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Carbon based nanotubes and nanopowder as impregnated electrode structures for enhanced power generation: Evaluation with real field wastewater

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  • Mohanakrishna, G.
  • Krishna Mohan, S.
  • Venkata Mohan, S.

Abstract

Carbon based multiwalled nanotubes (MWCNT) and nanopowder (CNP) impregnated using conductive epoxy resin on anodic surface were evaluated for bioelectricity generation in single chambered microbial fuel cells in comparison with plain graphite anode (MFCP). The study demonstrated the positive function of carbon nano structures impregnated anode with respect to power generation. MFCMWCNT exhibited higher electrogenic activity (267.77mW/m2) followed by MFCCNP (168.45mW/m2) and MFCP (107.51mW/m2). MFCMWCNT and MFCCNP showed 148% and 57% enhancement in the power generation respectively compared to MFCP. Microbial mediators were also found to be more effective with modified anodes operation. Impregnation with nano material facilitates higher surface area that enables higher charge transfer from anolyte to electrodes. Impregnated anodes showed marginal influence on substrate degradation. Further, feasibility of MWCNT impregnated anode was evaluated with real field distillery wastewater which depicted good electrogenic activity (245.34mW/m2) and yield (3.43W/m3).

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  • Mohanakrishna, G. & Krishna Mohan, S. & Venkata Mohan, S., 2012. "Carbon based nanotubes and nanopowder as impregnated electrode structures for enhanced power generation: Evaluation with real field wastewater," Applied Energy, Elsevier, vol. 95(C), pages 31-37.
    • Handle: RePEc:eee:appene:v:95:y:2012:i:c:p:31-37
    DOI: 10.1016/j.apenergy.2012.01.058
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    1. Rahimnejad, Mostafa & Ghoreyshi, Ali Asghar & Najafpour, Ghasem & Jafary, Tahereh, 2011. "Power generation from organic substrate in batch and continuous flow microbial fuel cell operations," Applied Energy, Elsevier, vol. 88(11), pages 3999-4004.
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    2. Nikhil, G.N. & Venkata Subhash, G. & Yeruva, Dileep Kumar & Venkata Mohan, S., 2015. "Synergistic yield of dual energy forms through biocatalyzed electrofermentation of waste: Stoichiometric analysis of electron and carbon distribution," Energy, Elsevier, vol. 88(C), pages 281-291.
    3. Fang, Fang & Zang, Guo-Long & Sun, Min & Yu, Han-Qing, 2013. "Optimizing multi-variables of microbial fuel cell for electricity generation with an integrated modeling and experimental approach," Applied Energy, Elsevier, vol. 110(C), pages 98-103.
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    5. Venkata Mohan, S. & Velvizhi, G. & Annie Modestra, J. & Srikanth, S., 2014. "Microbial fuel cell: Critical factors regulating bio-catalyzed electrochemical process and recent advancements," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 779-797.
    6. Modestra, J. Annie & Chiranjeevi, P. & Mohan, S. Venkata, 2016. "Cathodic material effect on electron acceptance towards bioelectricity generation and wastewater treatment," Renewable Energy, Elsevier, vol. 98(C), pages 178-187.
    7. Chen, Yinguang & Luo, Jingyang & Yan, Yuanyuan & Feng, Leiyu, 2013. "Enhanced production of short-chain fatty acid by co-fermentation of waste activated sludge and kitchen waste under alkaline conditions and its application to microbial fuel cells," Applied Energy, Elsevier, vol. 102(C), pages 1197-1204.
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    10. Magdalena Zielińska & Katarzyna Bułkowska & Wioleta Mikucka, 2021. "Valorization of Distillery Stillage for Bioenergy Production: A Review," Energies, MDPI, vol. 14(21), pages 1-17, November.

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