IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v92y2012icp361-368.html
   My bibliography  Save this article

A kinetic study of NO formation during oxy-fuel combustion of pyridine

Author

Listed:
  • Wang, B.
  • Sun, L.S.
  • Su, S.
  • Xiang, J.
  • Hu, S.
  • Fei, H.

Abstract

In this work, pyridine-N was converted into NO and N2 by using a flow reactor and the dominant NO evolution pathways were identified by means of a kinetic modeling under O2/CO2 atmosphere in temperature range of 1073–1473K for different stoichiometries. The experimental results indicated higher temperatures promoted the formation of NO, with conversions varied from 1.26–18.64% to 3.85–43% for fuel-rich and fuel-lean conditions respectively. As for N2 formation, conversion of pyridine to N2 had a slight increase from 1073 to 1173K then declined rapidly in oxidizing atmosphere, whereas this conversion stabilized at about 36% before decreasing to 29% above 1173K in the presence of insufficient O2. Increasing the equivalence ratio led to a monotonic increase of NO in both O2/Ar and O2/CO2 atmospheres, and the gap between these atmospheres developed with α. The simulation results showed that the high CO2 concentration reduced the availability of oxygen thus altered the evolution of NO through promoting reaction HNO+M↔H+NO+M and limiting reaction HNO+O2↔HO2+NO. This was even more important at higher temperatures. Besides, the major pathways for NO consumption were taken through reaction with NCO and NH as intermediates. In general, the model of Terasa09 described the experimental trends well, and this combustion kinetic was applicable to oxy-fuel conditions.

Suggested Citation

  • Wang, B. & Sun, L.S. & Su, S. & Xiang, J. & Hu, S. & Fei, H., 2012. "A kinetic study of NO formation during oxy-fuel combustion of pyridine," Applied Energy, Elsevier, vol. 92(C), pages 361-368.
    • Handle: RePEc:eee:appene:v:92:y:2012:i:c:p:361-368
    DOI: 10.1016/j.apenergy.2011.11.039
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261911007367
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2011.11.039?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Aspelund, Audun & Gundersen, Truls, 2009. "A liquefied energy chain for transport and utilization of natural gas for power production with CO2 capture and storage - Part 2: The offshore and the onshore processes," Applied Energy, Elsevier, vol. 86(6), pages 793-804, June.
    2. Aspelund, Audun & Gundersen, Truls, 2009. "A liquefied energy chain for transport and utilization of natural gas for power production with CO2 capture and storage - Part 1," Applied Energy, Elsevier, vol. 86(6), pages 781-792, June.
    3. Hu, Yukun & Yan, Jinyue, 2012. "Characterization of flue gas in oxy-coal combustion processes for CO2 capture," Applied Energy, Elsevier, vol. 90(1), pages 113-121.
    4. Liu, Hao & Shao, Yingjuan, 2010. "Predictions of the impurities in the CO2 stream of an oxy-coal combustion plant," Applied Energy, Elsevier, vol. 87(10), pages 3162-3170, October.
    5. Li, H. & Yan, J. & Yan, J. & Anheden, M., 2009. "Impurity impacts on the purification process in oxy-fuel combustion based CO2 capture and storage system," Applied Energy, Elsevier, vol. 86(2), pages 202-213, February.
    6. Aspelund, Audun & Tveit, Steinar P. & Gundersen, Truls, 2009. "A liquefied energy chain for transport and utilization of natural gas for power production with CO2 capture and storage - Part 3: The combined carrier and onshore storage," Applied Energy, Elsevier, vol. 86(6), pages 805-814, June.
    7. Castillo, Renzo, 2011. "Thermodynamic analysis of a hard coal oxyfuel power plant with high temperature three-end membrane for air separation," Applied Energy, Elsevier, vol. 88(5), pages 1480-1493, May.
    8. Wu, Yinghai & Wang, Chunbo & Tan, Yewen & Jia, Lufei & Anthony, Edward J., 2011. "Characterization of ashes from a 100kWth pilot-scale circulating fluidized bed with oxy-fuel combustion," Applied Energy, Elsevier, vol. 88(9), pages 2940-2948.
    9. Okazaki, K. & Ando, T., 1997. "NOx reduction mechanism in coal combustion with recycled CO2," Energy, Elsevier, vol. 22(2), pages 207-215.
    10. Aspelund, Audun & Gundersen, Truls, 2009. "A liquefied energy chain for transport and utilization of natural gas for power production with CO2 capture and storage - Part 4: Sensitivity analysis of transport pressures and benchmarking with conv," Applied Energy, Elsevier, vol. 86(6), pages 815-825, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Luo, Jianghui & Zou, Chun & He, Yizhuo & Jing, Huixiang & Cheng, Sizhe, 2019. "The characteristics and mechanism of NO formation during pyridine oxidation in O2/N2 and O2/CO2 atmospheres," Energy, Elsevier, vol. 187(C).
    2. Woo, Mino & Choi, Byung Chul & Ghoniem, Ahmed F., 2016. "Experimental and numerical studies on NOx emission characteristics in laminar non-premixed jet flames of ammonia-containing methane fuel with oxygen/nitrogen oxidizer," Energy, Elsevier, vol. 114(C), pages 961-972.
    3. Li, Shiyuan & Xu, Mingxin & Jia, Lufei & Tan, Li & Lu, Qinggang, 2016. "Influence of operating parameters on N2O emission in O2/CO2 combustion with high oxygen concentration in circulating fluidized bed," Applied Energy, Elsevier, vol. 173(C), pages 197-209.
    4. Xu, Mingxin & Li, Shiyuan & Wu, Yinghai & Jia, Lufei & Lu, Qinggang, 2017. "The characteristics of recycled NO reduction over char during oxy-fuel fluidized bed combustion," Applied Energy, Elsevier, vol. 190(C), pages 553-562.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chi, Chung-Cheng & Lin, Ta-Hui, 2013. "Oxy-oil combustion characteristics of an existing furnace," Applied Energy, Elsevier, vol. 102(C), pages 923-930.
    2. Chen, Wei-Hsin & Hou, Yu-Lin & Hung, Chen-I, 2011. "A theoretical analysis of the capture of greenhouse gases by single water droplet at atmospheric and elevated pressures," Applied Energy, Elsevier, vol. 88(12), pages 5120-5130.
    3. Jiang, Xi, 2011. "A review of physical modelling and numerical simulation of long-term geological storage of CO2," Applied Energy, Elsevier, vol. 88(11), pages 3557-3566.
    4. Xu, Mingxin & Li, Shiyuan & Wu, Yinghai & Jia, Lufei & Lu, Qinggang, 2017. "The characteristics of recycled NO reduction over char during oxy-fuel fluidized bed combustion," Applied Energy, Elsevier, vol. 190(C), pages 553-562.
    5. Obara, Shin’ya & Yamada, Takanobu & Matsumura, Kazuhiro & Takahashi, Shiro & Kawai, Masahito & Rengarajan, Balaji, 2011. "Operational planning of an engine generator using a high pressure working fluid composed of CO2 hydrate," Applied Energy, Elsevier, vol. 88(12), pages 4733-4741.
    6. Baccanelli, Margaret & Langé, Stefano & Rocco, Matteo V. & Pellegrini, Laura A. & Colombo, Emanuela, 2016. "Low temperature techniques for natural gas purification and LNG production: An energy and exergy analysis," Applied Energy, Elsevier, vol. 180(C), pages 546-559.
    7. Pérez Sánchez, Jordán & Aguillón Martínez, Javier Eduardo & Mazur Czerwiec, Zdzislaw & Zavala Guzmán, Alan Martín, 2019. "Theoretical assessment of integration of CCS in the Mexican electrical sector," Energy, Elsevier, vol. 167(C), pages 828-840.
    8. Jiang, Xi & Akber Hassan, Wasim A. & Gluyas, Jon, 2013. "Modelling and monitoring of geological carbon storage: A perspective on cross-validation," Applied Energy, Elsevier, vol. 112(C), pages 784-792.
    9. Lee, Inkyu & Park, Jinwoo & You, Fengqi & Moon, Il, 2019. "A novel cryogenic energy storage system with LNG direct expansion regasification: Design, energy optimization, and exergy analysis," Energy, Elsevier, vol. 173(C), pages 691-705.
    10. Wang, Xucen & Li, Min & Cai, Liuxi & Li, Yun, 2020. "Propane and iso-butane pre-cooled mixed refrigerant liquefaction process for small-scale skid-mounted natural gas liquefaction," Applied Energy, Elsevier, vol. 275(C).
    11. Morandin, Matteo & Maréchal, François & Mercangöz, Mehmet & Buchter, Florian, 2012. "Conceptual design of a thermo-electrical energy storage system based on heat integration of thermodynamic cycles – Part A: Methodology and base case," Energy, Elsevier, vol. 45(1), pages 375-385.
    12. Yin, Chungen & Yan, Jinyue, 2016. "Oxy-fuel combustion of pulverized fuels: Combustion fundamentals and modeling," Applied Energy, Elsevier, vol. 162(C), pages 742-762.
    13. Yan, G. & Gu, Y., 2010. "Effect of parameters on performance of LNG-FPSO offloading system in offshore associated gas fields," Applied Energy, Elsevier, vol. 87(11), pages 3393-3400, November.
    14. Teyber, Reed & Holladay, Jamelyn & Meinhardt, Kerry & Polikarpov, Evgueni & Thomsen, Edwin & Cui, Jun & Rowe, Andrew & Barclay, John, 2019. "Performance investigation of a high-field active magnetic regenerator," Applied Energy, Elsevier, vol. 236(C), pages 426-436.
    15. Tan, Y. & Jia, L. & Wu, Y. & Anthony, E.J., 2012. "Experiences and results on a 0.8MWth oxy-fuel operation pilot-scale circulating fluidized bed," Applied Energy, Elsevier, vol. 92(C), pages 343-347.
    16. Li, Xiao-Sen & Yang, Bo & Zhang, Yu & Li, Gang & Duan, Li-Ping & Wang, Yi & Chen, Zhao-Yang & Huang, Ning-Sheng & Wu, Hui-Jie, 2012. "Experimental investigation into gas production from methane hydrate in sediment by depressurization in a novel pilot-scale hydrate simulator," Applied Energy, Elsevier, vol. 93(C), pages 722-732.
    17. Zhao, Guoying & Aziz, Baroz & Hedin, Niklas, 2010. "Carbon dioxide adsorption on mesoporous silica surfaces containing amine-like motifs," Applied Energy, Elsevier, vol. 87(9), pages 2907-2913, September.
    18. Querol, E. & Gonzalez-Regueral, B. & García-Torrent, J. & Ramos, Alberto, 2011. "Available power generation cycles to be coupled with the liquid natural gas (LNG) vaporization process in a Spanish LNG terminal," Applied Energy, Elsevier, vol. 88(7), pages 2382-2390, July.
    19. Obara, Shin'ya & Kikuchi, Yoshinobu & Ishikawa, Kyosuke & Kawai, Masahito & Yoshiaki, Kashiwaya, 2015. "Development of a compound energy system for cold region houses using small-scale natural gas cogeneration and a gas hydrate battery," Energy, Elsevier, vol. 85(C), pages 280-295.
    20. Aspelund, Audun & Gundersen, Truls, 2009. "A liquefied energy chain for transport and utilization of natural gas for power production with CO2 capture and storage - Part 4: Sensitivity analysis of transport pressures and benchmarking with conv," Applied Energy, Elsevier, vol. 86(6), pages 815-825, June.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:92:y:2012:i:c:p:361-368. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.