevier, vol. 181(C), pages 75-82.
    2. Jiang, Hong & Wang, Xirui & Li, Chaoying & Gu, Di & Jiang, Tingting & Nie, Chunhong & Yuan, Dandan & Wu, Hongjun & Wang, Baohui, 2021. "An alternative electron-donor and highly thermo-assisted strategy for solar-driven water splitting redox chemistry towards efficient hydrogen production plus effective wastewater treatment," Renewable Energy, Elsevier, vol. 176(C), pages 388-401.
    3. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Zhao, Xiaotong & Sun, Xiaohang, 2017. "Hydrogen production from ethanol decomposition by pulsed discharge with needle-net configurations," Applied Energy, Elsevier, vol. 206(C), pages 126-133.
    4. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Liu, Yongjun & Liu, Hui, 2016. "Characteristics of hydrogen produced by pulsed discharge in ethanol solution," Applied Energy, Elsevier, vol. 168(C), pages 122-129.
    5. Gao, Yuan & Zhang, Shuai & Sun, Hao & Wang, Ruixue & Tu, Xin & Shao, Tao, 2018. "Highly efficient conversion of methane using microsecond and nanosecond pulsed spark discharges," Applied Energy, Elsevier, vol. 226(C), pages 534-545.
    6. Khalifeh, Omid & Mosallanejad, Amin & Taghvaei, Hamed & Rahimpour, Mohammad Reza & Shariati, Alireza, 2016. "Decomposition of methane to hydrogen using nanosecond pulsed plasma reactor with different active volumes, voltages and frequencies," Applied Energy, Elsevier, vol. 169(C), pages 585-596.
    7. Kim, Taegyu & Jo, Sungkwon & Song, Young-Hoon & Lee, Dae Hoon, 2014. "Synergetic mechanism of methanol–steam reforming reaction in a catalytic reactor with electric discharges," Applied Energy, Elsevier, vol. 113(C), pages 1692-1699.

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